吸附作用

When pH is 10, adsorption time is 30 min, dosage of bone char is 0.6 g/L, the original concentration of As in drinking water is 0.5 mg/L, As removal can reach 95.2%. The adsorption behavior is fitted both with Langmuir and Freundlich isotherm. The adsorption mechanism is supposed to be Ca—OH functional groups combined with anion. And there may occur the co-precipitation between calcium hydrogen arsenate and hydroxylapatite in the aqueous solution, and ions also exchange. The saturation adsorption capacity of As reaches 4.688 mg/g. Indexes of effluent are in good agreement with the WHO stringent drinking water standards (0.01 mg/L).

研究结果表明：在pH=10，吸附时间为30 min和骨炭加入量为0.6 g/L，饮用水砷初始质量浓度为0.5 mg/L时其砷去除率可达95.2%；骨炭吸附砷的行为同时符合Langmuir和Freundlich等温吸附模型；其吸附机理可能是Ca—OH官能团结合HASO4阴离子，并产生砷酸氢钙和羟基磷灰石的共沉淀，另外还存在离子交换作用；吸附柱的饱和吸附容量为4.688 mg/g；出水砷浓度符合世界卫生组织规定饮水砷标准(0.01 mg/L)。

Demonstrated by adsorptive capacity and adsorptive energy, polyacrylamides have strong interaction on mineral surface with similar action mode to that of starches, for example, hydrolyzed polyacrylamide and hydroxamic acid polyacrylamide mainly by chemical force, cationic polyacrylamide by electrostatic force and hydrogen bond, nonionic polyacrylamide by hydrogen bond, while amphoteric polyacrylamide embodying both the characters of anionic and cationic one.

聚丙烯酰胺类化合物在矿物表面的吸附能以及吸附量均显示出药剂与矿物间存在的强作用，作用方式与淀粉类药剂相似：阴离子聚丙烯酰胺、羟肟酸聚丙烯酰胺主要靠化学作用，阳离子聚丙烯酰胺借助静电力和氢键，非离子型的聚丙烯酰胺则主要是氢键作用，两性聚丙烯酰胺同时具有阴离子和阳离子聚丙烯酰胺药剂的作用特点。

Each starch reagent has its own mode of action on mineral surface, such as primary starch mainly by hydrogen bond, cationic starch by the co-action of hydrogen bond and electrostatic force (for minerals with negative charge on its surface), while carboxymethyl starch, hydroxamic acid starch and dialdehyde starch principally by chemical force accompanied with hydrogen bond and electrostatic force in part. Such chemical forces ensure the close adsorption of reagent on diaspore surface and enforces the hydrophilic of mineral surface. Also the branched chain enable the starch to cover the collector adsorbed on mineral surface, so as to depress diaspore furthermore.

不同淀粉药剂在矿物表面表现不同作用，原淀粉主要是氢键的作用，阳离子淀粉是氢键和静电力的共同作用，羧甲基淀粉、羟肟酸淀粉和双醛淀粉离子性药剂与矿物间的作用除了氢键、静电力外，更重要的是与矿物表面金属离子间产生的化学作用，使药剂能牢固地吸附在一水硬铝石矿物表面，增加矿物表面的亲水性，同时，淀粉支链结构的存在，使它能够掩盖吸附的捕收剂，达到抑制一水硬铝石的目的。

Found that the constitution of the absorbent could affect the debinding efficiency greatly; for the liquid phase debinding temperature extent, the mechanism of the absorbent is capillary action, 100~200 screen mesh alumina powder had the best debinding efficiency at 130℃; for the gas phase debinding temperature extent, adding some active carbon to the absorbent could control the formation of the hyperoxide barrier lay, accelerate the mass transfer rate, also enhance the debinding efficiency; studied the relationship between the debinding efficiency and the shape of the green part and the solid load; furthermore, did trial study on the solvent debinding.

发现吸附剂的组成对脱脂效率有较大影响；在液相脱脂温度段，吸附剂的作用机制为毛细管作用，100~200目的氧化铝粉末在130℃时具有最高的脱脂效率；在气相脱脂阶段，在吸附剂中引入活性碳可以抑制不利于脱脂的过氧化物阻挡层的形成，加快气相在坯体中的传质速率，进而提高脱脂效率；研究了坯体形状尺寸和装载量等因素与脱脂效率的关系；还对溶剂脱脂进行了试探性研究。

X6 3?,large specific surface area and adsorbent capacity However,most molecules and hydrated ions can not enter the aperture pass because of their size over the aperture diameter of palygorslote except less simple ones Furthermore,Palygorskite adsorbs water molecule choosingly In most cases the absorbing of palygorskite is by its outside surface that works in the form of colloid and ion exchange other than i...

