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With two tripodal ligands, dtma and tmpa, dtma=diethylenetriamine-N'-acetate and tmpa=tris(2-pyridyl-methylamine and a polyamine ligand, trien (=triethylenetetramine), serving as terminal ligands, we synthesized 19 species of new imidazolate -bridged Cu-Zn, Zn-Zn and Cu-Cu, and other relating compounds, in which 〓 and 〓 complexes are model compounds of Cu, Zn-SOD.

用不等臂三脚架dtma(diethylenetriamine-N'-acetate)、直链trien和等臂三脚架tmpatris(2-pyridyl-methyl-amine为配体,合成了一系列咪唑桥联Cu-Zn、Zn-Zn和Cu-Cu等有关19个新化合物,其中两个异双核〓Cu〓和〓〓配合物为Cu,Zn-SOD活性中心的模型化合物。2。

As CAAX-mimetics, 1, 3-dihydro-5-phenyl-2-H-1, 4-benzodiazepin-2-one was modified by linking carboxyl groups with various carbon through N-1 and C-3, 3-(imidazol-4-yl) propion amido group with different substituents was connected at C-7; In the synthesis of bisubstrate analogues, thiocarbamido compounds was alkylated by alkyl iodide and then hydrolyzed to give alkylthiol benzoate compounds.

1,4-苯并二氮杂草-2-酮类化合物的合成过程中分别对其1、3、4和7位进行了基团变化,在1和3位连接不同长度含羧基或酯基的侧链,在7位连接不同取代的咪唑丙酰氨基。在苯甲酸硫醇酯化合物合成过程中,建立了一种硫原子连有不同长度碳链的苯甲酸硫醇酯的合成方法。

Methylimidazole in soy sauce was extracted with methylene chloride,diazotized to forms a red colored azo-compound with the highly absorbance at the wave length of 440nm and determined by ultraviolet-visible spectrometry.

酱油样品在层析柱中用二氯甲烷洗脱,经重氮化后在波长440nm处具有最大吸收,据此建立了紫外可见光谱法测定酱油中4-甲基咪唑的方法。

Chapter V: A 1-D Zn coordinatin polymers is synthesized by the reaction of sodium azide, nicotinic acid and zinc chloride. A 3-D Ag supramolecular complex is synthesized by the reaction of sodium azide, 2-methylimidazole and silver chloride.

第五章:采用叠氮为基本构建单元,和烟酸共同桥联金属Zn得到一种一维链状配位聚合物;和2-甲基咪唑反应,得到一种银的三维超分子配合物。

The application of midazolam is effective on anti-axiety, sedation and anterograde amnesia in orthopaedic surgery with epidural block and the dose of 0.075mgkg^(-1) is more effective and safe.

咪唑安定应用于硬膜外麻醉下行骨科手术的抗焦虑、镇静及顺行遗忘效果好,按0.075mgkg^(-1)给药效果满意且安全性高,不良反应少。

In addition, the application of the RTILs (BF4, PF6) in the Beckmann rearrangement have been firstly studied. On the conditions of the reducing the oil of vitriol, the effects of the two RTILs in the Beckmann rearrangement have been reviewed and contrast experiment.

另外,首次将咪唑类离子液体应用于Beckmann重排反应体系,考察了在减少发烟硫酸用量的情况下,两种离子液体对Beckmann重排反应的影响并做了空白实验。

The Beckmann rearrangement of cyclohexanone oxime was effectively realized to prepare e-caprolactam by using phosphorous trichloride (PCl3) as catalyst in a two-phase system composed of 1-n-butyl-3- methylimidazolium tetrafluoroborate ([BF4]) ionic liquids and toluene.

在1丁基3甲基咪唑四氟硼酸盐([BF4])与甲苯组成的两相体系中,以三氯化磷(PCl3)为催化剂,实现了由环己酮肟制备己内酰胺的液相贝克曼重排反应,两相体系有利于反应控制和体系取热。

Photosensitizer rose bengal reacts with O 2 to generate singlet oxygen ( 1O 2) under illumination .

光敏剂RB在光照射下与O2反应产生1O2,1O2与组氨酸或咪唑反应的中间产物使RNO发生氧化,导致RNO在440nm处吸光度减小,此即为RNO脱色反应。

Secondly, the syntheses of functionalized macrocyclic polyamine complexes containing nucleobases, PNA monomer, imidazolium side, crown ether, ferrocenyl side and their interaction with DNA were studies, respectively.

在功能化大环多胺方面,我们合成了含有碱基、PNA单体、咪唑鎓盐、冠醚、二茂铁等功能化基团的大环多胺衍生物及金属配合物,并研究了其与DNA的相互作用。

In this test, metabolites and enzyme activities involved in energy metabolism in Cysticercus cellulosae were determined systematicly in vivo and in vitro and under action of drugs.The principles of variation of energy metabolism in Cysticercus cellulosae and mechanism of action of the benzimidazol carbamate drugs were illustrated so as to select an effective drug against immature and mature cysticerci and to provide a theoretical and experimental chemotherapy.

本研究首次系统地测定了体内发育过程中、体外培养条件下及抗囊药物作用下猪囊尾蚴能量代谢的有关物质含量和酶活性的变化,阐明了猪囊尾蚴的能量代谢变化规律和苯并咪唑氨基甲酸酯类药物作用机理,为筛选有效的抗囊药物以及为药物治疗提供了重要的实验和理论依据。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。