咪唑

Benzoin condensation using imidazolium based ionic liquids as solvent for the first time has been successfully achieved. The reaction conditions have been studied in detail. When under 65 and with 0.5 equiv. NaOH in ionic liquid l-butyl-3-methyl-imidazolium tetraborate, benzoin was obtained in excellent yield of 91%. Recycling of ionic liquid has been available.

首次探索并成功实现了在咪唑鎓盐离子液体中进行苯偶姻缩合反应，详细探讨了反应条件，当反应在65℃下和0.5当量NaOH存在下以及在离子液体4-丁基-1-甲基咪唑鎓四氟硼酸盐中进行时，苯偶姻产率可达91％；并对离子液体进行了有效回收再利用。

Finally, reacting II with PhNCO givethe compound 1-(6-nitrobenzimidazol-l-acetyl)-4-phenylsemicarbazide,III in the presence of〓 give the new cyclic compound 2-phenylamino-5-(6-nitrobenzimidazol- 1-methylene)-l,3,4-oxadiazole.

第三部分：以6-硝基苯并咪唑-1-乙酰肼为原料，分别与取代苯甲醛、苯乙酮及乙酰基二茂铁进行缩合反应，合成了10个新的6-硝基苯并咪唑-1-乙酰腙衍生物。

The synthesis, crystal structure and characterization of 4, 5-dimethyl-2-(2-pyridyl) imidazole were reported.

为了制备研究2-取代咪唑配合物，设计合成了4， 5-二甲基-2-（2-吡啶基）咪唑，用IR、MS、1H-NMR对其结构进行了确证，并对其晶体结构进行了分析。

Optimized geometries of these compounds show that they have not imaginary frequeneies, and they are stable on the potential energy surface. The results show that the ring of imidazole has some aromaticity.

基于自然键轨道理论和三维静电势图，分析了稳定结构的成键情况、咪唑环上的共轭性及硝基咪唑化合物的反应性。

Secondly, through the filariasis immune experiment, people improve that the skin is wiped with the levamisole liniment at regular intervals instead of preparing the bacterin for inoculability, levamisole actions of resisting the virus and infection are exerted without the disease when inoculating the pathogeny, and the specificity immune protection is obtained under the pathogeny action, the immune preventive intention is reached just as injecting the bacterin.

二是，经丝虫病免疫实验证实，不用制苗接种，通过左旋咪唑搽剂定期皮肤涂药，在接种病原时，发挥左旋咪唑抗病毒、抗感染作用而不发病，并在病原作用下，获得特异性免疫保护，就像注射疫苗一样达到免疫预防的目的。

The solubility and the dissolution rate of cellulose in two ionic liquids with different structure AMIMCl and BMIMCl were investigated.

测定了纤维素在不同结构的离子液体——1-烯丙基-3-甲基咪唑氯化物和1-丁基-3-甲基咪唑氯化物中的溶解度和溶解速率。

In the meantime, we proposed a mechanism for this catalytic reaction. According to the possible formation of intermediate B, we designed a disubstituted ketene of more function to re-capture the zwitterion.

在同位素标记基础上，我们推测了这个N-甲基咪唑催化的二组分反应可能的机理，并根据此机理设计用一个二取代的烯酮来捕捉N-甲基咪唑和DMAD形成的两性离子。

The better technology has been obtained: taking water-EG as solvent 2-imidazolidinone was prepared. The molar ratio of the methanal (36%) to the formic acid (85%) is 1:2.8, reaction temperature is 95~100℃, reaction time is 16 h, taking cuprous chloride and triethylamine as catalyst, the molar ratio of the cuprous chloride and triethylamin to 2-imidazolidinone is 1.0% while 1,3-DMI was prepared.

较佳工艺条件为：制备2-咪唑啉酮时，以水－乙二醇混合作溶剂；制备1，3-DMI时，甲醛(36%)：甲酸(85%)摩尔比为1：2.8，反应温度95~100℃，反应时间16 h，氯化亚铜和三乙胺作催化剂，用量分别是2-咪唑啉酮摩尔数的1.0%。

Main products include: 1,3-dimethyl-2-imidazolone, also named dimethyl-ethenylurea, 1,3-Dimethyl-2-imidazolone、1,3- Dimethyl-3,4,5,6- four hydrogen-2-pyrimidone, 2-imid-azolidinone、methane acid amine,、pyridylmethanol、pyridylaldehyde、50% methane acid,etc series products.

公司主营：1，3-二甲基-2-咪唑啉酮，又称二甲基乙烯脲，1，3-Dimethyl-2-imidazolinone、1，3-二甲基-3，4，5，6-四氢-2-嘧啶酮、 2-咪唑啉酮、甲酸胺、吡啶甲醇、吡啶甲醛、50%甲酸等系列产品。

Main products include: 3-Dimethyl-2-imidazolidinone, also named dimethyl-ethenylurea, 3-Dimethyl-2-imidazolidinone、1,3- Dimethyl-3,4,5,6- four hydrogen-2-pyrimidone, 2-imid-azolidinone、methane acid amine,、pyridylmethanol、pyridylaldehyde、50% methane acid,etc series products.

公司主营：1，3-二甲基-2-咪唑啉酮，又称二甲基乙烯脲， 1， 3-Dimethyl-2-imidazolidinone、1，3-二甲基-3，4，5，6-四氢-2-嘧啶酮、 2-咪唑啉酮、甲酸胺、吡啶甲醇、吡啶甲醛、50%甲酸等系列产品。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。