吸附剂

The conclusions were as follows: theνO-H andνC=O IR absorption maxima shifted towards higher wave numbers after imprinting 17β-estradiol on TFMAA-co-TRIM copolymer with the red shift of theνO-H groups being apparent after precipitation polymerization for 16h while that forνC=O groups being observed after polymerization for 24h. A strong interaction between TFMAA and 17β-estradiol was confirmed by the high selectivity for 17β-estradiol, as indicted by the values of the separation factor of isomers of 17β-estradiol/17α-estradiol (2.28) and the imprinted factor (3.01). Particle diameter of TFMAA-co-TRIM polymer was between 300 nm and 1.5μm, which suited well for solid phase sorbent throughout at low column pressure. The recognition of imprinting TFMAA-co-TRIM polymer for sterol molecules was driven by enthalpy eluted with acetronitile, and low temperature was in favor of the separation of sterol structure analogues on imprinting column. TFMAA-co-TRIM polymer possessed of determinate anti-heat stability, with melting point beginning at 255.84℃, Tp=257.40℃, control TFMAA-co-TRIM polymer and imprinting TFMAA-co-TRIM polymer were respectively decompounded at 267.79℃and 343.11℃, and solid micro-extraction noddle prepared by the special polymerization also showed definite recognition for 17β-estradiol by GC/MS detecting at 270℃. By selection of various washing and elution solvents, elution reagents of close polymerization system were of more advantage in template molecules retention and recognition on molecularly imprinted solid phase extraction column. At a certain extent, progesterone, 17α-estradiol, 17β-estradiol and 4-androstene-3, 17-dione could be intercepted on the MISPE column. Especially, MISPE had high selectivity for progesterone, and imprinting TFMAA-co-TRIM polymer could achieve adsorption balance within 50 min by absorption kinetics test for 17β-estradiol. However, MISPE column showed better selectivity and enrichment property for 17β-estradiol than C18 and CSPE columns according to the data from HPLC and GC/MS analyses. Recovery of 17β-estradiol on MISPE column was up to 85.5% while when prime extracting solution of milk powder was sampled, the recovery of CSPE and C18 columns were 43.7% and 30.7%, respectively.

通过研究阐明：紫外聚合产物TFMAA-co-TRIM中的νO-H振动吸收峰在聚合16h后红移，νC=O振动吸收峰在聚合24h后红移；TFMAA-co-TRIM对雌二醇异构体的印迹因子达到了3.01，α为2.28，优于其它功能单体参与得到的聚合物识别特性；TFMAA-co-TRIM聚合物粒径介于300 nm至1.5μm之间，作为色谱固定相具有良好的通量和低的柱压；在乙腈流动相中，TFMAA-co-TRIM分子印迹固定相的分离过程主要被焓驱动，低温有利于分子印迹固定相分离甾醇结构类似物；TFMAA-co-TRIM分子印迹聚合物在255.84℃时开始熔融，Tp=257.40℃，聚合物CP的降解温度在267.79℃，MIP降解温度在343.11℃，制备的固相微萃取头初步经GC/MS 270℃的耐热性测定；不同的洗提溶剂筛选证明了选择接近聚合溶剂的洗脱体系更有利于MISPE发挥识别效应；分子印迹固相萃取柱对孕酮、17α-雌二醇、17β-雌二醇和雄烯二酮都具有不同程度的保留特性，可作为此类化合物的吸附材料，特别对孕酮强保留的富集特性，可作为孕酮的选择性识别吸附剂，其分子印迹聚合物对17β-雌二醇的吸附动力学测定显示在50 min内基本达到吸附平衡，具有作为传感器核心敏感材料的潜力；对比萃取奶粉中17β-雌二醇性能，MISPE柱比非分子印迹固相萃取柱和C18柱具有更高的保留，回收率依次为85.5%，43.7%和30.7%。

Improvement on selectivity and capacity of adsorbents and deep research on mechanism will be the most important research areas.

指出吸附剂吸附选择性及吸附容量的提高和吸附机理的深入研究是今后研究的重要方向。

The sorbent is prepared from a kind of natural mineral zeolite - stilbite (its Chinese code name is CXN, its English code name is STI, and its scientific name is stilbite); through positive ion exchange produce H-STI, mix with artificial compounded commodity H-ZSM-5 zeolite, add cementing agent to molding, after strengthening process, then through silver carrying to produce. The small ball of the sorbent of 1 mm diameter can get 40 Newton per grain.

该吸附剂是由一种天然矿物沸石-辉沸石(中国代号CXN，英文代码STI，学名stilbite)，通过阳离子交换制成H-STI，与人工合成的商品H-ZSM-5沸石混合加粘结剂成型，经强化处理后再经载银而制成，直径1毫米的该吸附剂小球强度可达40牛顿/粒。

At pH 2.0, the adsorption capacities of sunset yellow and tartrazine are 408.92 mg/g and 306.96 mg/g respectively.

