吸附化合物

The conclusions were as follows: theνO-H andνC=O IR absorption maxima shifted towards higher wave numbers after imprinting 17β-estradiol on TFMAA-co-TRIM copolymer with the red shift of theνO-H groups being apparent after precipitation polymerization for 16h while that forνC=O groups being observed after polymerization for 24h. A strong interaction between TFMAA and 17β-estradiol was confirmed by the high selectivity for 17β-estradiol, as indicted by the values of the separation factor of isomers of 17β-estradiol/17α-estradiol (2.28) and the imprinted factor (3.01). Particle diameter of TFMAA-co-TRIM polymer was between 300 nm and 1.5μm, which suited well for solid phase sorbent throughout at low column pressure. The recognition of imprinting TFMAA-co-TRIM polymer for sterol molecules was driven by enthalpy eluted with acetronitile, and low temperature was in favor of the separation of sterol structure analogues on imprinting column. TFMAA-co-TRIM polymer possessed of determinate anti-heat stability, with melting point beginning at 255.84℃, Tp=257.40℃, control TFMAA-co-TRIM polymer and imprinting TFMAA-co-TRIM polymer were respectively decompounded at 267.79℃and 343.11℃, and solid micro-extraction noddle prepared by the special polymerization also showed definite recognition for 17β-estradiol by GC/MS detecting at 270℃. By selection of various washing and elution solvents, elution reagents of close polymerization system were of more advantage in template molecules retention and recognition on molecularly imprinted solid phase extraction column. At a certain extent, progesterone, 17α-estradiol, 17β-estradiol and 4-androstene-3, 17-dione could be intercepted on the MISPE column. Especially, MISPE had high selectivity for progesterone, and imprinting TFMAA-co-TRIM polymer could achieve adsorption balance within 50 min by absorption kinetics test for 17β-estradiol. However, MISPE column showed better selectivity and enrichment property for 17β-estradiol than C18 and CSPE columns according to the data from HPLC and GC/MS analyses. Recovery of 17β-estradiol on MISPE column was up to 85.5% while when prime extracting solution of milk powder was sampled, the recovery of CSPE and C18 columns were 43.7% and 30.7%, respectively.

通过研究阐明：紫外聚合产物TFMAA-co-TRIM中的νO-H振动吸收峰在聚合16h后红移，νC=O振动吸收峰在聚合24h后红移；TFMAA-co-TRIM对雌二醇异构体的印迹因子达到了3.01，α为2.28，优于其它功能单体参与得到的聚合物识别特性；TFMAA-co-TRIM聚合物粒径介于300 nm至1.5μm之间，作为色谱固定相具有良好的通量和低的柱压；在乙腈流动相中，TFMAA-co-TRIM分子印迹固定相的分离过程主要被焓驱动，低温有利于分子印迹固定相分离甾醇结构类似物；TFMAA-co-TRIM分子印迹聚合物在255.84℃时开始熔融，Tp=257.40℃，聚合物CP的降解温度在267.79℃，MIP降解温度在343.11℃，制备的固相微萃取头初步经GC/MS 270℃的耐热性测定；不同的洗提溶剂筛选证明了选择接近聚合溶剂的洗脱体系更有利于MISPE发挥识别效应；分子印迹固相萃取柱对孕酮、17α-雌二醇、17β-雌二醇和雄烯二酮都具有不同程度的保留特性，可作为此类化合物的吸附材料，特别对孕酮强保留的富集特性，可作为孕酮的选择性识别吸附剂，其分子印迹聚合物对17β-雌二醇的吸附动力学测定显示在50 min内基本达到吸附平衡，具有作为传感器核心敏感材料的潜力；对比萃取奶粉中17β-雌二醇性能，MISPE柱比非分子印迹固相萃取柱和C18柱具有更高的保留，回收率依次为85.5%，43.7%和30.7%。

The performance of static adsorption of phenolic compounds onto this kind of resin was i...

研究了该树脂对水溶液中酚类化合物的吸附性能，并与NKA-II吸附树脂进行了比较，结果表明，固化单宁大孔吸附树脂对水溶液中苯酚的吸附能力高于NKA-II，这主要得益于树脂表面的酚羟基。

The adsorption processes are exothermic reaction and belong to the chemical adsorptions.The Langmuir iso therm is followed.

