咪唑

The chapter 1 introduces the background of imidazole, thiazole, tetrazole derivatives and their glycosides, and organic solid phase research.

论文第一章介绍了咪唑环、噻唑环、四氮唑环等杂环的合成，总结了糖苷的合成方法，对杂环的固相合成化学进行了简单介绍。

The synthesis of thiazole ,imiadzole,oxazole and their derivatives were stress introduced.

综述了近几年来五元杂环化合物的研究进展，重点介绍了噻唑、咪唑、唑等衍生物的合成进展，并展望了这3类衍生物的发展前景。

Author had started the research on design and synthesis of heterocycles several years ago, mainly focused on the design and synthesis of imidazole, thiazole, tetrazole derivatives and their glucosides, in which most of them may have some particular bioactivities.

本论文主要是围绕具有生理活性含氮杂环化合物的设计与合成而展开的，在论文工作中我们应用液相"一锅法"和固相组合化学方法进行了咪唑环、噻唑环、四氮唑环等具有生理活性的杂环化合物及其糖苷的合成。

The chapter 6 makes a study on the design and synthesis of new glycosides, which prepared from imidazole, thiazole and tetrazole aglycones mentioned above and glucose derivatives by phase transfer catalysis under the moderate reaction condition.

我们以合成的新杂环化合物作为糖的配基，用相转移催化法合成了25个糖苷类化合物。其中包括4个咪唑氮糖苷，12个含有噻唑环的糖苷，6个含有噻唑环的糖酯，3个四氮唑糖苷。

The benezothiazolocoumarin dyes substituted with chlorine on 5'-position also showed bathochromic shift of the maximum absorption and fluorescence emission.

这9只染料用於涤纶染色有很好的应用性能，差别不大；恶唑环结构和喹唑酮结构的染料耐光牢度明显好於噻唑环结构和咪唑环结构的染料。

We firstly introduced benzoazole (including benzimidazole, benzoxazole and benzothiazole) into the meso-positions of porphines and obtained five new porphyrins 36a-e. Their structures were characterized by 1H NMR, MS, UV-vis spectra and fluorescence emission spectra.

将苯并唑类基团(苯并咪唑、苯并噁唑和苯并噻唑)引入到卟吩中位，得到5个新型卟啉36a-e衍生物，并经核磁氢谱、质谱、紫外吸收光谱和荧光发射光谱表征了化合物的结构。

An inclusion complex -BINOL--Omeprazole or -BINOL--Omeprazole was first obtained from racemic omeprazole with chiral host --or --2, 2'- dihydroxy-1, 1'-binaphthyl in high selectivities, and thus both optically pure enantiomers of omeprazole were prepared as syrup with more than 99% enantiomeric excess, the overall yields of both two enantiomers are more than 60%.

首次发现光学纯R--或s--联二萘酚高效识别并包结R--或S--奥美拉唑，形成包结络合物的现象，并首次将包结拆分法应用于手性苯并咪唑类抗溃疡药物的制备，用一种构型的光学纯联二萘酚直接拆分奥美拉唑，可同时得到油状或糖浆状e.e。

Aqua, Sorbitol, PPG-1 PEG-9 Lauryl glycol ether, Hydrolyzed elastin, Hydrolyzed wheat gluten, Hydrolyzed collagen, Hydrolyzed glycosamino-glycans, Humulus lupulus, Propylene glycol, Triethanolamine, Sodium hydroxide, Carbomer, Maris limus extract, Ostrea extract, Imidazolidinyl urea, Parfum, Benzyl salicylate, Coumarin, Alpha isomethyl ionone, Hexyl cinnamal, Buthylphenylmethylpropionate, Linalol, Methylisothiazolinone, Methylchloroisothiazolinone.

水，山梨醇， PPG 公司- 1聚乙二醇- 9十二烷基醇醚，水解弹性蛋白，水解小麦面筋蛋白，水解胶原蛋白水解粘多糖，多聚糖，啤酒花提取物花，丙二醇，三乙醇胺，氢氧化钠，卡波姆，马里斯提取物，牡蛎提取物，咪唑烷基脲，香水，水杨酸苄酯，香豆素，阿尔法 l 紫罗兰酮，己基肉桂醛，丁苯基甲基丙醛，芳樟醇，甲基异噻唑啉酮，甲基氯异塞唑晽酮。

Starting with two reactive methylene compounds, ethyl cyanoacetate and malononitrile, two 5-amino-1H-pyrazoles were prepared through the intermediates ketene dithioacetal.

从两个活泼亚甲基化合物开始，经过乙烯酮二硫代缩醛中间体，合成了两个5-氨基-1H-吡唑，以这个两个化合物为中间体，与芳香族和脂肪族α-溴代酮反应，而后经酸催化亚胺化互变异构后得到含咪唑并[1，2-b]吡唑甲硫醚类化合物6a-6g。

Author had started the research on design and synthesis of heterocycles several years ago, mainly focused on the design and synthesis of imidazole, thiazole, tetrazole derivatives and their glucosides, in which most of them may have some particular bioactivities.

本论文主要是围绕具有生理活性含氮杂环化合物的设计与合成而展开的，在论文工作中我们应用液相&一锅法&和固相组合化学方法进行了咪唑环、噻唑环、四氮唑环等具有生理活性的杂环化合物及其糖苷的合成。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。