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In addition, the stability of ternary Cu 〓complexes polypyridyl=1, 10-phenanthroline (Phen , pyrido [3, 2-f] [1, 7] phenanthroline , 1, 4, 8, 9-tetraazatriphenylene , dipyrido [3, 2-a: 2'3'-c] phenazine , imidazo phenanthroline and 2-phenylimidazo phenanthroline , NTP=ATP and UTP was studied by potentiometric pH titration in water at temperature 15℃, 25℃ and 35℃, and in 30% and 50% aqueous dioxane solution at 25℃.

另外,用pH电位滴定法研究了多吡啶芳香配体polypyridyl配合物Cu〓(PL=1,10-邻菲咯啉、吡啶并[3,2-f][1,7]邻菲咯啉、1,4,8,9-四氮三联苯、二吡啶并[3,2-a∶2'3'-c]吩嗪和2-苯基咪唑并邻菲咯啉或咪唑并邻菲咯啉)在不同温度(15℃、25℃和35℃)水溶液及30%和50%二氧六环-水混和溶剂(25℃)中的稳定性。

It is found that the corrosion inhibition rates come to 91.55% when the proportion of imidazoline and diethyl phosphite is 2:1, which meets the requirements of corrosion inhibition.

经过对咪唑啉和亚磷酸二乙酯这两种环烷酸缓蚀剂在不同配比下复配的评价,得出:在咪唑啉和亚磷酸二乙酯2:1配比时,缓蚀速率为91.55%,达到缓蚀的要求。

However, in the case of bis (trifluoromethyl sulfonyl amide, more complicated tribochemical reaction occurred during friction process with the formation of FeS as well as organic and inorganic fluoride.

XPS研究表明,在摩擦过程中,烷基咪唑氟硼酸盐离子液在钢/钢摩擦副表面形成FeF〓和B〓O〓;烷基咪唑六氟磷酸盐离子液在摩擦过程中形成了FeF〓和FePO〓,而二胺盐发生了复杂的摩擦化学反应,有氟化物和FeS形成。

Levamisole hydrochloride, the ramification of imidazole, is a broad-spectrum medicine against wireworm.

本论文所研究的盐酸左旋咪唑,又名驱虫净,是咪唑的一个衍生物。

Benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene]dichloro(2-methylpyridine)ruthenium (62), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] dichloro(2,4-dimethylpyridine)ruthen ium (63) introduce ortho substituted pyridine as dissociating ligand to weaken Ru-N bondand accelerate dissociation of pyridine derivative ligand through steric hindrance.

在钌卡宾配合物[1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基]-苯亚甲基-(2-甲基吡啶)-二氯合钌(62),1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基1-苯亚甲基-(2,4-二甲基吡啶)-二氯合钌(63)中,邻位取代的吡啶作为解离配体,通过邻位基团的空间效应削弱钌-氮配位键,使配体更易解离,提高了催化剂的初活性。

Based on the problem of various types of catalyst and according to the features of carbonylation catalysts reactions, our team has been designed a series of new metal complexes of benimidazoles, which can be used for carbonylation catalyst of industry. Seven new benzimidazole derivatives were prepared by the o-phenylenediamine、oxalic acid、glycolic acid、monomethyl monopotassium malonate、ethyl cyanoacetate、succinic anhydride. The structures of them were confirmed by IR、Elemental analsis. The crystal structures of d and e were determined by X-ray single crystal diffraction of Germanic Bruker Smart APEX II CCD. The catalysis of them was tested by carbonylation reactions.

本文设计以邻苯二胺和草酸、羟基乙酸、丙二酸单甲酯、氰基乙酸乙酯、丁二酸单甲酯为原料采用PPA催化和无机酸催化法,合成了4种苯并咪唑-2-羧酸衍生物并进行了表征;培养了2个化合物d、e的晶体并测定和讨论了晶体结构;制备了3种未见报道的苯并咪唑金属配合物,对配合物在羰基化法制醋酐-醋酸反应的催化作用进行了初步试验。

Methods Glutaric dialdehyde was prepared from benzimidazolium salt and saturated dihalide by the addition-hydrolysis reaction of benzimidazolium salt with Di-Grignard reagent.

方法以苯并咪唑盐和二卤代烷为原料,利用苯并咪唑盐与双Grignard试剂的加成水解反应合成戊二醛。

A bis-imdazoline corrosion inhibitor JUC was synthesized by reacting with divinyl three amine,and its quaternary ammonium JUCI was also synthesized for corrosion inhibition in acids.

以己二酸、二乙烯三胺为原料合成了双环咪唑啉缓蚀剂JUC,并对其季铵化后得到了适于酸化用的双环咪唑啉季铵盐缓蚀剂JUCI;采用静态挂片失重法对合成的缓蚀剂在酸化条件下的缓蚀性能及与非离子表面活性剂SA-1复配后的缓蚀性能进行了评价研究。

Anti-benzimidazole eggs of Haemonchus contortus were collected with saturated salt and sugar solutions,respectively. The egg hatch test in vitro of H.contortus was carried out in different concentrations of benzimidazole solutions for different preservative periods.

用饱和盐水、饱和糖水漂浮法获得抗苯并咪唑的捻转血矛线虫虫卵,在实验室进行了在不同浓度的苯并咪唑药液中保存不同时间的虫卵发育试验。

One class is CAAX-mimetic compounds with an imidazolyl residue on one end and a carboxylic group on the other connected by benzodiazepine scaffold at different positions.

连有咪唑基的苯并二氮杂草化合物,以苯并二氮杂草-2-酮为分子骨架,7位连接含有咪唑基的侧链,1位或3位连接含羧基或酯基的侧链。此类化合物模拟了CAAX配体。

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