两种化合物在Cu表面上的吸附过程为放热过程，其在Cu表面上的吸附行为服从Langmuir吸附等温式，属化学吸附。

Adsorption mechanism of uranyl ion (UO22+) on this polymer was studied with IR spectra and by means of the adsorption behaviors of compounds of similar structure.

为了探索吸附机理，本文用类似结构的化合物作吸附铀的对比和从红外光谱均可看出，吸附剂的各配位基在同铀的配合中，表现出明显的协同作用。

As an absorbent prepared by present invention contains the houghite compound, the absorbent can adjust the pore structure, the size and the acidity and basicity of the absorbent.

本发明所制备的吸附剂由于该吸附剂中含水滑石类化合物，可以针对硫化物分子对吸附剂的孔结构、尺寸以及酸碱性进行调节。

Quercetin, quercetin rhamnoside, hyperin, syringoside and eleutheroside E wereisolated from the flower of Acanthopanax senticosus. Searching bioactive natural compound and establishing quality evaluation standard arefocused on this experiment. Using cold immersing of 70% methanol to extract from flower ofAcanthopanax senticosus and integrating macroporous resin, silica gel column chromatography,sephadex gel to abstract. We obtained five monomer compounds (compoundⅠ-compoundⅤ),quercetin, quercetin rhamnoside, hyperin, syringoside and eleutheroside E. That five compoundswere determined by HPLC in eight parts of Acanthopanax senticosus (flower, root, leaf fruit,shoot, new shoot, phloem of shoot, skin of shoot), which provide science bases for establishingquality evaluation system and settle infarctate foundation.

本文以从刺五加花蕾中寻找具有重要生物活性的天然化合物和建立质量评价标准为主要目的，对其化学成分进行研究，采用70％甲醇冷浸的方法对刺五加花蕾中的成分进行提取，运用大孔树脂吸附色谱法、硅胶柱层析法以及葡聚糖凝胶柱层析相结合的方法进行分离，得到5种单体化合物，分别为槲皮素、槲皮素鼠李糖苷、金丝桃苷、紫丁香苷和刺五加苷E；利用高效液相色谱法对这5种化合物在刺五加花蕾中的含量进行了测定；考察了8个部位(花蕾、根、叶、果、茎干、新枝、茎韧皮部、茎皮)中这5种化合物的含量分布情况，并作一比较，为今后建立刺五加质量评价体系提供了科学依据，奠定了坚实的基础。

Estimations of the isosteric enthalpy of adsorption, free energy, and entropy of adsorption were reported and the adsorption behaviors were reasonably interpreted.

并计算了氯酚类化合物在两树脂上的吸附洽变、自由能变、吸附熵变，对吸附行为进行了合理的解释。

The obtained rice husk adsorbent showed great capability of adsorption to aromatic compound and heterocyclic dye in the process of water purification.

以酸处理稻壳为原料，研究了稻壳吸附剂的活化工艺，所制备的吸附剂对水中芳香化合物和杂环染料均有较大的吸附能力。

First of all, a systematic study on adsorption properties of the four phenolic compounds (phenol, p-chlorophenol, p-cresol and p-nitrophenol) on MX-4, AM-1 and NJ-8 was carried out, and a comparison of the adsorption behavior between the new resins and Amberlite XAD-4 was also made. In addition, the impact of the resin structure and the property of a specific compound on adsorption behavior was discussed herein.

用静态吸附法系统地研究了四种酚（苯酚、对氯苯酚、对甲苯酚、对硝基苯酚）在乙酰基修饰交联聚苯乙烯树脂(MX-4)、酚羟基修饰超高交联聚苯乙烯树脂(AM-1)以及氧修饰超高交联聚苯乙烯树脂(NJ-8)上的吸附行为并与AmberliteXAD-4树脂的吸附行为进行比较，探讨了树脂结构和化合物性质对吸附行为的影响。

Results showed that all of the adsorbents worked effectively.

对平衡吸附数据的相关分析显示，萘系列化合物在六种大孔吸附树脂上的吸附等温线均符合Freundlich方程。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。