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吸附化合物

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Demonstrated by adsorptive capacity and adsorptive energy, polyacrylamides have strong interaction on mineral surface with similar action mode to that of starches, for example, hydrolyzed polyacrylamide and hydroxamic acid polyacrylamide mainly by chemical force, cationic polyacrylamide by electrostatic force and hydrogen bond, nonionic polyacrylamide by hydrogen bond, while amphoteric polyacrylamide embodying both the characters of anionic and cationic one.

聚丙烯酰胺类化合物在矿物表面的吸附能以及吸附量均显示出药剂与矿物间存在的强作用,作用方式与淀粉类药剂相似:阴离子聚丙烯酰胺、羟肟酸聚丙烯酰胺主要靠化学作用,阳离子聚丙烯酰胺借助静电力和氢键,非离子型的聚丙烯酰胺则主要是氢键作用,两性聚丙烯酰胺同时具有阴离子和阳离子聚丙烯酰胺药剂的作用特点。

A surface-modified adsorbent is a support bearing at the surface of a chemically bonded "monomolecular" layer of adsorbing groups, which provides fast kinetics of the recovery and elution of the molecules and ions under study.5–9 SPE by use of alkyl-bonded silica gels has been widely applied in the environmental analysis of polyaromatic hydrocarbons, pesticides, substances of biochemical origin and other organic compounds.

表面改性吸附剂是一种载体,它负载在一层化学键合的单分子吸附性官能团的表层,为所研究的分子和离子的回收和洗脱提供了快速动力。使用含烷基的硅胶的SPE技术已经被广泛应用到芳烃聚合物、农药、生物成因物质以及其他有机化合物的环境分析中。

Effect of solute adsorption on vapor pressure osmometry measurment was studied by four low molecular weight organic compounds and five narrow MWD oliomeric polystyrene samples with known average molecular weight in Knauer VPO apparatus.

在气相渗透仪上,用四个低分子量有机化合物和五个已知平均分子量的窄分布聚苯乙烯低聚体,对VPO方法中的溶质吸附效应作了研究,提出了一种对吸附效应作改正的方法。

The adsorption rate curves and istherms of five kinds of phenolic compounds were given in this paper.

给出五种酚类化合物在黄河水体沉积物中的吸附速率曲线和吸附等温式。

The polymer was adsorbed in a more coiled configuration at lower pH values and turned to a more stretched-out configuration at higher pH values.

PAANH〓在Al〓O〓表面吸附的红外光谱表明,PAANH〓是通过长链上的羧基离子与Al〓形成化合物而吸附在Al〓O〓表面上的。

Cryptomelane was prepared by precipitation method and characterized as tetragonal crystal with specific surface area and abundant hydroxyl groups at its surface.

文章表征了由沉淀法合成的锰钾矿型化合物的多种理化特性,并应用于铅离子吸附的研究,对吸附反应机理进行了初步探讨。

To further study the chemical constitutes of lipophilic active parts, we prepared Alc95% and Alc50% according to original literature. 20 compounds were isolated by using macroporous resin, silica gel, polyamide, Sephadex LH-20, Rp-18, preparative TLC and preparative HPLC chromato-graphy. The structures of them were elucidated by means of physical and chemical properties, modern spectroscopic analysis techniques—UV、IR、 EI/MS、ESI/MS、〓H-NMR、〓C-NMR、DEPT、HMQC、HMBC. They are nine anthraquinones: chrysophanol (95-1), physcion (95-2), emodin (95-5), aloemodin (95-7), rhein (50-1), sennoside A or B (50-6),ω-hydroxylemodin (95-10), chrysophanol-8-0-β-D-glucoside (95-12), aloemodin-ω-0-β-D-glucoside (95-13); three phenanthaquinones: tanshinone ⅡA (95-3), cryptotanshinone (95-6), tanshinone Ⅰ(95-4); one isoflavone: 7, 3'-dihydroxyl-5' methoxyisoflavone (95-14) and protocaechuic aldehyde (95-9), protocaechuic acid (95-11), astragaloside Ⅳ(50-4), amygdalin (50-5), 2, 3, 5, 4'-tetrahydroxylstilbene-2-0-β-D-glucoside (50-3),-catechin (50-2), cinnamic acid (95-8). Among them, 3'-dihydroxyl-5' methoxyisoflavone (95-14) is a new compound.

经过溶剂萃取、大孔吸附树脂富集、Sephadex LH-20精制、制备TLC及Semi-pre HPLC等手段从中分离了20个化合物,利用理化性质和波谱技术(UV、IR、EI/MS、ESI/MS、〓H-NMR、〓C-NMR、DEPT、HMQC、HMBC)相结合鉴定了它们的结构,分别为9种蒽醌类化合物:大黄酚,大黄素甲醚,大黄素,芦荟大黄素,大黄酸,番泻苷A或B,ω-羟基大黄素(ω-hydroxylemodin),大黄酚-8-0-β-D-葡萄糖苷(chrysophanol-8-0-β-D-glucoside),芦荟大黄素-ω-0-β-D-葡萄糖苷(aloemodin-ω-0-β-D-glucoside);3种菲醌类化合物:丹参酮ⅡA(tanshinoneⅡA),隐丹参酮,丹参酮Ⅰ(tanshinone Ⅰ);1种异黄酮:7,3'-二羟基-5'-甲氧基异黄酮(7,3'-dihydroxy-5' methoxyisofla-vone)以及原儿茶醛,原儿茶酸,黄芪甲苷(astragaloside Ⅳ),苦杏仁苷,2,3,5,4'-四羟基二苯乙烯-2-0-β-D-葡萄糖苷(2,3,5,4'-tetrahydroxylstilbene-2-O-β-D-g1ucoside),Z—儿茶素,桂皮酸。

Trees have adsorption, absorption of pollutants or impede the spread of pollutants, trees absorb SO2, nitrogen oxide, hydrogen nitrogen compounds, Cl, fluorine compounds and Hg, Cr, and other heavy metals.

树木具有吸附、吸收污染物或阻碍污染物扩散的作用,树木吸收SO2、氮氧化合物、氮氢化合物、Cl、氟化合物和Hg、Cr等重金属。

Effect of chemical properties of naphthalene derivatives on adsorption was discussed, and it was concluded that naphthylamines with small dipole moment were ready to be adsorbed on nonpolar XAD-2 and XAD-4, while naphthols with high dipole moment were more likely adsorbed on XAD-7 and XAD-8 with medium polarity.

讨论了萘系列化合物性质对于吸附的影响,发现偶极矩小的萘胺分子更容易在非极性的XAD-2和XAD-4上吸附,而偶极矩大的萘酚更容易在中极性的XAD-7和XAD-8树脂上吸附。

Four different SPE cartridges were tested for extracting six triazines, including atrazine, simazine, prometryn, desethylatrazine, 2-hydroxyatrazine and desisopropylatrazine, and finally ENVI-18 was selected as optimal. The method for solid phase extraction was further systematically studied for details.

考察了4种不同固相萃取柱对三嗪类化合物的吸附效果,最终选择ENVI-18固相萃取柱用于萃取地表水中的三嗪类化合物;系统研究了环境水样中三嗪类化合物的最佳固相萃取条件,选择洗脱溶剂为甲醇,洗脱溶剂用量5 mL,水样在萃取前不需要添加甲醇,不调节pH值。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力