吸附了的

The adsorption isotherm of neptunium on silica gel correspond to the form of Langmuir isotherm. According to Clausius-Claperon equation,from the slope in InKd vs 1/T plot,adsorption heat could be estimated. From the data of adsorption heat it is concluded that the adsorption of neptunium on silica gel in nitric acid solutions belongs to chemical adsorption and the adsorption process is an endothermic reaction.

三种价态的镎在硅胶上吸附的等温线符合兰格缪尔吸附等温线的形式，是单分子层吸附；根据克劳修斯-克拉柏龙方程，以1nKd对1／T作图，通过直线斜率计算出吸附热，从吸附热的数据可判断三种价态的镎在硅胶上的吸附属于化学吸附，是吸热的过程；对NpOV）、Np和Np（VD在硅胶上的吸附进行了比较，提出了三种价态的锋在硅胶上吸附的机理。

The result showed that the optimal condition of inorgano-absorbent manufacture as following: concentration of vitriol is 15%, the bentonite carrier must be soaked in the 0.4% La(superscript 3+) solution, the pH is 10, microwave radiation power is 340 W for 5 min. The optimal condition of organo-absorbent manufacture process as following: concentration of CTMA is 5%. The rate of wave must 166 W and the time of radiation is 6 mi In addition, the experimental results showed that with inorgano-absorbent the pH number is 3~6 and the reaction time is 45 min, the removal efficiency of phosphor will be up to 99% and the amount of adsorption will be up to 41 mg/g. And with organo-absorbent the pH number is 3~4 and the reaction time is 45 min, the removal efficiency of phosphor is more 30% than that of inorgano-absorbent. The removal efficiency of phosphor will be up to 99% and the number of adsorption will be up to 60 mg/g.

实验表明：①制备无机稀土吸附剂的适宜条件为：硫酸浓度15%，镧浓度0.4%，浸渍pH值10，微波功率340 W，辐射时间为5 min；②制备有机稀土吸附剂的适宜条件为：表面活性剂浸泡浓度为5%，微波功率为166 W，微波辐射时间为6 min；③无机稀土吸附剂当溶液的pH值为3~6，振荡时间为45 min时，对磷去除率为99%以上，吸附量达到了41 mg/g以上，有机稀土吸附剂当溶液的pH为3~4，振荡时间为45 min时，其效果比原来镧改性的无机吸附剂吸附量提高了30%，磷去除率为99%以上，吸附量达到了60 mg/g以上。

Different mechanisms and model of the sorption of organic compounds by soli /sediment in combined polluted environment were reviewed, including many factors which influence the sorption.

本文评述了复合污染中有机物在土壤/沉积物上的吸附机理及影响吸附的主要因素，主要论述了共存物质及环境条件对有机物吸附行为的影响，同时，总结了表面活性剂在土壤/沉积物上的吸附机理和吸附模型，探讨了影响表面活性剂吸附的因素，评述了表面活性剂对有机物在土壤/沉积物上吸附行为的影响及机理。

The yeast of Saccharomyces cerevisiae is an ideal biomaterial to be used for exploring the mechanism and for actual util...

结合自己的研究成果，总结了酿酒酵母作为生物吸附材料的优点、研究中的表现形式和吸附性能，重点讨论了酿酒酵母生物吸附机理，介绍了等温吸附平衡模型和动力学模型在酵母生物吸附中的应用情况。最后提出生物吸附进一步的研究方向。

X6 3?,large specific surface area and adsorbent capacity However,most molecules and hydrated ions can not enter the aperture pass because of their size over the aperture diameter of palygorslote except less simple ones Furthermore,Palygorskite adsorbs water molecule choosingly In most cases the absorbing of palygorskite is by its outside surface that works in the form of colloid and ion exchange other than i...

