和硫

The chemical deposition method was applied to prepare bismuth sulfide through reaction of bismuth salt complexed by triethanolamine or EDTA with an aqueous solution containing a sulfur sourse such as thioacetamide, thiourea, sodium thiosulphate, geseous H2S.

化学淀积方法被提出申请准备硫化铋经过被和一个水溶液的三乙醇胺或乙二胺四醋酸合成物的铋盐反作用含有硫 sourse，像是硫代乙醯胺，硫，钠 thiosulphate ， geseous H2S 。

Two analogues of Trichosanthes trypsin inhibitor I with the Cys14- Cys26 or Cys8- Cys20 disulfide bonds replaced by Tys or Phe and two negative control analogues substitution serine for cysteine at 14 and 26 or 8 and 20 positions were synthesized, respectively. The C14F-C26Y mutant had 1/140 inhibitory activity of native Trichosanthes trypsin inhibitor I to trypsin.

第二章是对天花粉胰蛋白酶抑制剂的两对二硫键的作用进行了研究，二硫键在蛋白质的折叠和功能中有重要的作用，芳香族氨基酸的芳环之间形成π-π共轭能否部分补偿二硫键的作用？

Through Friedel-Crafts reaction, We have prepared highly purified triphenylphosphine sulfide by using benzene, phosphorus trichloride, sulfur, and aluminum trichloride, which is desulfurized with metal powder to produce triphenylphosphine.

实验方法为以苯、三氯化磷、硫和三氯化铝为原料，利用Friedel-Crafts反应，合成三苯基硫膦，收率为79.4％；然后用金属将三苯基硫膦还原制得三苯基膦，收率为80％。

Research result indicated that the cooperative effect between swell and precursor is main factor for the nanoparticle loaded in Nafion, and moreover, polarity of solvent and water content in Nafion also affects the load largely. To improve away the surface concentration of CdS nanocrystal on two side of membrane for general preparation, thioacetamide was first used as a precursor instead of inorganic sulfur source(H2S and Na2S) in synthesis of CdS nanocrystal. The assembly mechanism for several sulfur source had been studied, and CdS/Nafion with the character of homogeneous disperse had been prepared, which is fit for mass transmission in photocatalitic reaction. Following the investigation of several crystallizing way, simple and reliable hydrothermal-crystallizing was found. According to this way, maximal TiO2 load in Nafion achieved 43%. Activity of TiO2/Nafion or CdS/Nafion as a photocatalyst was explored initially for disintegrating liquid contamination. Maximal decompose rate achieved 86% under condition of this research.

研究结果表明：Nafion膜对纳米粒子负载量的主要影响因素是溶胀作用与前驱体协同效应，同时溶剂极性和薄膜含水量对负载量也影响相当大；本课题首次使用硫代乙酰胺代替传统无机硫源（H2S、Na2S）合成CdS纳晶，研究了各种硫源的组装机理，克服了常规技术存在的CdS纳晶趋于膜表面富集的缺点，得到了有利于光催化传质需要的体相均匀分布CdS/Nafion；研究了多种Nafion膜内纳米粒子晶化途径，找到了简单可靠的水热晶化法，TiO2纳晶最高负载量达43％；初步探索了TiO2/Nafion、CdS/Nafion作为光催化剂降解水中模拟污染物的活性，在本实验条件下最高降解率达86％。

The present invention adopts ammonium salt solution as leach, and adopts the liquid-phase oxidation activating agent formed from surfactant sodium ligno-sulfonate or sodium dodecyl sulfonate, liquir phase oxidation catalyst Cu(2+) and sulfur-extracting agent tetrachloroethylene to implement quick leaching process of sulkfide mineral in gas-liquid-solid three-phase reactor, all the sulfurs contained sulfide in mineral powder can be converted into elementary sulfur and sulfuric acid radical, the contained zinc, copper, nickel, cobalt, lead, cadmium and silver can be changed into soluble salt, and fed into leach or remained in the leaching out slag.

本发明涉及的有色金属硫化矿的铵盐液相氧化直接浸出方法，其特征在于：采用铵盐溶液作浸出剂，采用由表面活化剂木质磺酸钠或十二烷基磺酸钠，液相氧化催化剂Cu2+、萃硫剂四氯乙烯组成的液相氧化活化剂，在气液固三相反应器内，实现硫化矿的快速浸出过程，矿粉中各种硫化物所含的硫转变为单质硫和硫酸根，所含的锌、铜、镍、钴、铅、镉、银等变成可溶性盐类进入浸出液中或留在浸出渣中，消除传统流程中二氧化硫，硫化氢，氮氧化物及含砷含汞含铅等有毒烟气的排放。

In this study,the organic sulfur compound is decomposed in a oxygen flask;organic sulfur is turned into sulfate sulfur,and then the measure of sulfate is determined by Barium Chromate Spectrophotometer .

本文用氧弹燃烧法将煤中有机硫氧化成二氧化硫和三氧化硫，再将其转化成硫酸盐硫，建立铬酸钡光度法测定硫酸根的方法，从而间接得到有机硫的含量。

The research presented here is aimed at exploring the effect of DTT on the in vitro fibril formation of hen egg-white lysozymes with four disulfide bonds. In this work, we specifically addressed the effect of DTT concentration under different incubation temperatures on the hen lysozyme structure and fibril formation, the effect of addition of DTT at later time points on the amyloid fibrillization of hen lysozymes, and the effect of concentration ratio between reduced and oxidized forms of DTT on the fibril formation of lysozymes.

本研究以具有四对双硫键的母鸡蛋白溶菌酶为蛋白质模式系统，在含盐类之酸性溶液环境下诱导生成类淀粉纤维，再配合二硫代苏糖醇破坏溶菌酶中的双硫键，探讨：（1）不同温度下加入不同DTT浓度对溶菌酶类淀粉纤维形成之影响，（2）不同生长时期加入DTT对溶菌酶类淀粉纤维形成之影响，（3）不同比例之DTT和氧化态DTT浓度对溶菌酶类淀粉纤维形成之影响。

By using lysozyme, RNase A and protein disulfide isomerase as model proteins, we present a hypothesis that protein cross-linking can be accomplished in three concerted steps:(1) a change in protein conformation;(2) formation of interchain disulfide bonds; and (3) formation of interchain isopeptide cross-links.

我们以溶菌酶、核糖核酸酶A和蛋白质二硫键异构酶为模型对异肽键进行了体外详细的研究，提出了解释异肽键形成机理的假说：1蛋白质发生构象变化包括二级结构的改变；2蛋白质形成分子间二硫键：3二硫键的形成帮助蛋白质形成了分子间异肽键。

A large releases of kinetic energy for channel CH3CS++ H of least energy might result from a dissociation mechanism according to which c-C2H4S+ isomerizes to a local minimum CH3CSH+ and then dissociates through a transition state to form CH3CS++ H. On the other hand, a predicted dissociation energy 11.05 eV for c-C2H4S ?

实验中观察到环硫乙烯离子解离成CH3CS++ H的解离通道释放出大量的平均动能，并采用G3计算预测环硫乙烯离子的解离通道，推测环硫乙烯离子异构化至次稳定态CH3CSH+结构，再经过渡态结构，断裂S-H键生成C2H3S+和H，同时释放出大量的动能。

In the body and animals, dimethyl sulfone is one of the main sources of sulfur that is in the synthesis of methionine, cysteine , sulfur-containing tissue, protein and peptide.

二甲基砜是人体、动物等合成蛋氨酸、胱氨酸和含硫肽、蛋白，以及含硫组织中硫的主要供应源之一。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。