咪唑基

Three new fluo-rine-containing nitro benzimidazole derivatives were synthesized in the presence of 4-dimethylaminepyridine andtheir structure and configuration were confirmed by elemental analysis, IR, and 1HNMR.

在碱性条件下由2-(4′-羟苯基)-5-取代苯并咪唑与氯乙酸作用得到5个新化合物取代苯并咪唑基苯氧乙酸。

Benzoin condensation reaction of benzaldehyde using simple imidazolium based ionic liquids as catalyst has been successfully achieved. The reaction factors such as solvent, base and ionic liquids have been studied in detail.

成功地实现了简单咪唑基离子液体对苯甲醛自缩合成苯偶姻的催化反应，以及详细探讨了溶剂、碱、离子液体种类及用量等各种影响因素。

The carboxylicgroup was not the necessary group. The presence of the imidazole group wouldenhance the cleavage activity.

羧基不是必需基团，咪唑基的存在可以使丝组二肽具有较高的切割活性。

The weight—average molecular weight and imidazole content of PBIOM were determined to be 3.4×105 and 57 mol ％ by GPC and elemental analysis,respectively.

合成的PBIOM重均分子量和咪唑基含量分别由GPC和元素分析方法测定，结果为3.4×105和57mol%。

1 To mimic the active centers of tyrosinate iron enzymes whichcontain phenolate donors, new tripodal ligand, N-(2-hydroxybenzyl)-N, N-bis(2-benzimidazolymethyl) aminewhich contain imidazoleand phendate groups were designed and synthesized and its iron com-plexes 〓(2)(where Mim=N-Methylimidazole) and Fe 〓(3) were prepared andcharacterized by various spectroscopic methods.

1.1 为了模拟酪酸铁酶活性中心，设计并合成了含有酚羟基和苯骈咪唑基四齿配体N，N-(2-羟基苯)-N，N-二氨，并合成它的铁配合物：Fe〓、Fe〓〓(2)和Fe〓，并经各种谱学手段表征了这些铁配合物。

In this dissertation, synthesis of benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene]dichlororuthenium (41) has been improved.

本论文首先改进了钌卡宾配合物[1，3-二-(2，6-甲苯基)-4，5-二氢咪唑基]-苯亚甲基-三苯基膦-二氯合钌(41)的合成方法。

Using Gassian98 with LANL2DZ basis sets, the quantum chemistry calculation of the model was performed.4. A series of ligands which all include imidazolyl group were designed and synthesized. The crystal structure of one of them was determined by X-ray diffraction.

设计并合成了一系列含有咪唑基的配体，应用X-射线衍射方法测定了其中一种配体的晶体结构，并用Gaussian98程序包进行了量子化学计算。

Isoflavone; imidazole; imidazolyl isoflavone derivatives; microwave-mediated synthesis; antioxidative activity

工程科技I，化学，有机化学异黄酮；咪唑；咪唑基异黄酮衍生物；微波合成；抗氧化活性

Eight kinds of 2-benzimidazolylalkylene derivatives in polyphosphoric acidhave been synthesized by multi-power bands microwave irradiation technique,starting from corresponding cinnamic acid compounds and they were characterized by~1H NMR,(~13C NMR and MS respectively.

以8种肉桂酸衍生物和邻苯二胺为原料，在多聚磷酸中，采用分段式微波辐射方法合成了8种2-苯并咪唑基烯烃衍生物，并通过1H NMR、13C NMR和MS进行了表征。

But the electrochemical results show that complexes exhibitcompletely irreversible redox behaviour which is different from thatfound in diiron proteins. 1.3 To obtain the diiron species which are stable to elec-trochemical reduction, a series of new tetranuclear cage ironspecies containing two 〓 cores, with using hexadentatepolybenzimidazole ligands, were synthesized and characterized by vari-ous spectroscopic methods. Their physical properties have been investi-gated. The crystal structures of 〓〓tetrakis (benzimidazol-2-ylmethyl)-1, 4-diaminobutane and 〓,〓-tetrakis ( N-ethylbenzimidazol-2-ylmethyl )-1, 4-diaminobutane were determined. They contain two 〓 cores which arelinked to each other by -〓-chain in the ligands.

1.3为了获得电化学还原稳定双核氧桥联Fe化合物，使用六齿配体合成了一系列含有两个〓单元四核笼状化合物，并用各种谱学手段表征了它们，还研究了它们的物理化学性质确定了〓L=N，N，N'，N'-四(苯骈咪唑基-1，4-丁二胺和〓，〓四-1，4-丁二胺化合物的晶体结构，它们含有两个〓单元，其中两个〓单元是通过配体的〓链桥联成四核笼状结构。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。