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These results suggest that desorption of PEO segments and their entanglement are hindered due to the formation of hydrogen-bonding complexation between the undissociated carboxylic groups and the PEO chains.

这些结果表明由于未电离的羧酸根基团和PEO链形成了氢键,阻碍了压缩过程中PEO链节的解吸附和链节间的缠结。

The absorption characteristics and the structure at (0,0,1) plane of the 1,3,5-triamino-2,4,6-trinitrobenzene crystals of alternative copoly(vinylidene fluoride-chlorotrifluoroethylene) with various degree of polymerization has been studied by molecular dynamics simulations using compass forcefield and NVT ensemble model.

采用COMPASS力场和NVT正则系综的动力学模拟方法,搭建了聚合度分别为10, 50和100的偏氟乙烯/三氟氯乙烯交替共聚物,对交替共聚物在1,3,5-三氨基-2,4,6-三硝基苯的(0,0,1)晶面上的吸附和结构进行了分子动力学模拟。

In order to understand the mechanisms of cation surfactant changing the wettability of solid surface, the effect of CTAB on the wettability is studied based on washburn method and microscopic experiments.

为了解阳离子表面活性剂改变固体表面润湿性的机理,首先用washburn法和微观实验研究了十六烷基三甲基溴化铵对润湿性的影响,然后从吸附状态及化学反应的角度分析了CTAB与砂岩表面的作用机理。

Regarding polyurethane varnish as host of the formaldehyde absorbent,mainly aminoacetic aicd , casein, tannins, L - glutamate, DL - a - amino acid, urea, hexamethylenetetramine, lignin and molecule are chosen to serve as formaldehyde absorbent.

以硝基清漆为吸收基质,主要选择了如氨基乙酸、干酪素、鞣质、L-谷氨酸、DL-α氨基丙酸、尿素、六次甲基四胺、木质素、分子筛等作为甲醛吸收剂,涂布于聚氯乙烯胶片上做甲醛吸收测试;根据测试结果,制作的甲醛吸附剂能起到较好的甲醛吸收效果;并探讨了硝基清漆中吸收剂用量的筛选及吸收时间对甲醛消除的影响因素。

The isolation ability of AB-8 macroporous adsorption resin for total flavones of Ficus carica was studied by examining the characteristics of adsorption and desorption.

研究了AB-8大孔树脂对无花果总黄酮的吸附和解吸的特性,并考察了相关的工艺条件。

The expressions of current density and the Faradaic Impedance for the three-step electrode processes involving chemical adsorption,charge transfer and desorption steps in the presence or absence of a chemical competitive reaction have been derived in terms of linear condition in this paper,by which the effect of the chemical competitive reaction on the main reaction was analyzed.

在线性条件下,推导了由化学吸附、电荷传递、化学脱附三步骤的电极过程在有化学竞争反应条件下的电流密度和法拉第阻抗的表达式,分析了不同条件下化学竞争反应对主反应的影响,并使用等效电路对可能出现的阻抗结果进行了理论描述。

Isosteric heats of methane adsorption on activated carbon were determined from our experimental adsorption isotherm of methane by using the Clausius-Clapeyron equation.

讨论了活性炭床温度、充气量及充气效率等的变化规律,并对缓减吸附热引起的充气量下降的措施进行了数值模拟。

Electrochemical behaviors on the surface of jamesonite in an acidic solution of pH4.0 buffer solution containing diethyl dithiocarbamate were investigated by the methods of cyclic voltammetry and AC impedance.The changes of the reactions,electrochemical adsorption,passivation action,electrochemical impedance and interfacial capacitance on jamesonite were discussed under the different conditions of electrode potentials.

用循环伏安和交流阻抗法,研究了脆硫锑铅矿在含乙硫氮的pH 4.0缓冲溶液中的表面电化学行为,讨论了在不同电位下脆硫锑铅矿表面的反应、电化学吸附、钝化作用、电化学阻抗、微分电容的变化。

Experimental results indicate that a kind of lignosulphonate, which has a water reducing rate of 15.2%, with —OH and —SO3 groups, can be obtained by oxidation and sulphonating straw pulp lignin, and that MLP has better adsorption-dispersion ability to cement grains by electrostatic repulsion.

论文摘要:为开发利用草浆碱木素,通过引发氧化和磺化制备了改性草浆碱木素减水剂,测定了MLP的红外光谱、MLP在水泥颗粒表面的吸附量、水泥ζ-电位、MLP水溶液的表面张力及掺MLP的水泥净浆流动性,并测定了掺MLP的混凝土性能。

The total of 36 compounds were characterized by X-ray single crystal diffraction, EA, TG, IR, luminescence, adsorption, XPS, powder XRD, M〓ssbauer spectra, EPR, magnetical measurements.

本论文利用水热法,成功设计和合成出三个系列Ln-M(M=Mn〓,Fe〓,Ag〓)共23个未见文献报道的稀土—过渡混合金属配位聚合物,同时也得到了结构新颖的仅含稀土或两种不同过渡金属的从一维到三维的聚合物13个,并对它们进行了结构、元素分析、热重分析、红外光谱、荧光、吸附、磁性、光电子能谱、粉末衍射和M〓ssbauer谱等表征。

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