吸附作用的

When pH is 10, adsorption time is 30 min, dosage of bone char is 0.6 g/L, the original concentration of As in drinking water is 0.5 mg/L, As removal can reach 95.2%. The adsorption behavior is fitted both with Langmuir and Freundlich isotherm. The adsorption mechanism is supposed to be Ca—OH functional groups combined with anion. And there may occur the co-precipitation between calcium hydrogen arsenate and hydroxylapatite in the aqueous solution, and ions also exchange. The saturation adsorption capacity of As reaches 4.688 mg/g. Indexes of effluent are in good agreement with the WHO stringent drinking water standards (0.01 mg/L).

研究结果表明：在pH=10，吸附时间为30 min和骨炭加入量为0.6 g/L，饮用水砷初始质量浓度为0.5 mg/L时其砷去除率可达95.2%；骨炭吸附砷的行为同时符合Langmuir和Freundlich等温吸附模型；其吸附机理可能是Ca—OH官能团结合HASO4阴离子，并产生砷酸氢钙和羟基磷灰石的共沉淀，另外还存在离子交换作用；吸附柱的饱和吸附容量为4.688 mg/g；出水砷浓度符合世界卫生组织规定饮水砷标准(0.01 mg/L)。

Organic montmorillonite combines inorganic montmorillonites excellent dilatability, adsorption and dispersion with huge hydrophobic area, so it has very good affinity for organic substance and has been widely used in organic system.

模拟汽油体系的吸附脱硫实验表明，改性后的蒙脱土表面由亲水性转变为亲油性，体系中的含硫化合物被吸附到蒙脱土的层间，有机蒙脱土吸附脱硫的作用是分配作用和表面吸附共同作用的结果。

Main contents and conclusions are: 1 The ionization current was measured continuously by a charge-integration method with a computer after the introduction of radon into the chamber.

主要内容及结论：1充氡后利用计算机连续进行电离电流累积测量，得到了精细的电流随时间的变化曲线，可清楚看出氡及其子体的生成衰变造成的电离电流的生长—稳定—衰减过程，与理论计算值进行了比较，由电离电流衰减速度的变化得出氡吸附作用的影响，并测量到电离室冲洗后氡的反扩散现象；2由已知活度的标准源定出相对测量的刻度系数K值，K=24.62 Bq／pA，对同一个监测源以半年为周期进行多次测量后得出稳定性符合要求；3通过测量电离电流和气压的关系曲线以及不同气压下的饱和曲线，确定了常规的工作条件；4测量了盐酸清洗电离室内表面降低本底的效果；5不确定度分析表明相对测氡的扩展不确定度(k=2)小于5％，由本底涨落得出探测下限为0.5 Bq；6理论上对壁损失修正进行了计算，实验上保持电离室工作在饱和区的情况下，测量了不同气压下电离电流的变化，从中得出了壁损失随气压变化的规律，可以看出，电离电流的实测值和计算值随气压变化规律基本一致；当气压大于125 kPa时，端效应等其它因素造成的影响不大于2％，因而在此工作条件下，测量电离电流后通过计算修正壁损失可以实现近似的绝对测氡，提出了进一步提高绝对测量准确度的方法。

And adsorption of jack bean proteins onto the amphoteric resin was studied in this paper. The amphoteric resin was in innersalt form. The results of adsorption experiments show that when the proteins are adsorpted into the amphoteric resin in the neutral phosphate buffer solution, the diffusion coefficient of protein is near twofold in 0.4 mol/L NaCl phosphate buffer solution than that in solution without salt, and the adsorption capacity of protein also rises at the same ti...

通过盐浓度对吸附的动力学和热力学影响的研究，结果表明，在中性磷酸盐缓冲液中，两性树脂吸附刀豆蛋白，有盐( 0 。4mol/L Na Cl)的比无盐的扩散系数提高将近一半，且吸附量增加，其吸附等温线的效率在最初始部分高于无 Na Cl时的；随着盐浓度( 0～ 1 mol/L Na Cl)的提高，树脂对蛋白的吸附量也变大，盐浓度提高时树脂膨胀体积的增大与蛋白吸附量的增加呈线性关系，内盐型两性树脂对大分子蛋白质的吸附作用与小分子高价离子的相似，同样是通过内盐键破裂吸附。

The function mechanism among the minerals and floatation drugs had been studied with the way of IR and academic calculation, which pointed out that absorption of G-4 on the surface of phosphorite belonged to physical and chemical types, but the chemical one was in the highest flight. Absorption of amine collector named GE-609 on the surface of quartz belonged to electrostatic and physical type. Distilled water could hardly wash the GE-609 down from the surface of quartz. Leading component of S-721 was the concentrated compound of naphthol sulfonic acid and formaldehyde. The compound had a stronger affinity to the Mg~(2+) on surface of dolomite than the Ca2+ on surface of phosphorite, which is the essential reason in the separation of phosphorite and dolomite. The leading components of soluble glass in function were HSiO3 hydronium and F^SiC^ colloid granule.

