吸附态离子

Organic matter reduces effective content of ion of heavy metals through adsorption and chelation.

有机质通过吸附作用和螯合作用减少有效态重金属离子含量。

The dark adsorption of Cr ion on TiO〓 surface was studied.

考察了Cr离子在TiO〓表面的暗态吸附规律。

FT-IR results show that in the strongly acidic、weakly acidic and basic solutions, the glycine exists in the form of cation、zwitterion and anion, respectively.

在强酸性、弱酸性和碱性溶液中，吸附态的甘氨酸分别主要以阳离子、两性离子和阴离子形式存在。

FF-IR results showed that in the strongly acidic, weakly acidic, and basic solutions, the glycine exists in the form of cation, zwitterion, and anion, respectively.

在强酸性、弱酸性和碱性溶液中，吸附态的甘氨酸分别主要以阳离子、两性离子和阴离子形式存在。

As an extension to the "973" Program of National Planning key basic research project -----the study of China lake nutrient over-enrichment process and the mechanism of blue alga outbreak, this paper introduces our experiments as below:(1) Experiment on heavy metal absorption and disorption abilities of Ceratophyllum demersum , Hydrilla verticillata and Myriophyllum triphyllum, in order to campare their absorption capability .

本文在前人的研究基础上，依托国家&973&国家重点基础研究规划项目&湖泊富营养化过程与蓝藻水华暴发机理&，开展了下列工作： 1、选取狐尾藻、金鱼藻、黑藻三种大型沉水植物作为研究对象，通过对重金属离子铜离子的吸附及解吸实验，比较其三种沉水植物之间吸附能力的大小； 2、选取狐尾藻、黑藻为研究对象，研究了重金属离子铜离子对沉水植物的胁迫作用及铜离子在植物体内的富集情况； 3、选取黑藻为研究对象，研究了沉水植物在富营养条件下不同浓度的氨态氮和硝态氮对沉水植物的生理生长的影响。

The surface action mechanism of sodium polydithio dipropyl sulfonate in acidic Cu plating bath indicates that the surface complex produced by adsorbed sodium polydithio dipropyl sulfonate and Cu + resists copper ions' electrodeposition.

酸性镀铜溶液中表面活性剂聚二硫二丙烷磺酸钠的表面作用机理表现为：吸附态的聚二硫二丙烷磺酸钠与Cu＋形成表面络合物阻化铜离子的电沉积。

The results of the present research are as follows, The correlation between physico-chemical properties of organic compounds and their competitive power was studied, and it was indicated that organic compounds preferable to form H-bonding with organic matter of sorbents have stronger competitive power; Sorption behaviors of ionizable organic compounds in different species and their competitive power were examined, and the results showed that phenols and carbonxylic acids with benzyl circle have much stronger competitive power in molecular species than in ionized species, because negative charges of anionic forms can depressed their adsorption on the surface of the sediment; in contrast, organic bases such as aniline and p-chloroaniline show weaker competitive power in molecular species than in ionized species, and this is because both species of the organic bases could adsorb strongly onto the sediment; there is a correlation between competitive power of organic pollutants in multi-solute systems and their sorption isotherm nonlinearity in single-solute systems, and organic compounds whose sorption isotherms is linear in single-solute systems hardly have competitive power in multi-solute systems; Competitive sorption effects in more than two-solutes systems was studied, and it was exhibited that mixture of two cosolutes each of which could suppress sorption of nominal solute onto the sediment had synergistically competitive sorption effect on the nominal solute; A method about incorporating sorption/desorption of organic pollutants into river water quality model was developed, and discussion about degree of sorption/desorption effect on model prediction for different organic compounds was made, which will provide theoretical basis and practical processes for setting up more accurate water quality model.

