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But no electron transfer was found from the excited porphyrin moiety to the oxadiazole moiety. Moreover, cyclic voltammetric studies of the dyads 5a , 3b and 4b further indicated that electron transfer from the oxadiazole moiety to the porphyrin moiety was possible.

nm激发下不存在分子内卟啉基团向噁二基团的电子回传竞争;电化学性能测定进一步表明从噁二基团向卟啉基团的电子传递是可能的。

Electron-transporting oxadiazole monomer 2-phenyl-5-p-(N-acrylateamino-phenyl-1,3,4-oxadiazole was designed, synthesized and copolymerized with NVK, MMA and Tb2 to give a Tb-complex containg copolymer PKMOTb with dual transporting moieties.

设计并合成了一种具有电子传输性能的噁二类单体2-苯基-5--1,3,4-噁二,并将此单体和NVK、MMA、Tb_2共聚,合成了同时带有双传输基团和稀土金属配合物单元的新型四元共聚物PKMOTb。

Heterocyclic compounds contianing oxazole or thiazole moiety are also an important organic fluorescent compounds,which extensively exist in nature compounds and have superior biological activities.

含有噻和噁母体的杂环化合物广泛存在于天然化合物中,具有很好的生物活性,而且还是一类很重要的有机荧光材料,因而受到广大科学研究者的广泛关注。

OxazoleⅠand methyl oxazole Ⅱ,key intermediates of leucamide A which is a natural ocean material,were prepared from L-serine,L-alanine and L-threonine by two different methods.

以L-丝氨酸、L-丙氨酸和L-苏氨酸为起始原料,采用两种不同的方法分别合成了天然海洋化合物Leucam ide A的关键中间体口恶化合物Ⅰ及甲基口恶化合物Ⅱ。

A polymer that had the highest binding selectivity and capability was used as solid-phase extraction sorbents for direct extraction of TBZ from different biological and environmental samples (cabbage, pannage, shrimp, orange juice and tap water).

三、以合成最优的戊醇分子印迹微粒作为固相萃取剂,检测包菜、饲料、虾肉、桔汁、水中痕量的戊醇。

ABSTRACT The decomposition temperature and heat of cefazolin sodium pentahydrate were measured by the differential scanning calorimetry technique. Its solubility data in various mixed solvents of water?

采用差热分析法测定头孢林钠的分解温度和分解热;采用激光法测定头孢林钠在不同配比的水?

To discover new strobilurin analogues with high pesticidal activity, a series of new strobilurin derivatives containing substituted pyrazole and pyrimide ring, which included 124 novel compounds (73 compounds containing substituted pyrazole ring and 51 compounds containing substituted pyrimide ring) were designed and synthesized. In addition, 36 new intermediates were synthesized. Their structures were characterized by ~1H NMR and elemental analysis, partial compounds were characterized by MS and IR once again.

为了发现具有更好生物活性的新型Strobilurin类化合物,本论文在详尽总结文献的基础上,设计并合成了含吡和嘧啶环的新型Strobilurin类化合物124个,其中含吡环的新型Strobilurin类化合物73个,含嘧啶环的新型Strobilurin类化合物51个;未见文献报道的中间体36个,所合成的化合物经过~1H NMR、IR、LC-MS或元素分析等确定了结构。

To discover new strobilurin analogues with high pesticidal activity, a series of new strobilurin derivatives containing substituted pyrazole and pyrimide ring, which included 124 novel compounds (73 compounds containing substituted pyrazole ring and 51 compounds containing substituted pyrimide ring) were designed and synthesized. In addition, 36 new intermediates were synthesized. Their structures were characterized by 1H NMR and elemental analysis, partial compounds were characterized by MS and IR once again.

为了发现具有更好生物活性的新型Strobilurin类化合物,本论文在详尽总结文献的基础上,设计并合成了含吡和嘧啶环的新型Strobilurin类化合物124个,其中含吡环的新加热管型Strobilurin类化合物73个,含嘧啶环的新型Strob 加热管 ilurin类化合物51个;未见文献报道的中间体36个,所合成的化合物经过1H NMR、IR、LC-MS或元素分析等确定了结构。

Methods Phenylacetaldehyde was prepared from benzimidazolium salt and benzyl chloride by the addition-hydrolysis reaction of benzimidazolium salt with Grignard reagent.

方法以苯并咪盐和苄基氯为原料,利用苯并咪盐与Grignard试剂的加成-水解反应合成苯乙醛。

A new imidazolinyl intermediate is prepared from phenylacetic acid and diethylenetriamine firstly, and then they react with the solution of sodium chloroacetate into the imidazolinyl quaternary ammonium salt.

以二甲苯为溶剂,苯乙酸和二乙烯三胺为原料,经酰胺化和环化脱水合成了新型咪啉化合物,并用氯乙酸钠溶液对其进行改性得到了苯乙酸咪啉季铵盐。

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And Pharaoh spoke to Joseph, saying, Your father and your brothers have come to you.

47:5 法老对约瑟说,你父亲和你弟兄们到你这里来了。

Additionally, the approximate flattening of surface strip using lines linking midpoints on perpendicular lines between geodesic curves and the unconditional extreme value method are discussed.

提出了用测地线方程、曲面上两点间短程线来计算膜结构曲面测地线的方法,同时,采用测地线间垂线的中点连线和用无约束极值法进行空间条状曲面近似展开的分析。

Hey Big Raven, The individual lies dont matter anymore - its ALL a tissue of lies in support of...

嘿大乌鸦,个别谎言的事不要再-其所有的组织的谎言,在支持。