吸附作用

As a result, electrostatic interactions and hydrogen bond were identified to contribute to the affinity interaction, while hydrophobic interaction contributed little. Moreover, the importance of electrostatic interactions and hydrogen bond to the affinity changed with pH value.The effect of rate of mobile phase on the retention of insulin was researched and the dynamic adsorption isotherm was got by analyzing the breakthrough data with Langmuir equation.

通过调节流动相的pH值和离子强度，并使用尿素和乙二醇分别对吸附蛋白进行洗脱，详细研究了吸附效果最好的目标蛋白质与肽配基之间的亲和吸附机理，发现静电作用和氢键是二者之间产生亲和吸附的主要作用力，而疏水相互作用对该亲和几乎没有贡献。

The flotation mechanism of MG reverse-floating dolomite was studied by measuring the Zeta-potential of collophanite and dolomite, Infrared Absorptions Spectra analysing the adsorption of MG onto the minerals surface, ultraviolet- visible light absorbing spectrum calculating the amount of MG which was adsorbed onto the minerals surface. These researches showed that MG was more easyly adsorded onto the surface of dolomite in feeble acidic solution because of pure dolomite charges positive as well as pure collophanite charges negative. Therefore, a lot of MG negative ions was adsorded onto dolomite, and that MG negative ions contained hydrophobic group, the hydrophobicity of dolomite was modified, the grains of dolomite were adhered to air bubble and float with them.

对白云石和胶磷矿的Zeta-电位测定、红外光谱分析MG药剂在矿物上面的吸附情况、紫外-可见吸收光谱测定矿物上MG的吸附量等，研究了MG药剂反浮选白云石的浮选作用机理，表明在弱酸性条件下，由于白云石表面荷正电而胶磷矿表面荷负电，带有羧基和羟基官能团的MG药剂更容易吸附在白云石上，使其周围吸附有大量的MG负离子，而MG负离子的另一端为烃基，这就改变了白云石的疏水性，使其矿粒容易附着于气泡上浮。

Based on theoretical calculation of electronegativity of groups offlotation-reagent and method of infra-red adsorption spectroscopy, the collection andadsorption of α-nitroso-β-naphthol in hematite flotation have been studied. The chemicaladsorption seems to be predominant owing to formation of pentacyclic nitrosyl chelate com-pound by atoms of nitrosyl bond in α-nitroso-β-naphthol together with Fe~(3+) on hematitesurface.

研究了α-亚硝基β-萘酚对赤铁矿的捕收性能及吸附规律，导出了吸附方程和吸附速率方程用药剂基团电负性理论计算以及红外吸收光谱法论述了其作用机理α-亚硝基β—萘酚主要是以N O键合原子与赤铁矿表面的Fe形成N O五元环螯合物而化学吸附。

In NaY supercage, adsorption of thiophene by p-electronic interaction reaches its balance earlier and adsorption of thiophen via pore-filling mechanism reaches its balance later.

温度为373K时，每个NaY超笼内，通过p电子作用吸附的噻吩分子是0.67个，通过孔填充作用吸附的噻吩分子是4.50个。

The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

Adsorption by mineral components and active carbon in fly ash, coagulation and settlement, electrolytical agglomeration, aid-coagulation by silicic acid and increase of BET were the main mechanisms of phosphate and chroma removal with modified fly ash.

改性粉煤灰的除磷、脱色机理是粉煤灰中矿物成分和活性炭的吸附、混凝沉淀作用以及电解质的脱稳凝聚作用、硅酸凝胶的助凝作用以及改性后比表面积增加吸附能力提高等因素的综合效应。

Contributions of humic acid and base-treated soils to the sorption of original soils were quantitied and the results indicated that:More than 60 percent of whole sorption of original soils were contributed by base-treated soils.Thus,base-treated soils played the dominant role in whole sorption of original soils and were main cause of nonlinear sorption.

设计了一个方法对胡敏酸和胡敏素在原土/风化煤吸附中的贡献进行了定量，结果表明，原土/风化煤对DEP吸附超过60%是由Hu贡献的，Hu在原土/风化煤吸附DEP过程中起主导作用，并且是造成原土/风化煤非线性吸附的主要原因。

Better agreement between metallic Pd~n-CO clusters and CO/Pd chemisorption systems demonstrates that the "Metallic State Principle" overweighs the "Lowest Spin State Principle".

总的计算结果表明，依据金属态原则，其结果可以更好地符合CO/Pd吸附体系的实验数据，并认为CO/Pd吸附过程的成键作用主要是CO(5σ)→Pd(5sp)与Pd(5sp)→CO(2π^*)的σ/π授受作用。

The aniline HDN was strongly stressed by the presence of quinoline and DHQ and the HDN of quinoline proceeds exclusively via a pathway which involves fully saturated intermediates on the MCM-41-supported nickel phosphides. The HDN activity of nickel phosphide catalyst was dramatically reduced by the presence of H2S and DBT, probably due to the strong adsorption of H_2S and DBT on active sites which inhibited the adsorption of quinoline.

喹啉和DHQ对苯胺的HDN反应有强烈的抑制作用，喹啉在磷化镍催化剂上几乎全部通过完全加氢饱和路径进行反应。H_2S和二苯并噻吩强烈地吸附在磷化镍催化剂活性中心上，阻碍了反应物分子的吸附，从而对喹啉的HDN反应有强烈的抑制作用。

The empirical Freundlich equation was successfully employed to describe the adsorption process. Due to hydrogen-bonding interaction between the tertiary amino groups on the resin and the amino groups of p-methylaniline, the adsorption capacity towards p-methylaniline of NDA-8 is higher than that of NKA when the equilibrium concentration is 5 mmol/L.

结果表明：2种树脂吸附对甲苯胺均符合Freundlich等温吸附方程，NDA-8树脂表面叔氨基与对甲苯胺之间的氢键作用可有效强化吸附能力，在平衡浓度均为5mmol/L的情况下，其吸附容量达到NKA的1.5~1.6倍。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新