论文主要取得了以下研究成果。(1)有机化合物的吸附竞争能力与其物化性质具有相关性，易与沉积物有机质形成氢键的化合物其竞争能力也比较强；(2)可离子化有机化合物的吸附竞争能力与其存在形态有关。酚类、含苯环的羧酸类化合物，其离子态的吸附竞争能力远小于分子态，其机理为有机酸阴离子所带的负电荷抑制了表面吸附能力，主要发生分配作用；而苯胺类化合物，其离子态和分子态都表现出显著的竞争能力，而且离子态的竞争能力略强于分子态，原因在于有机碱阳离子所带的正电荷促进了其表面吸附能力；有机化合物竞争能力的强弱与其单组分吸附等温线的非线性程度具有一定的相关性，吸附等温线近似为线性的化合物没有或只具有微弱的竞争能力；(3)对目标有机化合物的吸附具有竞争效应的有机化合物混合后，将对目标有机化合物的吸附产生协同竞争效应；(4)以京杭运河为例，率先提出了将有机污染物的吸附／脱附作用及水文水力参数耦合到水质模型中的方法，并讨论了吸附／脱附作用对不同有机污染物预测模型的影响，为建立更准确的水质模型及进行更客观的风险和生态评估提供了参考依据。

The new opinion and mechanism that the simultaneously adsorption of complex pollution of both organic and heavy metals will be achieved on soil modified with amphoteric surface modifying agent, which have both charged group and organophilic group on one ASMA molecule, were proposed at first time, and its rationality was testified at the same time; The 50% was the critical CTMAB modifying ratio of soil CEC at which the organophilic bond modifying mechanism was emerged; The thermodynamic characteristics of adsorption of OPT and HMP on OMS were discovered ; The study revealed the surface peculiarity of OMS that the modifying agent were distributed at uneven scatter mode and multi-characters surface were coexisted on surface of OMS, revealed the adsorption peculiarity of OMS that multi-mechanisms were coexisted, confirmed the unequal charge amount modifying mode of OMS in which dual-modifying mechanism of both ion exchange and OPB were processed at the same time, and confirmed that the adsorption hobby to CTMAB was higher than that to Ca2+ on Lou soil.

首次提出了用两性表面修饰剂对土壤进行修饰改性，利用两性表面修饰剂所具有的荷电基团和疏水基团达到对土壤中有机、重金属污染物同时吸附的思路和机理，并通过实验证实了所提设想的合理性；发现了土壤CEC值的50%修饰比例是CTMAB开始显现以疏水键机制对土土样表面进行修饰的临界点；揭示了有机修饰改性土对有机物、重金属吸附过程的热力学特征，填补了该项研究工作的空白；阐明了修饰剂在改性土表面呈分散态的非均匀分布，改性土表面具有不同性质表面共存的表面特征和对污染物多机制共存的吸附特征，确定了阳离子表面修饰剂在土表面的修饰是一种离子交换和疏水键结合两种机制相伴并行且为非等电荷量交换的修饰反应模式，以及土具有对CTMAB的吸附偏好性远大于对钙离子吸附偏好性的特征。

The immobilizing effects of red mud by bayer process is much better than by sintering process under different concentration of application, because of the smaller particle size, larger surface area, higher content of Fe2O3 and Al2O3.The adsorption capacity of red mud and zeolite to Cd was very large.

通过钝化剂对溶液中Cd离子的吸附解吸试验表明：赤泥、沸石对Cd离子具有很大的吸附容量和较强的吸附亲和力；只有不到25%的吸附镉为水溶态和可交换态，而绝大部分吸附的镉(50%以上)为与赤泥结合稳定的、不易为生物利用的形态。

The nonionic surfactants in soil not only have no toxicity to microorganisms, but also enhance the growth of soil microorganisms, the bioavailability and biodegradation of hydrophobic pollutants sorbed in soil.

非离子表面活性剂进入土壤后，对微生物不但没有毒性，而且还促进微生物的生长，并有利于吸附态污染物的解吸，增加了其生物可利用性，加快了微生物的降解作用。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。