但是由于凹凸棒石孔道直径小于大多数分子及水合离子的直径，除少数简单分子和离子外，多数分子和离子都不能进入凹凸棒石孔道，而且凹凸棒石选择性吸附水分子，因而在多数情况下，凹凸棒石对吸附质的吸附不是内表面吸附，而是外表面吸附。并且外表面吸附是胶体和离子交换吸附。本文阐述了凹凸棒石的孔道直径、吸附选择性、体系pH 值及凹凸棒石和蒙脱石胶体颗粒的互相作用对凹凸棒石吸附性能应用的制约。

The results of the present research are as follows, The correlation between physico-chemical properties of organic compounds and their competitive power was studied, and it was indicated that organic compounds preferable to form H-bonding with organic matter of sorbents have stronger competitive power; Sorption behaviors of ionizable organic compounds in different species and their competitive power were examined, and the results showed that phenols and carbonxylic acids with benzyl circle have much stronger competitive power in molecular species than in ionized species, because negative charges of anionic forms can depressed their adsorption on the surface of the sediment; in contrast, organic bases such as aniline and p-chloroaniline show weaker competitive power in molecular species than in ionized species, and this is because both species of the organic bases could adsorb strongly onto the sediment; there is a correlation between competitive power of organic pollutants in multi-solute systems and their sorption isotherm nonlinearity in single-solute systems, and organic compounds whose sorption isotherms is linear in single-solute systems hardly have competitive power in multi-solute systems; Competitive sorption effects in more than two-solutes systems was studied, and it was exhibited that mixture of two cosolutes each of which could suppress sorption of nominal solute onto the sediment had synergistically competitive sorption effect on the nominal solute; A method about incorporating sorption/desorption of organic pollutants into river water quality model was developed, and discussion about degree of sorption/desorption effect on model prediction for different organic compounds was made, which will provide theoretical basis and practical processes for setting up more accurate water quality model.

论文主要取得了以下研究成果。(1)有机化合物的吸附竞争能力与其物化性质具有相关性，易与沉积物有机质形成氢键的化合物其竞争能力也比较强；(2)可离子化有机化合物的吸附竞争能力与其存在形态有关。酚类、含苯环的羧酸类化合物，其离子态的吸附竞争能力远小于分子态，其机理为有机酸阴离子所带的负电荷抑制了表面吸附能力，主要发生分配作用；而苯胺类化合物，其离子态和分子态都表现出显著的竞争能力，而且离子态的竞争能力略强于分子态，原因在于有机碱阳离子所带的正电荷促进了其表面吸附能力；有机化合物竞争能力的强弱与其单组分吸附等温线的非线性程度具有一定的相关性，吸附等温线近似为线性的化合物没有或只具有微弱的竞争能力；(3)对目标有机化合物的吸附具有竞争效应的有机化合物混合后，将对目标有机化合物的吸附产生协同竞争效应；(4)以京杭运河为例，率先提出了将有机污染物的吸附／脱附作用及水文水力参数耦合到水质模型中的方法，并讨论了吸附／脱附作用对不同有机污染物预测模型的影响，为建立更准确的水质模型及进行更客观的风险和生态评估提供了参考依据。

The results show that the optimal value of CoCl2 concentration is 0.2 mol/L and the maximum adsorbed amount is 19.674 mg/g onto this adsorbent. The adsorption capacity of phosphine onto CoCl2-modified ACF decreases with the increase of temperatures. The maximum absorbed amounts are 19.674 mg/g at 298 K, 13.537 mg/g at 313 K and 11.087 mg/g at 328 K, respectively. It is found that the Freundlich equation is more suitable for the description of phosphine adsorption process than the Langmuir equation. The isosteric heat of adsorption decreases with the increase of the surface loading on CoCl2-modified ACF, which means that CoCl2-modified ACF adsorbent has an energetically heterogeneous surface. Meanwhile, adsorptive phosphine removal performance may be a dominant of physical adsorption when the heat of adsorption is 16-24 kJ/mol, the CoCl2-modified ACF adsorbent will be one of the candidates for tail gas purification of airtight calcium-carbide furnace and recycle of phosphine.