在25℃，pH2.0，吸附剂对日落黄和柠檬黄48h的吸附量分别达到408.92mg／g和306.96mg／g，吸附反应符合Langmuir等温吸附模型。

At pH 2.0, the adsorption capacities of sunset yellow and tartrazine are 408.92mg/g and 306.96mg/g respectively. And Langmuir isotherms are very suitable for describing the adsorption process.

在25℃。pH2.0，吸附剂对日落黄和柠檬黄48h的吸附量分别达到408.92mg/g和306.96mg/g，吸附反应符合Langmuir等温吸附模型。

It was found that the adsorption of reactive Turquoise Blue KN-G on the adsorbent was found to be initially pH and concentration dependent.

实验结果表明：活性翠兰KN-G在吸附剂上的吸附效果取决于吸附质溶液的pH值和吸附质的初始浓度。

These sorbents have been proven to have high sulfur-selective ability. CuMCM41 was used to adsorb model diesel, the results showed that CuMCM41 adsorbed more thiophenes and benzothiophene than naphthalene from model diesel.

吸附剂对硫化物具有很强的选择性，用CuMCM41来吸附模拟柴油，吸附结果表明它对噻吩和苯并噻吩的吸附性比对萘要强。

Because of this property, water is preferentially adsorbed by these surfaces, and large organic compounds cannot compete with strongly held water for adsorption sites on the clay surfaces. Thus, Na-clays are ine_ective sorbents for small organic molecules. However, it is possible to modify the surface properties of clays greatly by neutralizing the anionic framework of layer silicates by using positively charged organic species such as alkylammonim ions. In the modi_ed form (HDTMA-bentonite), the clay surface may become organophilic and interact strongly with organic compounds. Textile dyes represent a relatively large group of organic chemicals. In an HDTMA-bentonite-dye system it is possible that adsorption may be enhanced by the hydrophobic interaction between the adsorbed dye molecule and HDTMA-bentonite.

O组给予亲水的性质到矿物表面，因为这水是吸附在这些表面，和大的有机化合物不能比有坚强的为了吸附位置在泥土表面，因而，Na—泥土是ine_ective吸附剂为了小的分子，希，它是可能的到更改的表面属性，泥土非常在抵销anionic层硅酸盐在用的结构 Positively负荷的物种例如alkylammonim离子，在mod i_ed形状，泥土表面可能变成organophilic和互相作用坚强地有机化合物，织物染料表现相关的大的组化学的，在HDTMA—斑脱土—染料系统它是可能的那吸附可能是提高在交互作用在中间吸附染料分子和HDTMA—斑脱土，interlamellarHDTMA的间隔—斑脱土是获得在substracting泥土层从的厚度实验上坚决的基础的间隔（d001）。

The adsorption results of triethylene tetraamine-modified oxycellulose showed that:(1) when adsorption tests were carried at 37℃and pH7 in 5 h,static adsorption capacity of 0.5g adsorbent for urea(6g/L in dialysis solution),uric acid(1 g/L in redistilled water) and creatinine(0.1 g/L in dialysis solution) were 131.5mg/g,24.6mg/g,3.31mg/g respectively.

三乙烯基四胺基氧化纤维素的吸附性能结果表明：(1)吸附温度为37℃，pH值为7时，0.5g吸附剂对于尿素(6g/L透析液)、尿酸(1g/L二次水)、肌酐(0.1g/L透析液)在5h的静态吸附容量分别为131.5mg/g、24.6mg/g、3.31mg/g。

The invention discloses a treating method of tail water membrane filtering condensation fluid in chemical industry park, the steps of which are that the pre-treated membrane filtering condensation fluid goes through a device filled with resinous adsorbent under the common temperature and a flow quantity of 0.5-8BV / h, the absorbed water can be discharged after neutralizing with small capacity of alkali, desorbing and regenerating the resin by natrium hydroxydatum solution with the flow capacity of the desorbing agent is 0.5-3.0BV / h, the high concentration desorbing fluid disposes safely and the low concentration desorbing fluid can be periodically used to preparing next pluralities of desorbing agent.

本发明公开了一种化工园区尾水膜滤浓缩液的治理方法。其步骤为：将预处理后的膜滤浓缩液在常温和0.5～8BV/h的流量条件下，通过装填有树脂吸附剂的装置，吸附出水加少量碱中和后即可排放；将上述树脂用氢氧化钠溶液脱附再生，脱附剂流量为0.5～3.0BV/h，高浓度脱附液安全处置，低浓度脱附液可用于配制下一批脱附剂循环套用。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了