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The invention discloses a dielectric hole-microhole composite material and synthesizing method in the inorganic porous material, adsorbing material and catalytic material technical domain, which comprises the following steps: adopting zeolite molecular sieve as raw material; reacting with sodium bisilicate solution under 30-60 deg.c for 10-300 min; disintegrating particle part of zeolite molecular sieve into piece with microhole structure; adding cetyl trimethyl ammonium bromide as molder; adjusting pH value of mother liquid to 10-12; aging 1-8h; adding in the high-pressure autoclave to do water heat synthesizing reaction at 80-130 deg.c for 24-72h; separating solid; washing; drying; sintering under 500-600 deg.c for 5-10h; obtaining the Si-Al porous material with dielectric hole and microhole composite structure.

本发明属于无机多孔材料、吸附材料和催化材料技术领域,涉及具有介孔-微孔复合材料及其合成方法。其特征是以沸石分子筛为原料,用偏硅酸钠的水溶液在30~60℃反应10~300分钟,使沸石分子筛的颗粒部分解离形成具有微孔结构的碎片,加入模板剂十六烷基三甲基溴化铵,然后调节母液pH值为10~12,老化1~8小时,然后加入高压釜于80~130℃进行水热合成反应。反应24~72小时后,分离出固体,水洗、干燥,然后于500~600℃焙烧5~10小时,得到具有介孔和微孔复合结构的硅铝多孔材料。本发明的效果和益处是所发明的合成方法可用于合成多种沸石结构和介孔结构的复合材料,所合成的材料经过质子交换可以具有较强的酸性,在吸附和催化领域具有广泛应用前景。

Aluminum phosphate (AlPO 4) can be prepared by solid state synthesis with different templates, aluminum chloride and ammonium diacid phosphate at low temperature (180℃) within a short time (2 h).

以氯化铝和磷酸二氢铵为原料,在模板剂存在下用固相合成方法合成了磷酸铝类化合物,合成的化合物通过化学分析、ICP测定、XRD和 IR图谱对其进行了表征,研究了化合物对铬离子吸附性能,实验表明这类化合物对铬离子有较好的吸附能

The pigment of Berberis heteropoda Schrenk is a type of anchocyanin and it is strong in resistance against light and to some extent, good in enduring heat and low consistence oxide. But it is poor in resistance against reductant and preservative. It can be applied to the condition of PH. It is also found that sucrose and most of metal ions do not exert negative effects on the stability of the pigment, except Fe3+, Fe2+and low consistence Pb2+, which have some extent effects. Adding stability matter can improve its stability. The harm trace elements contains are within requirement of the National Standard on food safety, As the lexicological study indicates that the pigment does not have any toxicity and mutagenesis, it can be used as edible pigment.

结果表明:大孔树脂吸附-解吸附法纯化黑果小檗色素实验室工艺简单易行,色素回收率高;黑果小檗色素属于花色苷类色素;耐光性好;对热有一定耐受性;对低浓度氧化剂有一定耐受性;耐还原性差;对防腐剂耐性差;适用PH<6条件下使用;蔗糖和大多数金属离子对色素无不良影响,但Fe~(3+)、Fe~(2+)、Sn~(2+)和低浓度pb~(2+)对色素有影响,加入稳定剂后,可提高色素的耐热性、耐氧化性、耐防腐剂能力;经对有害微量元素进行检测和毒理试验表明,该色素安全无毒,可以作为天然食用色素使用。

The results show: in a specific concentration range, the solubility in neutral solution of SOL, as well as the surfactivity, the ability to reduce ITF and the wettability on the condition of non- alkali are better than the lignosulfonate in market.While using as sacrifice agent, the modified lignosulfonate can reduce 60% of the mahogany sulfonate and 50% of the α-alkene sulphonate which both are adsorbed on the oil sand surface.

结果表明在一定浓度范围内,SOL在中性溶液条件下的溶解性、在无碱条件下的表面活性、降界面张力能力、对岩石的润湿性效果优于市场木质素磺酸盐产品;作为牺牲剂使用时,改性磺化木质素能减少石油磺酸盐在油砂表面吸附的60%,减少α-烯烃磺酸盐在油砂表面上吸附的50%。

The red pigment from Parthenocissus Tricuspidate was extracted and purified with macroporous resin of type HPD-600 using methanol as the eluent.

