噻吩基

There is no electron transfer from tetrakis(2-thienyl)tetrathiafulvalene to [60]fullerene containing piperidinoxanthate dyad in benzonitrile in steady-state.

四硫富瓦烯及其衍生物是良好的有机导体及电子给体，噻吩基取代的四硫富瓦烯可作为合成含噻吩及四硫富瓦烯两种电子给体的聚合物的单体。

Project Background and Conditions: The company started research new chemical products in 1998. After two years of efforts, a series of pharmaceutical intermediate sulfathiazole leave instructions, including : 3- methyl sulfathiazole leave instructions, 2- sulfathiazole leave instructions ethanoic acid, 2- acetyl sulfathiazole leave instructions, 2-thiofuran amino ethane ,2-thiofuran acetic, 3,4,5- tighter nitrobenzene have been successfully developed. 2-thiofuran amino ethane are the precursors raw materials of series antibiotic analgesic.

二、项目建设背景及条件：1998年公司开始研究开发高新精细化工产品，经过两年的努力，已成功研制出噻吩系列医药中间体，包括：3-甲基噻吩、2-噻吩乙酸、2-乙酰噻吩、2-噻吩乙胺、2-噻吩乙醇、3，4，5-三氯硝基苯等。2-噻吩乙胺系列噻吩产品使用于血小板及血栓有关的心脏血管病及消炎镇痛等如氯吡格雷、兴孢噻吩钠、兴孢西丁、噻吩洛酸等十几种新药的前体原料，是国家政策鼓励发展和有自主知识产权的项目。

By adopting novel Pummerer-cyanation route and by using thionyl chloride as S-transfer reagent, the first thieno [3,4-c] thiophene bearing all electron withdrawing groups has been synthesized.

设计采用新颖的Pummerer-氰化路线和用亚硫酰氯作S-转移试剂的路线合成了第一例全部连吸电子基的噻吩并[3，4-c]噻吩。

With the aim of enhancing the nonlinear optical property of poly, poly[(thiophene-2,5-diyl)p-(N,N-dimethylamino) azobenzylidene] is prepared from 4-aldehyde-4'-dimethylamino azobenzene and thiophene through condensation polymerization reaction.

为了提高聚噻吩甲烯的非线性光学性能，通过4-醛基-4'-二甲胺基偶氮苯和噻吩的缩聚反应，合成了聚噻吩对二甲氨基偶氮苯甲烷，再用PTDMAAB与四氯苯醌发生脱氢反应合成了侧链含偶氮的聚噻吩甲烯。

A new organic compound, trans-2--5-dimesitylborylthiophene (abbreviated as DMASBT, 5) with dimesitylboryl, dimethylamino and styryl-thiophene as electron acceptor, electron donor and conjugate bridge respectively, was synthesized. Its crystal structure determined by X-ray diffraction method indicates that the B-C bond between B atom and it bridge is obviously shorter than those of between B atom and mesityl groups. This remarkably strengthened B-C bonding can be regarded as an evidence of additional p-7t conjugation between the B atom and n bridge.

合成了以含硼基团为电子受体，以二甲胺基为电子给体，以苯乙烯基噻吩为共轭桥的新化合物2-[（4'-N，N-二甲胺基）苯乙烯基]-5-二米基硼-噻吩 trans-2-[(4'-N， N-dimethylamino) styryl]-5-dimesitylboryl-thiophene（简写为DMASBT，5）。X射线衍射方法测定其单晶结构表明，硼原子与π共轭桥之间的硼碳键相对于其它的硼碳键明显缩短，硼与π共轭桥之间存在除了σ键之外的p-π共轭作用。

Formylation and diformylation of dithieno [2,3-b:3',2'-d] thiophene were prepared by two methods. Firstly, aromatic carbanions were prepared by 1 Br/Li exchange of bromo dithieno[2,3-b:3',2'-d]thiophene with n-BuLi in THF at low temperature; 2 deprotonation of dithieno[2,3-b:3',2'-d]thiophene with LDA.

二噻吩并[2，3-b：3'，2'-d]噻吩单醛与双醛的制备首先通过两种方法产生芳基负离子：1溴代并三噻吩在四氢呋喃中与正丁基锂发生的溴锂交换；2用LDA对二噻吩并[2，3-b：3'，2'-d]噻吩去质子化作用。

The Stille coupling reaction between 8 iodo 9 benzyl 9H purine and RSnBu 3 (R=vinyl,2 thienyl,2 furyl,phenylethynyl and phenyl) was studied using (Ph 3P) 2PdCl 2 as catalyst and DMF as solvent.

采用 (Ph3 P) 2 PdCl2 为催化剂，DMF为溶剂，对 8 碘 9 苄基 9H 嘌呤与有机锡试剂RSnBu3 (R=乙烯基、2 噻吩基、2 呋喃基、苯乙炔基和苯基等)之间的 Stille偶合反应进行了研究，合成出了5种 8位取代的嘌呤衍生物。

Eight half-sandwich titanium complexes (S1-S8) with pendant thienyl group were synthesized. These complexes with MAO were tested in ethylene conversion.

合成了8个含有噻吩基的半夹心茂钛络合物（S1-S8），考察了它们在MAO的活化下对乙烯的催化性能。

A novel macromonomer,polystyrene capped with thienyl group,which can undergos oxidation coupling polymerization,has been synthesized by anionic polymerization of styrene with butyl lithium as the initiator and 3-bromo-thiophene as the terminator.

以丁基锂为引发剂、四氢呋喃为溶剂，在氮气气氛和-78℃下进行苯乙烯阴离子聚合，并加入 3-溴噻吩作为终止剂，从而合成出末端含噻吩基的聚苯乙烯，它可以进行氧化偶联聚合，是一类新的大分子单体。

In order to improve the hole mobility, a novel conjugated polymer DOTPAV-PT with triphenylamine unit in the side chain was synthesized and characterized in details, and the photophysical and electrical properties were investigated .

为提高聚噻吩衍生物的空穴迁移率，将空穴传输基元三苯胺引入到聚合物结构中，合成一种侧基为三苯胺乙烯基的聚噻吩衍生物DOTPAV-PT，并对其进行详细的表征和光物理性质及电性能研究。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。