唑

In order to find high active pesticide containing heterocycle, six novel terephthaloyl bisthioureas containing 1, 3, 4-thiodiazole were synthesized by the reaction of 2-amino-5-alkyl-1, 3, 4-thiodiazoles with terephthaloyl diisothiocyanate.

摘 要：为寻找高活性的含杂环农药，由中间体5-烷基-2-氨基-1， 3， 4-噻二唑与对苯二甲酰基二异硫氰酸酯反应，合成6种新的含1， 3， 4-噻二唑环的对苯二甲酰基双硫脲化合物Ⅲaf。

In order to find high active pesticide containing heterocycle, six novel terephthaloyl bisthioureas Ⅲ(subscript a-f containing 1,3,4-thiodiazole were synthesized by the reaction of 2-amino-5-alkyl-1,3,4-thiodiazoles with terephthaloyl diisothiocyanate.

为寻找高活性的含杂环农药，由中间体5-烷基－2-氨基－1，3，4-噻二唑与对苯二甲酰基二异硫氰酸酯反应，合成6种新的含1，3，4-噻二唑环的对苯二甲酰基双硫脲化合物Ⅲ。

One-pot reactions of 4 with isocyanates, triphenyl phosphine, hexachloroethane and triethylamine produced 2-anilino-5-arylidene-1-aryl-4,5-dihydroimidazo[1,2-b]-1',2',4'-triazol-4-ones 6 (or 7) in good yields.

而后用4与芳基异氰酸酯、三苯基膦、六氯乙烷和三乙胺"一锅"反应，得到4，5-二氢咪唑并[1，2-b]-1'，2'，4'-三唑-4-酮衍生物6或7。

Methods 4-Hydroxybenzonitrile (2) as the starting material was transformed to 4-hydroxy-thiobenzamide (3) via thioformylation. And ethyl 2-(4-hydroxyphenyl)-4-methylthiazole-5-carboxylate (4), which was synthesized via cyclization from 3, was treated with hexamethylenetetramine to generate the intermediate ethyl 2-(3-formyl-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate (5). The target compound febuxostat (1) was obtained from 5 by etherification, cyanidation, hydrolysis.

以羟基苯腈为原料，经硫代甲酰化得到对羟基硫代苯甲酰胺(3)，3经环合得到2-（4-羟基苯基）－4-甲基－噻唑－5-羧酸乙酯(4)，4与乌洛托品反应，得到中间体2-（3-甲酰基－4-羟基苯基）－4-甲基－噻唑－5-羧酸乙酯(5)，之后再经醚化、氰化、水解得到目标产物(1)。

In this paper, a novel kind of pyrazolone derivatives and their transition metal complexes have been synthesized by the reaction of 4-acylpyrazolone with hydrazide and salicylthydrazone.

本文以4-酰基吡唑啉酮为主体分别与酰肼类和酰腙类有机化合物反应，合成了新的吡唑啉酮衍生物及其它们的过渡金属配合物。

Two novel development accelerant s with function were synthesized from 6-amido-benzimid-azole, phenyl-hydrosulfuryl-triazole and ringy hydrazide. The structures were confirmed by IR, MS and elemental analysis.

以6-氨基苯并咪唑和苯基巯基三唑为吸附基团，以环状酰肼为显影促进基团，合成了两个新型功能性显影促进剂，其结构经IR，MS和元素分析确证。

Six derivatives of 4-phenyl-3-phenoloxymethyl-5-mercapto-1,2,4-triazlyole were synthesized from phenoloxyacetyl hydrazide by two-steps reaction under microwave irradiation, then reacted with 2-chloroacetic acid to give six novel derivatives of 2-(3-phenoxymethyl-4-phenyl-[1,2,4]triazole-5-thio)-acetic acid.

在微波辐射条件下，芳氧乙酰肼经两步反应制得4-苯基－3-芳氧甲基－1，2，4-三唑－5-硫酮衍生物，再与氯乙酸反应得到6种尚未见文献报道的2-（3-芳氧甲基－4-苯基－1，2，4-三唑－5-硫基）乙酸衍生物。

The trials were carried out in field experiment and artificial climate incubator. The sugar beet growth buds were treated at 1～3pairs of true leaves with gibberellin , autix , naphthaleneacetic acid and kinetin , and the plant growth regulating substances enhancing bolting of sugar beet in the first year and its doses were selected out. The sugar beet seedling induced by temperature and light were treated by abscisic acid , maleic hydrazide , uniconazole (S-3307) and paclobutrazol (PP333), and the plant growth regulating substances which make bolting reverse and their doses were screen out. The mechanisms of bolting and bolting reversing were discussed by examining the changes of endogenous hormones, activities of correlative enzyme to bolting, soluble protein, components of amino acid in the protein, components of fatty acid. The results were as follow

本研究通过田间试验和人工气候箱培养相结合的方法，在甜菜幼苗1~3对真叶时利用赤霉素、生长素、奈乙酸和激动素等生长调节物质处理茎生长点，筛选促进甜菜当年抽苔的植物生长物质及剂量；同时利用脱落酸、马来酰肼、烯效唑（S-3307）和多效唑（PP333）等处理经温光诱导当年抽苔的甜菜幼苗，筛选对当年抽苔逆转有效的种类和剂量，并通过测定内源激素含量、相关酶活性、可溶性蛋白质含量和氨基酸组分及脂肪酸含量及其组分的变化，探讨甜菜当年抽苔和抽苔逆转的机理，得到如下结论

Therefore the goal of this study was to determine the effect of fluconazole, clarithromycin, and rifabutin on sulfamethoxazole hydroxylamine formation in indiiduals with HI-1 infection.

因此此研究的目的是在HIV感染者中，检测氟康唑，克拉仙霉素，利福布汀对羟胺磺胺甲噁唑的形成的影响。

The synthesis, crystal structure and characterization of 4, 5-dimethyl-2-(2-pyridyl) imidazole were reported.

为了制备研究2-取代咪唑配合物，设计合成了4， 5-二甲基-2-（2-吡啶基）咪唑，用IR、MS、1H-NMR对其结构进行了确证，并对其晶体结构进行了分析。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。