吸附剂

With the help of infrared spectroscopy, it is known that the linkage between dodecylamine and sodium oleate and diaspore, kaolinite, illite and pyrophyllite is fundamentally electrostatic forces, which contributes to physical adsorption. The adsorption is related with surface electric property of minerals. The effect of chemical composition of diaspores on their electrokinetics was investigated.

对于一水硬铝石矿物来说，三个主要晶面（010）、（100）和（001）上的单位面积断裂键数有如下关系：〓；一水硬铝石表面吸附的动力学模拟可以说明，一水硬铝石的（010）晶面、（100）晶面和（001）晶面，分别吸附几种捕收剂离子的吸附能大小为：（010）晶面的吸附能＞（100）晶面的吸附能＞（001）晶面的吸附能；分别吸附这些药剂离子的单位面积吸附量〓的大小顺序为：（010）晶面＞（100）晶面＞（001）晶面。

The function mechanism among the minerals and floatation drugs had been studied with the way of IR and academic calculation, which pointed out that absorption of G-4 on the surface of phosphorite belonged to physical and chemical types, but the chemical one was in the highest flight. Absorption of amine collector named GE-609 on the surface of quartz belonged to electrostatic and physical type. Distilled water could hardly wash the GE-609 down from the surface of quartz. Leading component of S-721 was the concentrated compound of naphthol sulfonic acid and formaldehyde. The compound had a stronger affinity to the Mg~(2+) on surface of dolomite than the Ca2+ on surface of phosphorite, which is the essential reason in the separation of phosphorite and dolomite. The leading components of soluble glass in function were HSiO3 hydronium and F^SiC^ colloid granule.

通过红外光谱测定以及理论计算的方法研究了选矿药剂与矿物间的作用机理，研究表明：脂肪酸捕收剂G-4对胶磷矿的捕收作用是以化学吸附为主、化学吸附与物理吸附共同作用的结果；胺类阳离子捕收剂GE-609在石英表面的吸附属于静电物理吸附，但很难用水洗的方法使GE-609从石英表面脱附；S-721主要成分为萘酚磺酸与甲醛的缩合物，萘酚磺酸与甲醛的缩合物对白云石表面Mg~(2+)的吸附明显强于对胶磷矿表面Ca~(2+)的吸附，这是胶磷矿与白云石分离的根本原因；水玻璃溶液中对石英起抑制作用的主要组分是HSiO_3~-和H_2SiO_3胶粒，水玻璃除对石英起抑制作用外，对矿浆还具有一定的分散作用。

In this study, we developed the ammonia sensing material by using MCM-41 impregnated with bromocresol green. MCM-41 is one kind of mesoporous molecular sieves. It can be applied to many fields due to well-defined pore shapes, narrow distribution of pore sizes, large pore volumes, high surface area, excellent thermal, hydrothermal, chemical and mechanical stability. And the bromocresol green dye is commonly used as a pH indicator with colorimetric from pH 3.8 to pH 5.4.

本研究之目的是结合变色染剂及中孔洞分子筛MCM-41进行氨气吸附，研究中所选择之变色染剂溴甲酚绿是一种偏酸性之大分子有机染剂，其变色范围在pH 3.8到pH 5.4；而MCM-41由於其孔洞大小分布范围狭窄、孔洞体积大、高比表面积、具有良好的吸附容积、表面反应性强及易於改质等优点，故期望利用此复合材料，经气体吸附达到氨的移除并同时在吸附饱和前能产生显色效果。

ABSTRACT Inhibition mechanism and the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles whose inhibition is caused by chemical adsorption and quaternary ammonium salts whose inhibition is caused by physical adsorption are mainly studied from microscope through quantum chemistry calculation, and the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles are studied by making use of model-constructing thought of grey theory in this paper.

本文主要通过量子化学计算，从微观角度研究了化学吸附型缓蚀剂苯腈类化合物和物理吸附型缓蚀剂季铵盐在盐酸溶液中对碳钢缓蚀的缓蚀机理和缓蚀性能与分子结构的关系；并运用灰色理论建模思想，研究了苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀性能与分子结构的关系。其中，通过量子化学计算，从微观角度研究物理吸附型缓蚀剂在盐酸溶液中对碳钢缓蚀的缓蚀机理和缓蚀性能与分子结构的关系，是在尝试着进行；而运用灰色理论建模思想，研究缓蚀剂缓蚀性能与分子结构的关系，是一项具有尝试性和开拓性的工作。

The new opinion and mechanism that the simultaneously adsorption of complex pollution of both organic and heavy metals will be achieved on soil modified with amphoteric surface modifying agent, which have both charged group and organophilic group on one ASMA molecule, were proposed at first time, and its rationality was testified at the same time; The 50% was the critical CTMAB modifying ratio of soil CEC at which the organophilic bond modifying mechanism was emerged; The thermodynamic characteristics of adsorption of OPT and HMP on OMS were discovered ; The study revealed the surface peculiarity of OMS that the modifying agent were distributed at uneven scatter mode and multi-characters surface were coexisted on surface of OMS, revealed the adsorption peculiarity of OMS that multi-mechanisms were coexisted, confirmed the unequal charge amount modifying mode of OMS in which dual-modifying mechanism of both ion exchange and OPB were processed at the same time, and confirmed that the adsorption hobby to CTMAB was higher than that to Ca2+ on Lou soil.

