咪唑基

Benzoin condensation using imidazolium based ionic liquids as solvent for the first time has been successfully achieved. The reaction conditions have been studied in detail. When under 65 and with 0.5 equiv. NaOH in ionic liquid l-butyl-3-methyl-imidazolium tetraborate, benzoin was obtained in excellent yield of 91%. Recycling of ionic liquid has been available.

首次探索并成功实现了在咪唑鎓盐离子液体中进行苯偶姻缩合反应，详细探讨了反应条件，当反应在65℃下和0.5当量NaOH存在下以及在离子液体4-丁基-1-甲基咪唑鎓四氟硼酸盐中进行时，苯偶姻产率可达91％；并对离子液体进行了有效回收再利用。

Finally, reacting II with PhNCO givethe compound 1-(6-nitrobenzimidazol-l-acetyl)-4-phenylsemicarbazide,III in the presence of〓 give the new cyclic compound 2-phenylamino-5-(6-nitrobenzimidazol- 1-methylene)-l,3,4-oxadiazole.

第三部分：以6-硝基苯并咪唑-1-乙酰肼为原料，分别与取代苯甲醛、苯乙酮及乙酰基二茂铁进行缩合反应，合成了10个新的6-硝基苯并咪唑-1-乙酰腙衍生物。

The synthesis, crystal structure and characterization of 4, 5-dimethyl-2-(2-pyridyl) imidazole were reported.

为了制备研究2-取代咪唑配合物，设计合成了4， 5-二甲基-2-（2-吡啶基）咪唑，用IR、MS、1H-NMR对其结构进行了确证，并对其晶体结构进行了分析。

Optimized geometries of these compounds show that they have not imaginary frequeneies, and they are stable on the potential energy surface. The results show that the ring of imidazole has some aromaticity.

基于自然键轨道理论和三维静电势图，分析了稳定结构的成键情况、咪唑环上的共轭性及硝基咪唑化合物的反应性。

The solubility and the dissolution rate of cellulose in two ionic liquids with different structure AMIMCl and BMIMCl were investigated.

测定了纤维素在不同结构的离子液体——1-烯丙基-3-甲基咪唑氯化物和1-丁基-3-甲基咪唑氯化物中的溶解度和溶解速率。

Replacement of one benzimidazole fragment with benzothiazole or benzoxazole and optimization of the structure to create the new frame of the compounds were also carried out with the exception to find more potent compounds. The purpose of design and synthesis of these compounds is to investigate the QSAR of this class of compounds with the inhibition of HCV NS3/NS4A protease and eventually to develop more potent inhibitors.

本文首次采用了丙二酰胺与邻芳二胺在微波辐射下制备对称性双芳并唑甲烷化合物、用芳并唑-2-乙酸乙酯与邻芳二胺在微波辐射下制备非对称性双芳并唑甲烷化合物、用4-取代噻唑-2-乙酸乙酯与邻芳二胺在微波辐射下制备非对称性(4-取代-噻唑-2-基)(1H-芳并咪唑-2-基)甲烷化合物等合成路线，共合成了48个目标化合物，其中41个为新化合物，用~1HNMR，ESI-MS，FT-IR，元素分析对这些化合物进行了全面表征，确定了这些化合物的结构，并对部分化合物进行了~(13)CNMR分析。

Based on the problem of various types of catalyst and according to the features of carbonylation catalysts reactions, our team has been designed a series of new metal complexes of benimidazoles, which can be used for carbonylation catalyst of industry. Seven new benzimidazole derivatives were prepared by the o-phenylenediamine、oxalic acid、glycolic acid、monomethyl monopotassium malonate、ethyl cyanoacetate、succinic anhydride. The structures of them were confirmed by IR、Elemental analsis. The crystal structures of d and e were determined by X-ray single crystal diffraction of Germanic Bruker Smart APEX II CCD. The catalysis of them was tested by carbonylation reactions.

本文设计以邻苯二胺和草酸、羟基乙酸、丙二酸单甲酯、氰基乙酸乙酯、丁二酸单甲酯为原料采用PPA催化和无机酸催化法，合成了4种苯并咪唑-2-羧酸衍生物并进行了表征；培养了2个化合物d、e的晶体并测定和讨论了晶体结构；制备了3种未见报道的苯并咪唑金属配合物，对配合物在羰基化法制醋酐-醋酸反应的催化作用进行了初步试验。

Methods Phenylacetaldehyde was prepared from benzimidazolium salt and benzyl chloride by the addition-hydrolysis reaction of benzimidazolium salt with Grignard reagent.

方法以苯并咪唑盐和苄基氯为原料，利用苯并咪唑盐与Grignard试剂的加成-水解反应合成苯乙醛。

By using 4-chloro-5-nitro phthalimide as raw material and through aminoysis, reduction, cyclization and hydrolysis, end-produce benzimidazole-5,6-diformic acid is prepared.

本发明公开了一种苯并咪唑－5，6－二甲酸的制备方法。该方法是以4－氯－5－硝基邻苯二甲酰亚胺为原料，依次经过氨解、还原、环合、水解反应过程，制得最终产品苯并咪唑－5，6－二甲酸。

Two new chiral imidazoles with big conjugate system were synthesized, that is,-1-(-methylbenzyl)-2-benzene-4,5-dibenzene-imidazole and-1-(-methyl benzyI)-2-styrene-4,5-dibenzene-imidazole, whose salifying conditions were also briefly investigated.

设计并合成了两个新的含有手性单元和较大共轭体系的多取代咪唑：-1--2-苯基-4，5-二苯基咪唑和-1--2-苯乙烯基-4，5-二苯基咪唑，并对其成盐反应和条件进行了一些初步研究。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。