吸附原子

The energetic and structural properties of SiH_2 adsorbed on single dimer vacancy of the Si(100)-c(4×2) surface, the structures of 0.5ML hydrogenated Si(100) surface and the deposition and diffusion behaviours of silicon adatom on the H-terminated Si (100) surfaces have been studied by using empirical tight-binding total energy calculations.

本文采用经验紧束缚近似方法研究了SiH_2在Si(100)-c(4×2)表面单空位处的吸附结构、0.5ML覆盖率氢化的硅表面结构以及附加硅原子在H-terminated Si(100)表面的沉积吸附行为。

Three new kinds of thiourea - type chelating cotton cellulose, thiourea cellulose, thiosemicarbazide cellulose and diphenylthiourea cellulose, were synthesized in our Lab, and their absorptive characteristics for copper was investigated.

将自制合成的三种新型硫脲型螫合纤维素——硫晚棉纤维，氨基硫脲棉纤维和二苯硫脲棉纤维应用于钢的吸附性能的研究，采用火焰原子吸收法测定选择了吸附和解吸的最佳条件。

With the varying of potential the adsorption behavior of picolinic acid is invariant,while the adsorption behavior of isonicotinic acid and nicotinic acid may change.

分析表明在电极电位负移过程中皮考酸分子一直采取通过羧基和苯环上的N原子侧立吸附在银电极表面，与之不同的是，异烟酸分子和烟酸分子在表面的吸附状态都随电位改变发生了变化，我们对此进行了分析和解释。

With the varying of potential the adsorption behavior of picolinic acid is invariant, while the adsorption behavior of isonicotinic acid and nicotinic acid may change. The probable reasons are given.

分析表明在电极电位负移过程中皮考酸分子一直采取通过羧基和苯环上的N原子侧立吸附在银电极表面，与之不同的是，异烟酸分子和烟酸分子在表面的吸附状态都随电位改变发生了变化，我们对此进行了分析和解释。

It was demonstrated thermodynamically that the initial products with respect to the uranium-hydrogen system included UH, UH2, UH3, U2H2 and U2H4. The potential energy surface analyzing results confirmed that the optimized structures and suggested, theoretically, that the main initial products were UO or linear U02 in the uranium-oxygen system, and uranium monocarbide or uranium oxycarbides in the uranium-carbon monoxide system, depending on the different interaction mode.

计算结果从热力学上证明了铀与H_2的初始反应产物可能有UH、UH_2、UH_3、U_2H_2和U_2H_4 等；随着铀与O_2相互作用的方式的不同，铀氧化的初始产物或者是UO分子，或者是直线型UO_2分子；CO在铀上的吸附属于解离吸附，并以CO的碳端与铀原子相互作用最有利，初始相互作用产物主要有碳化物和碳氧化物。

The literature about the synthesis of the ion exchange and chelating adsorbents used in the off-line separation and preconcentration of the noble metals and the development of the on-line microcolumn separation and preconcentration of the noble metals were reviewed. Four silica gel-based adsorbents with rhodanine, 2-mercaptopyrimidine, 2-mercaptothiazoline and isophenylthiourea as the functional groups were first synthesized and applied to the on-line separation and preconcentration of silver, gold, palladium and platinum for their FAAS determination.

本论文在回顾螯合吸附材料的合成及其在贵金属的离线和流动注射在线预浓集分离发展状况的基础上，首次合成了含罗丹宁、2-巯基嘧啶、2-巯基噻唑啉和异二苯基硫脲等四种以硅胶为载体的螯合吸附剂，并用于银、金、钯和铂的流动注射微填充柱在线预浓集分离、火焰原子吸收光谱分析。

Titanium incorporated mesoporous molecular sieves Ti-MCM-41, Ti-HMS, and Ti-MSU were synthesized through S〓I〓, S〓I〓, and N〓I〓 pathways using cetylpyridium bromide, tetredecylamine, and polyoxyethylene (10) stearyl ether as the structure-directing agents, respectively. The framework structure and the titanium coordination environment of these materials were characterized by XRD, N〓 adsorption/desorption, TG, TEM, FT-1R, DR UV-Vis, and ICP-AES. It was confirmed that the titanium was highly dispersed in the silica-based framework positions, and all samples were free of extra framework titanium impurities. The catalytic performance of these titanium containing mesoporous materials was investigated in the oxidation of styrene with aqueous H〓O〓 as the oxidant.

以TEOS和TBOT为硅源和钛源，分别以溴代十六烷基吡啶、十四胺和十八烷基聚氧乙烯基醚为模板剂，通过S〓I〓、S〓I〓和N〓I〓方式合成了含钛的介孔分子筛Ti-MCM-41、Ti-HMS和Ti-MSU，用XRD、N〓吸附/脱附、TEM、FT-IR、DR UV-Vis和ICP-AES等方法对它们的骨架结构、孔道结构以及钛原子的存在方式等进行了系统表征，结果表明钛原子以高分散的形式存在于以SiO〓为基本单元的介孔分子筛的骨架结构中，制备过程中未形成聚集态的骨架外金属氧化物物种。

The experiment is done based on a glass cell and all the results are quite in agreement with the theory. The decay process of the background vacuum pressure caused by the untrapped cesium atoms after shutting off the desorption light is well explained quantitatively.

通过实验获得了不同光强和照射时间下关闭解吸附光后磁光阱中铯原子的衰减过程，理论模型定量地描述了背景铯原子造成压强的变化及其对最终平衡态下真空度的影响。

Using hydrotreated gas oil as solvent, under the conditions of a reaction temperature of 400 C, a hydrogen partial pressure of 10 MPa and a reaction time of 1 h, a portion of coke deposits could be removed yet without the function of hydrogenating coke.

采用溶剂萃取法除去工业失活催化剂上沉积的焦炭和金属的研究结果表明，用四氢呋喃、吡啶和喹啉这3种含杂原子的有机强溶剂常温萃取催化剂，其去除焦炭能力很弱，而且会因这些溶剂的强吸附作用污染催化剂；盐酸洗涤能有效去除催化剂表面的钙、铁沉积层，但不能去除焦炭；低芳香性的加氢瓦斯油在400 C、H2压力为10MPa、反应1h的条件下可部分去除催化剂上的焦炭，但不具备强的氢化焦炭作用；1，2，3，4-四氢化萘因具有供给原子氢的能力，可以有效地氢化和去除催化剂上的焦炭。

H atom preoccupies the H1 site at low coverage.

在低覆盖度下， H原子优先吸附在子表面吸附位H1。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。