和硫

This model indicates that the sulfur isotopes, whose values tend to be negative fractionate to a large scale because of the reductive process of dissimilating bacteria of sulfate.

根据内蒙古乌达矿区高硫煤9煤层（有机硫同位素值 d 34 S=－12.3‰~5.8‰，黄铁矿硫同位素值 d 34 S=－18.7‰~1.1‰）和低硫煤13煤层（有机硫同位素值 d 34 S 为8.9‰~ 11.5‰，黄铁矿硫同位素值 d 34 S 为8.3‰~ 9.7‰）剖面上有机硫和黄铁矿硫同位素的组成，结合煤岩学特征的综合分析以及黄铁矿化菌落和蓝藻胶壳的发现，提出了高硫煤中硫的演化模式，认为高硫煤中硫的同位素由于硫酸盐的异化细菌还原作用导致硫同位素大规模分馏，使之趋于负值。

These compounds are of substantial interest both inviewpoints of theory and practical applications, mainlyunder the stimulus to achieve synthetic models either foractive sites of iron-sulfur proteins or for transitionmetal catalysts. This thesis describes the synthesis, structures andconformations of 51 new iron-sulfur cluster complexes,which have been characterized by elemental analysis andstandard spectroscopic methods. In addition, single-crystalX-ray diffraction analyses were performed for 4 representa-tive new compounds. Reactivities of μ-〓 with mono- and di- Grig-nard reagents derived intermediates toward various organicelectrophilic substrates were studied, along with complexa-tion of arynyl-containing iron-sulfur clusters by 〓Thus, several bridged, non-bridged, monomeric, dimeric,homonuclear, heteronuclear iron-sullfur and iron-sulfur co-balt-carbon cluster complexes were synthesized. A novelreaction and convenient route for the synthesis in highyield of tetranuclear iron complexes 〓 containing atetracoordinated sulfur atom was discovered, whereas aplausible mechanism based on experimental results was propo-sed for the formation of the new cluster type.

鉴于有机铁硫原子簇化学在基础理论发展和应用方面的重要意义，因此我们开展了这一课题的研究，并取得以下主要成果： 1、本文共合成了51个新有机铁硫及含钴碳簇基的有机铁硫原子簇配合物，除用元素分析，NMR，IR，MS法表征其结构和构象外，还用X-光衍射技术测得四个代表性配合物的单晶结构和构象； 2、我们业已发现炔基Grignard试剂同〓可形成一种&开环&与&闭环&中间物的平衡混合物，研究该平衡混合物同各种亲电试剂的反应； 3、研究发现了一种可高产率地形成〓含〓四配位硫挛合簇的新化学反应并对此反应提出了—种有趣的反应机理； 4、首次由1，4-二溴丁烷双Grignard试剂与〓制得一种新型铁硫簇双硫阴离子活性中间体，并进而研究了它的亲核反应性能； 5、找到了通过〓的光化学反应来合成簇合物〓-〓的一条有实用价值的新路线。

High organic sulfur Beisu bituminous coal and high pyritic sulfur Yangquan anthracite, which involved in raw coal and no inorganic sulfur coal, have been used to investigate the regularity about sulfur forms evolution during combustion by means of improved automatic sulfur analyzer in this paper.

利用改进的自动测硫仪，以高有机硫北宿烟煤和高黄铁矿硫阳泉无烟煤作为研究对象，在不同温度下对原煤和脱无机硫煤在煤燃烧过程中硫析出特性进行了研究，另外对原煤和脱无机硫煤在热解和燃烧时硫形态的变化进行了研究。

By using established analytical methods for determination of elemental sulfur,hydrogen sulfide,mercaptan,disulfide,total active sulfur and corrosive sulfur in Middle East crude oils were conducted Differences between the sum of various types of active sulfur and total active sulfur,the relationship of total active sulfur and total sulfur in the fraction of IBP to 350 ℃,the relationship of total active sulfur and corrosive sulfur,and the distribution of different active sulfurs in the same crude oil and to...

利用已经建立起来的方法对中东原油中的元素硫、硫化氢、硫醇、二硫化物、总活性硫、腐蚀性硫进行了分析，并讨论了不同类型活性硫的加和值与总活性硫的相关性、初馏点至 3 5 0℃馏分中总活性硫和总硫的关系、总活性硫与腐蚀性硫的关系、同一原油中不同类型活性硫和不同原油中总活性硫的分布以及中东原油在硫化合物分布上与哈萨克斯坦原油的差别等问题。

Then the selenium-catalyzed oxidative carbonylation of aniline with thiols has been studied.

接着，考察了在催化量硒作用下苯胺和硫醇的氧化羰基化反应。

Therefore we studied the redox carbonylation of nitroarenes with thiols at atmospheric pressure in detail and succeeded in reducing the high reaction pressure to atmospheric pressure .

所以我们在常压条件下对硒催化芳香硝基化合物和硫醇的氧化还原羰基化反应进行了详尽研究，成功地将加压反应常压化。

In order to broaden the types of the reaction, we have also studied and realized the selenium-catalyzed redox carbonylation of nitroarenes with thiols under pressurized carbon monoxide condition systematically.

为了拓宽反应类型，我们又系统地探讨并实现了在一氧化碳加压条件下硒催化芳香硝基化合物和硫醇的氧化还原羰基化反应。

A brittle silver-white metalloid element that is related to selenium and sulfur; it is used in alloys and as a semiconductor; occurs mainly as tellurides in ores of copper and nickel and silver and gold.

一种脆的、银白色非金属元素，与硒和硫有关联，用于合金及作半导体，主要作为碲化物存在于铜、镍、银、金矿石中。注意，注意力集中

It can be seen from Table 1 that the residual recalcitrant organics consisted of alcohols (36.68%a),phenols (6.88%),ketonnes,quinines, parafins, nitrogenous and sulfur compounds.

从表1中可见，残余的不易分解的有机物包括了酒精36.68%），长链烷醇混合物(6.88%，酮类、奎宁，石蜡，含氮和硫化合物。

In contrast, deletion of the propeptide yields mature but inactive NK, the inclusion bodies of NK or denatured rNK couldn't be renatured in any condition, but with the aid of exogenously purified propeptide or Ser221Ala proNK, the inactive mature protein could be renatured by an intermolecular pathway in vitro.

此外，我们利用融合基因表达系统在大肠杆菌中高效表达了谷胱甘肽S-转移酶／NK和硫氧还蛋白／NK两种融合蛋白，经体外复性、纯化，均获得活性蛋白。以上结果显示，pro肽在体内体外，通过分子内或分子间的方式均能帮助NK分子的折叠与再折叠，作为一种分子内的分子伴侣，pro肽为NK分子正确折叠所必需。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。