咪唑基

Deoxybenzoin(3) was prepareded by using the resorcinol and substituted phenylacetic as starting meterials in microwave-mediated.Then the compound(3) was reacted with acetic anhydride to produce(4).The compound(4) was hydrolyzed to convert compound(5) in the acid-mediated. The compound(5) was reacted with the 1,2-dibromo-ethane and 1,3-dibromo-propane in refluxed condition with acetone as solvent to give(6) or(7),respectively.Lastly,the title compounds were synthesized by refluxing(6) or(7) with 2-methyl-benzimidazole and potassium carbonate in acetone solution.

以取代苯乙酸和间苯二酚为起始原料，用微波辐射法合成脱氧安息香(3)，(3)与乙酸酐缩合生成2-甲基-7-乙酰氧基异黄酮(4)，(4)在酸性条件下水解生成相应的异黄酮(5)，化合物(5)分别与1，2-二溴乙烷和1，3-二溴丙烷反应生成(6)和(7)，化合物(6)和(7)再分别与2-甲基苯并咪唑偶合生成目标化合物。

The dependence of the radiolabeling yield of ~99mTcO-NIET and 99mTcN-NIET on pH, temperature, ligand concentration, the amount of added stannous chloride, and so on was screened by the normal procedure.

合成了一种新的氨荒酸类化合物，2-（4-硝基咪唑）-乙基二硫代氨基甲酸钾，研究了影响99mTcO-NIET以及99mTcN-NIET标记率的相关因素。

In addition, we have discovered a new reaction, it is that Dy/SiCl_4 can promote imines to give imidazolidines and tetrasubstituted hydrazines.

Dy／SiCl_4体系具有另外一个重要特性，就是我们发现它能够促进亚胺一步生成五取代的咪唑烷和四取代的肼，这是用其它自由基或直接用稀土金属和亚胺反应无法得到的。

Nickel sulfate was the most frequent sensitizer, followed by Thimerosal, Potassium dichromate, Fragrance mix and Formaldehyde. Frequencies of contact allergy to Thiuram mix, Mercapto mix, Imidazolidinyl urea, and bronopol were relatively low.

结果： 1 129 例受试者中，阳性反应747例，阳性反应率较高的变应原依次是：硫酸镍、硫柳汞、重铬酸钾、芳香混合物、甲醛，阳性反应率较低的变应原有：秋兰姆混合物、硫氢基混合物、咪唑烷基尿素、溴硝丙二醇。

The Beckmann rearrangement of cyclohexanone oxime was effectively realized to prepare e-caprolactam by using phosphorous trichloride (PCl3) as catalyst in a two-phase system composed of 1-n-butyl-3- methylimidazolium tetrafluoroborate ([BF4]) ionic liquids and toluene.

在1丁基3甲基咪唑四氟硼酸盐([BF4])与甲苯组成的两相体系中，以三氯化磷(PCl3)为催化剂，实现了由环己酮肟制备己内酰胺的液相贝克曼重排反应，两相体系有利于反应控制和体系取热。

Secondly, the syntheses of functionalized macrocyclic polyamine complexes containing nucleobases, PNA monomer, imidazolium side, crown ether, ferrocenyl side and their interaction with DNA were studies, respectively.

在功能化大环多胺方面，我们合成了含有碱基、PNA单体、咪唑鎓盐、冠醚、二茂铁等功能化基团的大环多胺衍生物及金属配合物，并研究了其与DNA的相互作用。

In this process, we have discovered a novel N-methylimidazole catalyzed two-component reaction. Dimethyl- and- succinates can be synthesized in moderate yields under mild conditions.

研究中，我们首先发现了一个新的N-甲基咪唑催化的DMAD与原位产生的单取代烯酮的二组分反应，在温和的条件下以中等收率合成了-型和-型的取代亚苄基琥珀酸二甲酯。

Three phosphorus-containing polybibenzimidazoles, namely, poly [2,2'-di-p-phenylene methyl phosphine oxide-5,5'-bibenzimidazole], have been prepared by condensing 3,3'-diaminobenzidine with di-(p-carboxy phenyl) methyl phosphine oxide.

用双烷基氧膦与3，3'-二氨基联苯胺缩聚，合成了三个在主链上带有联苯并咪唑和氧化三烃基膦结构的高分子化合物。

With the aid of 〓P NMR examination for the process and ESI-MS/MS analysis of the derivatized products from the reaction intermediate, it is found that the corresponding phosphoryl chloride is generated after mixing the hydrogen phosphonate derivative with chlorodiisopropylamine, and they react with amino acid, amino acid methyl ester, dipeptide methyl ester or N-methyl imidazole carboxyl alkyl diamine respectively to form the desired products.

利用〓P NMR对反应过程监测以及对反应中间体衍生化后产物的ESI-MS／MS检测分析发现，氢亚磷酸二酯与氯代二异丙胺反应首先生成了磷酰氯中间产物，它继续与氨基酸、氨基酸甲酯、二肽甲酯、1-甲基咪唑-2-酰基烷基二胺等反应生成了目标产物。

Dialkyldimethyl quats,and imidoamine quats are still quite popular in the United States,South America,and Asia.

在织物柔软剂的原料中，双烷基二甲基季铵盐，酰胺基二甲基硫酸甲酯季铵盐，以及含咪唑啉的季铵盐在美国、南美和亚洲等地仍然很流行。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。