和硫

Four extracting agents for Lanthanides/Actinides separation , dialkyldithiophosphinic acids, were synthesized from PSCl3 and alkyl halide by Grignard reaction, sulfuration and acidification.

以PSCl3和卤代烷为原料，经格氏反应、硫化和酸化合成了用于镧/锕分离的4个萃取剂——二烷基二硫代次膦酸，其结构经NMR，IR和MS表征。

Using mordern physical chemistry techniques (such as XRD、 TG-DTA、 IR、 XPS and 〓Xe-NMR)、 chemical adsorption techniques (NH〓-TPD、 H〓-TPD、 TPO、 TPR etc.) and pulse flow microreaction of n-hexane、 methylcyclopentene and n-hexane containing 0.2ppm thiophene, we studied mainly the following three points:(1). the changes occured during the calcination pretreatment of Pt ammine complex supported on β and L zeolites;(2). the effect of structure and acidity-basicity of zeolite on the dispersion and electron state of Pt particles; and (3). the influence of second metal component on the reactivity of nhexane aromatization and sulphur-resistance of Pt/L zeolite catalyst. Several interesting and valuable results are obtained and summerized as follows

本论文运用各种近代物理表征方法(XRD、BET、TG-DTA、IR、XPS和〓Xe-NMR)、化学吸附技术(NH〓-TPD、H〓-TPD、TPO、TPR等)和正己烷、甲基环戊烷及含噻吩正己烷的脉冲微反等方法，着重研究了(1)载Pt的β和L沸石在分解预处理过程中发生的变化；(2)沸石载体结构及酸碱性对Pt粒子分散及电子状态的影响；(3)第二金属组份对载Pt沸石催化剂上正己烷芳构化及抗硫性能的影响等，得到了某些有意义的结果。

Research on techniques for the synthesis of ACR impact modifier with core-shell structure;2. Preparation of polymer-tungsten-silica composite microspheres with multi-layer core-shell structures;3. Organosilicon-acrylate micro emulsion with core-shell structure was synthesized with OP-10,JFC and amyl alcohol nonionic compounded emulsifier by means of seeded emulsion polymerization.

运用种子乳液聚合工艺以OP-10/JFC/戊醇非离子复合乳化剂合成了具有核-壳结构的有机硅-丙烯酸酯微乳液，研究了复合乳化剂类型、丙烯酸酯单体、有机硅单体加入方式和含量、pH值、硫醇对微乳液聚合过程中稳定性和光泽度的影响，通过差示扫描量热仪和透射电镜对微乳液的结构进行了表征。

Organosilicon-acrylate micro emulsion with core-shell structure was synthesized with OP-10,JFC and amyl alcohol nonionic compounded emulsifier by means of seeded emulsion polymerization.

运用种子乳液聚合工艺以OP-10/JFC/戊醇非离子复合乳化剂合成了具有核-壳结构的有机硅-丙烯酸酯微乳液，研究了复合乳化剂类型、丙烯酸酯单体、有机硅单体加入方式和含量、pH值、硫醇对微乳液聚合过程中稳定性和光泽度的影响，通过差示扫描量热仪和透射电镜对微乳液的结构进行了表征。

As a result of recent world-widediscussions on the possible harmfulness of sulphites, theJoint FAO/WHO Expert Committee on Food Additives has assessed the intake of sulphur dioxide andrelated compounds, suchas calcium, potassium andsodium hydrogen sulphite; calcium, potassium and sodiummetabisulphite; calcium, potassium and sodium sulphite;and sodium thiosulphate.

由於最近全世界关於硫化物的可能的有害，在食品添加剂的联接FAO/WHO专家委员会的讨论估计了二氧化硫入口和相关化合物， suchas钙，钾和钠氢硫化物；钙、钾和钠偏亚硫酸氢盐；钙、钾和亚硫酸钠；并且钠硫代硫酸盐。

Base on the analysis, organophosphate inducible system has been established by treatment of the swimming seedling and drenching roots with organophosphate solution. This inducible system consists of model plant Arabidopsis thaliana and methamidophos, folimat or methyl parathion which are the representative types of highly toxical OPs. Meanwhile, the responses of the esterase isozymes and the total soluble proteins to OPs in Arabidopsis thaliana have been detected by Native-PAGE and SDS-PAGE.

在此基础上，采用模式植物拟南芥和甲胺磷、氧化乐果和甲基对硫磷三种极具代表性的高毒高残留有机磷农药，通过水培和灌根的方法，建立了有机磷诱导系统，并应用变性与非变性聚丙烯酰胺凝胶电泳技术，研究了拟南芥酯酶同功酶和可溶性总蛋白对有机磷胁迫的响应。

Since H〓S and SO〓 adsorbed on TiO〓 could react with each other and TiO〓 is the medium of their electron transfer, thus SO〓 could not be adsorbed quite strong on the active site of TiO〓, which makes it more resistant to sulfating and increase the stability of catalyst. Finally, the model and mechanism of the reduction of SO〓 by NH〓 to elemental sulfur is advanced as follows: on the sulfide catalyst, ammonia is decomposed to N〓 and H〓, and H〓 reacts with SO〓 to form the intermedium of H〓S; then H〓S and SO〓 react as Claus reaction on TiO〓 catalyst.

反应系统中过量水蒸气的存在使催化剂表面某些活性位被水蒸气抑制使活性和选择性有较大幅度降低，但这种影响是可逆的，不会造成催化剂永久性中毒；另外当单质硫和水蒸气同时存在时，在〓催化剂上能够生成硫化氢和二氧化硫，而且由于硫化氢和二氧化硫化学吸附能力不同而导致它们的脱附顺序不同，硫化氢的生成温度总是低于二氧化硫的生成温度，说明过量水蒸气的存在会导致氧化物催化剂上逆克劳斯反应的发生；而在硫化物催化剂上几乎没有硫化氢和二氧化硫生成，说明硫化物催化剂能够抑制逆克劳斯反应的发生。

Calcium unites with sulphur and oxygen to form calcium sulphate, and phosphors and oxygen to form calcium phosphate, sodium and potassium unite with oxygen and nitrogen to form sodium to potassium nitrates.

钙、硫和氧形成硫酸钙，钙、磷和氧形成磷酸钙，钠、钾和氧、氮结合生成硝酸钠和硝酸钾。

The picrites have low Re and high Os concentrations, which are probably controlled by the degree of partial melting and crystallization fractionation. The low Re ,Yb and Re/Os ratios of the picritic lavas support models of high degree partial melting with residual garnet in their mantle source during the early stages of partial melting, and without residual sulphide.

木里地区苦橄岩具有低的Re含量和高的Os含量，Re和Os的含量受到熔融程度和结晶分异的控制，低的Re和Os的含量和Re／Os，以及高的Os含量支持高程度的地幔熔融导致熔体中的硫不饱和，同时源区可能有石榴子石残留。

Results SDS-PAGE and western blot results show that approximately 45 kDa and 39 kDa proteins were expressed by pet22-srtA and pTRX-srtA respectively. The molecular chaperone thioredoxin was beneficial to the prokaryotic expression of srtA gene.

利用SDS-PAGE和western blot进行鉴定和分析，结果显示：(1)重组载体pet22-srtA和pTRX-srtA分别表达出相对分子量为约45 kDa和39 kDa的外源蛋白；（2）分子伴侣硫氧还蛋白有利于分选酶A基因的可溶性表达。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。