首次提出了用两性表面修饰剂对土壤进行修饰改性，利用两性表面修饰剂所具有的荷电基团和疏水基团达到对土壤中有机、重金属污染物同时吸附的思路和机理，并通过实验证实了所提设想的合理性；发现了土壤CEC值的50%修饰比例是CTMAB开始显现以疏水键机制对土土样表面进行修饰的临界点；揭示了有机修饰改性土对有机物、重金属吸附过程的热力学特征，填补了该项研究工作的空白；阐明了修饰剂在改性土表面呈分散态的非均匀分布，改性土表面具有不同性质表面共存的表面特征和对污染物多机制共存的吸附特征，确定了阳离子表面修饰剂在土表面的修饰是一种离子交换和疏水键结合两种机制相伴并行且为非等电荷量交换的修饰反应模式，以及土具有对CTMAB的吸附偏好性远大于对钙离子吸附偏好性的特征。

By comparison of eight micro adsorption, A resin with high adsorption rate and eluent rate was used to adsorb chlorogenic acid from extraction solution. The adsorption parameters are: the content of chlorogenic acid is 0.204 mg per mL adsorption solution, the acidity of adsorption solution is 4, the adsorption velocity of flow is 3 mL per min, the eluent is 30% ethanol, the eluting speed is 1.5 mL per min and the eluents volume is 4 times of resin volume. In the optimal adsorption condition, the final yield of CHA is 5.06%. the content of chlorogenic acid is 78.26% in dry productin.

通过对比8种大孔吸附树脂对绿原酸的吸附效果，选用对绿原酸吸附解吸性能均较好的树脂对绿原酸吸附，吸附参数如下：吸附液绿原酸的浓度为0.204mg／mL、吸附液pH值为4、流速为3mL／min，解吸参数如下：解吸剂为30％乙醇、解吸剂流速为1.5mL／min、解吸剂使用量为4倍树脂体积，在此条件下，绿原酸得率为5.06％，产物中绿原酸含量为78.26％。

Chitosan coagulates fine flocci together into lager, impact floccules and greatly strengthens the polymerization degree and coacervation force. The sedimentation rate and adsorption efficiency rise greatly. So the flocculation efficiency of this composite flocculant is superior to the single one.

无机絮凝剂CF-PAC、铝交联蒙脱石主要起吸附作用，而壳聚糖和PAM等有机高分子絮凝剂主要起吸附桥连作用，将细小的絮粒凝结在一起形成更大更致密的絮体，并使聚合度和凝聚力大大增强，从而使其沉降速度和吸附效率大大提高，起到优于单一絮凝剂的絮凝效果。

Side-stream experiment for the removal of sec-butanol from recycle butylenes by adsorption on adsorbent PUMS-01 was carried out in a methyl ethyl ketone unit.

对甲乙酮装置循环丁烯脱除仲丁醇吸附剂PUMS-01进行了工业放大实验，实验结果表明产品性能达到了小试实验的水平。

The line of isothermal adsorption with polysacharidcs adsorbent at 70℃, 80℃ and 90℃ respectively is determined by the method of frontal chromatography in this paper.

本文是在研究以多醣类物质作吸附剂制取无水乙醇的新工艺基础上，采用迎头色谱法测定了吸咐等温线，突验数据通过回归分析，获得符合Freundlich型的吸咐等温方程，计算值与实验结果吻合较好。

The depressing ability of the macromolecule organic depressants can be improved by the increase of their D.S.. The high D.S. CPVA and CPEG show strong depressing ability to calcite, while CPEG indicates strong depressing ability to diaspore, and HPAM to pyrite.The depressing mechanism of organic depressants was confirmed by the measurements of zeta potential, contact angles, adsorption capacity and IR spectrum.

利用动电位、接触角、吸附量和红外光谱等测试方法和手段，探讨了抑制剂的作用机理：苯氧乙酸类小分子抑制剂与方解石之间可发生较强的化学作用，可以选择性地吸附在方解石表面，使捕收剂发生解吸或阻止捕收剂在矿物表面的吸附而使矿物受到抑制；大分子抑制剂则主要是依靠亲固基吸附在矿物表面，再利用其长链的强亲水性而使矿物受到抑制。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。