比较了6种不同型号的大孔树脂对爬山虎红色素的吸附能力,筛选其中最佳的HPD 600树脂作为爬山虎红色素的吸附和分离的树脂;用甲醇作为洗脱剂,洗脱效果较好;研究了食品中6种常见的共存物、4种金属离子、氧化剂、温度及光等对爬山虎红色素稳定性的影响。

The highest occupied molecular orbit and the lowest unoccupied molecular orbit are calculated, and the energy gap of the two orbits determines the activity of the reagents, and yet, in an alkaline solutions for flotation, the HOMOs of the corresponding ions decide the rigidity of the reagents and therefore determine the reaction activity with different rigidity metal cations in minerals, which vary flotation performance to different minerals, and the experimental results were verified.

药剂与矿物作用的能量计算结果表明:苯氧乙酸类抑制剂与方解石和一水硬铝石作用后的能量变化均为负值,能量变化有利,可以形成稳定的吸附;而与黄铁矿作用后的能量变化为正,能量的变化是不利的,故不能形成稳定的吸附,表现出较弱的抑制作用。

The expression of one-dimensional mathematical model of vertical migration of ammonia in the CRI system is:The parameters in the CRI model are determined as following: the retardarce coefficient is determined by static isothermal absorption experiment, the velocity of sewage travel through the soil column is determined by permeability test, the vertical dispersion coefficient is determined by test the electric conductivity of tracer in the dispersion experiment, the rate of nitrification and denitrification is determined by test of Baps technology.

依据单一氨氮、硝氮配水条件下的试验结果,引入多孔介质的溶质运移理论及对流-弥散方程,考虑NH4+-N在CRI系统中的运移受到对流和水动力弥散作用的影响,并吸附-解吸、硝化与反硝化3个过程,首次将配水流经CRI土柱的孔隙水流速方程与CRI土柱内发生的、以氧为约束条件的硝化、反硝化过程联系起来,建立了CRI系统一维垂向氨氮运移转化数学模型,表达式为:研究分别通过静态等温吸附实验率定了模型方程中的阻滞系数、通过渗滤试验测定了土柱中的孔隙水流速、通过测定弥散试验中示踪剂的电导率确定了纵向弥散系数、通过气压过程分离技术测定了土柱中的总硝化与反硝化反应速率常数,最后通过测定土柱沿程氧化-还原电位的方法分析氨氮在CRI系统中的运移转化机理。

In HCl solution,an absorption model is suggested that those inhibitors w ould be adsorbed on metal surface in horizon flat-ended.

在HCl溶液中提出了这些缓蚀剂可能以平卧方式吸附于金属表面的吸附模型。

The interfacial chemistry, synergistic effects and interfacial kinetics of thesynergistic extraction system D_2EHPA-MPA-Fe~(3+) have been studied, where MPA is amono-alkyl phosphate extraction with long carbon chain. D_2EHPA in the mixed extractionsystem strongly exhibits the effect on the thermodynamics of micella formation and interfaceproperties of MPA. Some thermodynamic parameters of micella formation were obtained.The interfacial adsorption behaviour of D_2EHPA is opposite to that of MPA. Theemulsification for single MPA and the mixed system was discussed. The synergistic effectswere found in this mixed extraction system. It is proved that the process of Fe~(3+) extractionfor non-mixed extraction system is controlled by chemical reaction, the controlling reactionoccurs at the interface, and the reaction rate equation is obtained.

本文研究了协同萃取体系D_2EHPA—MPA—Fe~(3+的胶团形成热力学、界面特性、协萃效应和界面动力学(动力学控制机制和反应速率方程)研究发现,混合萃取体系中的D_2EHPA强烈地影响MPA的胶团形成热力学和界面吸附行为,得到了胶团生成常数、胶团形成自由能和临界胶团浓度的热力学参数D_2EHPA和MPA具有相反的界面吸附行为研究发现D_2EHPA—MPA混合萃取剂体系对Fe~(3+)产生了协萃效应动力学和界面化学的研究结果还证实了非胶束混合萃取体系的Fe~(3+)的萃取过程是受化学反应控制的,控制反应发生在界面上

This article investigated the red pigment extraction of raspberry by resin, and the absorption of 4 resin by ethanol of different concentration to red pigment of raspberry .

本文研究了树莓红色素的树脂法提取工艺,通过4种树脂对树莓红色素的吸附及不同浓度的乙醇对树莓红色素解吸的比较研究,结果表明,AB-8树脂对树莓红色素具有较高的吸附量,用90%乙醇为洗脱剂得到的产品质量好;产品收率达1.84%。

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