通过红外光谱测定以及理论计算的方法研究了选矿药剂与矿物间的作用机理，研究表明：脂肪酸捕收剂G-4对胶磷矿的捕收作用是以化学吸附为主、化学吸附与物理吸附共同作用的结果；胺类阳离子捕收剂GE-609在石英表面的吸附属于静电物理吸附，但很难用水洗的方法使GE-609从石英表面脱附；S-721主要成分为萘酚磺酸与甲醛的缩合物，萘酚磺酸与甲醛的缩合物对白云石表面Mg~(2+)的吸附明显强于对胶磷矿表面Ca~(2+)的吸附，这是胶磷矿与白云石分离的根本原因；水玻璃溶液中对石英起抑制作用的主要组分是HSiO_3~-和H_2SiO_3胶粒，水玻璃除对石英起抑制作用外，对矿浆还具有一定的分散作用。

X6 3?,large specific surface area and adsorbent capacity However,most molecules and hydrated ions can not enter the aperture pass because of their size over the aperture diameter of palygorslote except less simple ones Furthermore,Palygorskite adsorbs water molecule choosingly In most cases the absorbing of palygorskite is by its outside surface that works in the form of colloid and ion exchange other than i...

但是由于凹凸棒石孔道直径小于大多数分子及水合离子的直径，除少数简单分子和离子外，多数分子和离子都不能进入凹凸棒石孔道，而且凹凸棒石选择性吸附水分子，因而在多数情况下，凹凸棒石对吸附质的吸附不是内表面吸附，而是外表面吸附。并且外表面吸附是胶体和离子交换吸附。本文阐述了凹凸棒石的孔道直径、吸附选择性、体系pH 值及凹凸棒石和蒙脱石胶体颗粒的互相作用对凹凸棒石吸附性能应用的制约。

The results of the present research are as follows, The correlation between physico-chemical properties of organic compounds and their competitive power was studied, and it was indicated that organic compounds preferable to form H-bonding with organic matter of sorbents have stronger competitive power; Sorption behaviors of ionizable organic compounds in different species and their competitive power were examined, and the results showed that phenols and carbonxylic acids with benzyl circle have much stronger competitive power in molecular species than in ionized species, because negative charges of anionic forms can depressed their adsorption on the surface of the sediment; in contrast, organic bases such as aniline and p-chloroaniline show weaker competitive power in molecular species than in ionized species, and this is because both species of the organic bases could adsorb strongly onto the sediment; there is a correlation between competitive power of organic pollutants in multi-solute systems and their sorption isotherm nonlinearity in single-solute systems, and organic compounds whose sorption isotherms is linear in single-solute systems hardly have competitive power in multi-solute systems; Competitive sorption effects in more than two-solutes systems was studied, and it was exhibited that mixture of two cosolutes each of which could suppress sorption of nominal solute onto the sediment had synergistically competitive sorption effect on the nominal solute; A method about incorporating sorption/desorption of organic pollutants into river water quality model was developed, and discussion about degree of sorption/desorption effect on model prediction for different organic compounds was made, which will provide theoretical basis and practical processes for setting up more accurate water quality model.

论文主要取得了以下研究成果。(1)有机化合物的吸附竞争能力与其物化性质具有相关性，易与沉积物有机质形成氢键的化合物其竞争能力也比较强；(2)可离子化有机化合物的吸附竞争能力与其存在形态有关。酚类、含苯环的羧酸类化合物，其离子态的吸附竞争能力远小于分子态，其机理为有机酸阴离子所带的负电荷抑制了表面吸附能力，主要发生分配作用；而苯胺类化合物，其离子态和分子态都表现出显著的竞争能力，而且离子态的竞争能力略强于分子态，原因在于有机碱阳离子所带的正电荷促进了其表面吸附能力；有机化合物竞争能力的强弱与其单组分吸附等温线的非线性程度具有一定的相关性，吸附等温线近似为线性的化合物没有或只具有微弱的竞争能力；(3)对目标有机化合物的吸附具有竞争效应的有机化合物混合后，将对目标有机化合物的吸附产生协同竞争效应；(4)以京杭运河为例，率先提出了将有机污染物的吸附／脱附作用及水文水力参数耦合到水质模型中的方法，并讨论了吸附／脱附作用对不同有机污染物预测模型的影响，为建立更准确的水质模型及进行更客观的风险和生态评估提供了参考依据。

It is shown that the adsorption of propiolic alcohol on the surface of pure aluminium is the important reason resulted from corrosion inhibition and that the rule of adsorption conforms with Langmuir's isotherm.

采用失重法研究了氢氧化钠溶液中丙炔醇在不同温度和浓度下对铭的缓蚀作用，发现丙炔醇在铝表面上的吸附是产生缓蚀作用的重要原因，且吸附规律服从Langmuir吸附等温式。

The effects of magnetic seed, aluminum sulphate and pH value on phosphorus adsorption, precipitation and coagulation were surveyed. The results made it clear that Al ion as precipitant and coagulant was the main effect factor on P removal; as adsorbent magnetic seed had little effect on P removal, but made the phosphate precipitate sink faster; pH value had effect on both precipitation and adsorption.

研究了磁种、硫酸铝、pH值等对磷的吸附、沉淀、凝聚的影响，结果表明：铝离子的沉淀作用是除磷的主要原因；磁种的吸附作用对除磷的贡献较小，但使磷酸盐沉淀物的沉降性能大大提高；pH值既影响沉淀作用，也影响吸附作用。

Four different sorbents (CaSO4, kaoline, CaCO3 and bauxite) were used to make the control test of heavy metals; and different sorbents were found to have different adsorption of heavy metal. These sorbents not only had physical adsorption of heavy metals but also had chemical reaction between sorbents and heavy metals.

添加无水CaSO4，高岭土，铝土矿，无水CaCO3 4种不同的吸附剂，发现不同的吸附剂对不同的重金属有不同的吸附作用。4种吸附剂对重金属元素的吸附既有物理吸附，又有吸附剂与重金属之间的化学反应。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。