但是由于凹凸棒石孔道直径小于大多数分子及水合离子的直径，除少数简单分子和离子外，多数分子和离子都不能进入凹凸棒石孔道，而且凹凸棒石选择性吸附水分子，因而在多数情况下，凹凸棒石对吸附质的吸附不是内表面吸附，而是外表面吸附。并且外表面吸附是胶体和离子交换吸附。本文阐述了凹凸棒石的孔道直径、吸附选择性、体系pH 值及凹凸棒石和蒙脱石胶体颗粒的互相作用对凹凸棒石吸附性能应用的制约。

In this paper, adsorption is firstly described as a function of CSGC, and the effects of component and their ratio of grouts, leachate environment such as temperature, pH and salinity on adsorption are studied with equilibrium experiment. The evidence shows that the adsorption mechanism of CSGC to contaminant conforming to Freundlich Adsorption Model. It provides the theory for establishing CSGC and utilizing adsorption mechanism.

本文首次将吸附性能引入防渗帷幕的功能作用，通过大量的吸附平衡试验分析了浆液配比、地下水环境和用量对帷幕吸附污染物性能的影响，研究了帷幕对污染物的吸附规律和去除特征，结果表明粘土固化注浆帷幕对污染物的吸附符合Freundlich吸附模式，为建立粘土固化注浆帷幕、充分发挥其吸附性能提供了理论基础。

Gel-type cross-linked polystyrene-isocyanuric acid resin has been obtained by reaction of chloromethylated polystyrene with isocyanuric acid under the existence of triethylamine.

由氯甲基化低交联聚苯乙烯和异氰尿酸在三乙胺作用下反应，制得了凝胶型交联聚苯乙烯-异氰尿酸树脂，测定了该树脂对苯酚和间苯二酚在不同温度下的吸附等温线，依据Clapeyron-Clausius方程从吸附等温线计算出了吸附热，从热力学的角度论证了树脂是基于氢键键合和疏水作用而吸附苯酚和间苯二酚的。

Adsorption isotherms were obtained with static adsorption method. Isosteric adsorption enthalpy, adsorption free energy and adsorption entropy were calculated according to the relationship of thermodynamic function. Isosteric adsorption enthalpy was between 29 kJ-mol"1 ~ 34 kJ'mol"1, which reveals that the main molecularly recognition interaction is hydrogen bonding.

通过静态吸附试验，测定了球状分子印迹聚合物对水溶液中茶碱的吸附等温线，利用热力学函数关系计算了球状分子印迹聚合物的等量吸附焓，吸附自由能和吸附熵，等量吸附焓在29.17 kJ·mol~(-1)～34.54 kJ·mol~(-1)之间，推测其分子识别的作用力主要为氢键作用。

The humidity resistance and the sensitivity to chemical warfare agents simulants of the tuned films were also investigated.Self-assembled LBL polyaniline films were prepared from aniline monomers by in situ polymerization and the mechanism of film formation was discussed. It was proposed that the self-assembly of polyaniline occurred through the quick absorption of aniline monomer cations or aniline monomer cation radicals on the glass surfaces by electrostatic attractions to form homogeneous polymerization centers, then increased gradually by the way of upright to the glass supports for extensity, leading to the polyaniline chain growth. The polyaniline was doped under acidic condition to absorb anionic polyelectrolyte, such as sodium polystyrene sulfonate based on the electrostatic force, or to adsorb polymer based on hydrogen-bonding interactions, for example Polyvinyl Alcohol, and then recycled to fabricate_n or_n self-assembled multilayer films.

跟踪了原位聚合的具有纳米结构的聚苯胺多层自组装膜的成膜过程，提出了该自组装膜的成膜机理：聚合反应初始阶段的苯胺阳离子或苯胺阳离子自由基通过静电作用快速吸附到带负电荷的基片表面，形成均匀的聚合中心，然后以垂直于基片的方式进行链增长生成PANI；PANI在酸性条件下经现场掺杂后带正电荷，再通过静电作用吸附带负电荷的聚电解质如聚苯乙烯磺酸钠，或通过氢键作用吸附聚合物如聚乙烯醇，这样循环LBL-SA即得到_n或_n等原位聚合聚苯胺自组装膜。

The depressing ability of the macromolecule organic depressants can be improved by the increase of their D.S.. The high D.S. CPVA and CPEG show strong depressing ability to calcite, while CPEG indicates strong depressing ability to diaspore, and HPAM to pyrite.The depressing mechanism of organic depressants was confirmed by the measurements of zeta potential, contact angles, adsorption capacity and IR spectrum.

利用动电位、接触角、吸附量和红外光谱等测试方法和手段，探讨了抑制剂的作用机理：苯氧乙酸类小分子抑制剂与方解石之间可发生较强的化学作用，可以选择性地吸附在方解石表面，使捕收剂发生解吸或阻止捕收剂在矿物表面的吸附而使矿物受到抑制；大分子抑制剂则主要是依靠亲固基吸附在矿物表面，再利用其长链的强亲水性而使矿物受到抑制。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新