研究结果表明：浸渍液浓度最佳值为0.2 mol/L，此改性ACF对PH3的饱和吸附量为19.674 mg/g；PH3在CoCl2改性ACF上的吸附量随温度升高而迅速降低，在298，313和328 K时PH3的饱和吸附量分别为19.674，13.537和11.087 mg/g；Freundlich吸附等温方程较好地模拟了PH3在改性ACF上的等温吸附；PH3气体在改性ACF上的等量吸附热随吸附量的增大而减小，表明改性ACF吸附剂表面能量的不均匀性；吸附热在16~24 kJ/mol范围内，过程为物理吸附，有利于密闭电石炉尾气的净化。

Hydrophobic-hydrophilic macroporous polydivinylbenzene/polyacrylethylenediamine interpenetrating polymer networks (PDVB/PAEM IPN) were prepared by the sequential suspension polymerization method. These were composed of two networks, of which one was hydrophobic and the other was hydrophilic. The objective of this work was to study the adsorption thermodynamics and adsorption kinetics of this hydrophobic- hydrophilic IPN. The focus was on adsorption isotherms of vanillin at different temperatures, and these fit well into the Freundlich adsorption isotherm. The isosteric adsorption enthalpy, adsorption Gibbs free energies and the adsorption entropy could be calculated according to thermodynamic functions.

采用分步悬浮聚合法制备了具有疏水性能的聚二乙烯基苯(polydivinylbenzene， PDVB)为第一网，具有亲水性能的聚丙烯酰乙二胺(polyacrylethylenediamine， PAEM)为第二网的疏水／亲水大孔聚二乙烯基苯／聚丙烯酰乙二胺互穿聚合物网络(interpenetrating polymer networks， IPN)，研究这类疏水／亲水IPN组成的树脂对吸附质的吸附热力学和吸附动力学；测定了该树脂对香兰素在不同温度下的吸附等温线，吸附等温线符合Freundlich等温吸附方程，利用热力学函数关系计算出了吸附焓、自由能和熵变。

First, we investigate the methods of sepiolite s purification from ore , from which we get the incompact short fibrous sepiolite for the experiment ; the prime activatited term is also obtained through this experiment. We use activated sepiolite to process the absorption experiment on heavy meatal ion ( Ni2+, Cr6+, Pb2+, Cu2+, Cd2+), noble metal ion, dynamite cotnposton in water and industrial oil. we take Ni2+ for example to confirm the prime adsorbent term , from the experiment we get the adsorbent isotherm . Make the dynamic absorption experiment and regenerate experiment using sepiolite on the heavy metal(Ni2+) on the base of static absorption experiment.

我们首先研究了从矿石中提纯海泡石的方法，制得供实验用的松散短纤维状海泡石；通过实验确定了最佳活化条件；进行了活化后的海泡石对重金属离子Cr~(6+、Pb~(2+)、Cu~(2+)、Cd~(2+)、贵金属离子、水中炸药组份、工业油的吸附实验；以Ni~(2+)为例选择了最佳吸附条件；通过实验作出了以上各组分的吸附等温线；在静态吸附实验的基础上进行了海泡石对重金属Ni~(2+的动态吸附实验及再生实验。

Results show that the mycelium is better than the peanut hull in the preparation of the surface coating chitosan adsorbent; the adsorptive capacity of Ni2+ by the surface-coated adsorbent increased by 50%, compared with the mycelium adsorbent.

系统研究了菌丝体包覆吸附剂的制备工艺及吸附剂对Ni2+的吸附特性，结果表明，菌丝体作核心材料优于花生壳，菌丝体包覆吸附剂对Ni2+的吸附容量比普通菌丝体水处理剂提高了50%，并可以重复使用10次，吸附容量没有明显降低；同时菌丝体包覆吸附剂对Ni2+的吸附特性较好地符合Langmuir 等温方程和Freundlich等温方程。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。