吸附

While the adsorptions of 1-propanol and 1-Br-propane at 100℃ give rise to 1-propoxy species, which mainly converted to propanal at higher temperature. IR spectrum arising from the interaction of propene with the catalyst at 100 ℃ shows the IR bands of allyl alcoholate and isopropoxy species. As the temperature was increased to 150℃, the bands ascribable to the adsorbed acetone and acrolein were observed. Based on these results, it is suggested that isopropoxy species is one of the intermediates for SOP to acrolein over MoPO/SiO〓 catalyst.

2原位IR光谱实验结果表明：200℃时丙烷/O〓混合气在催化剂表面吸附后的IR谱与同温度下异丙醇吸附的IR谱相似，均检测到吸附态丙酮物种和丙烯醛物种的IR谱峰；溴代异丙烷和异丙醇在催化剂表面吸附后均转化为异丙氧基，异丙氧基主要转化为丙烯和丙酮，丙烯进一步转化为丙烯醛；溴代正丙烷和正丙醇在催化剂表面吸附后均转化为正丙氧基，正丙氧基主要转化为丙醛；丙烯在催化剂表面吸附后转化为σ-氧烯丙基和异丙氧基，升温后σ-氧烯丙基转化为丙烯醛而异丙氧基转化为丙酮。

Different mechanisms and model of the sorption of organic compounds by soli /sediment in combined polluted environment were reviewed, including many factors which influence the sorption.

本文评述了复合污染中有机物在土壤/沉积物上的吸附机理及影响吸附的主要因素，主要论述了共存物质及环境条件对有机物吸附行为的影响，同时，总结了表面活性剂在土壤/沉积物上的吸附机理和吸附模型，探讨了影响表面活性剂吸附的因素，评述了表面活性剂对有机物在土壤/沉积物上吸附行为的影响及机理。

The function mechanism among the minerals and floatation drugs had been studied with the way of IR and academic calculation, which pointed out that absorption of G-4 on the surface of phosphorite belonged to physical and chemical types, but the chemical one was in the highest flight. Absorption of amine collector named GE-609 on the surface of quartz belonged to electrostatic and physical type. Distilled water could hardly wash the GE-609 down from the surface of quartz. Leading component of S-721 was the concentrated compound of naphthol sulfonic acid and formaldehyde. The compound had a stronger affinity to the Mg~(2+) on surface of dolomite than the Ca2+ on surface of phosphorite, which is the essential reason in the separation of phosphorite and dolomite. The leading components of soluble glass in function were HSiO3 hydronium and F^SiC^ colloid granule.

通过红外光谱测定以及理论计算的方法研究了选矿药剂与矿物间的作用机理，研究表明：脂肪酸捕收剂G-4对胶磷矿的捕收作用是以化学吸附为主、化学吸附与物理吸附共同作用的结果；胺类阳离子捕收剂GE-609在石英表面的吸附属于静电物理吸附，但很难用水洗的方法使GE-609从石英表面脱附；S-721主要成分为萘酚磺酸与甲醛的缩合物，萘酚磺酸与甲醛的缩合物对白云石表面Mg~(2+)的吸附明显强于对胶磷矿表面Ca~(2+)的吸附，这是胶磷矿与白云石分离的根本原因；水玻璃溶液中对石英起抑制作用的主要组分是HSiO_3~-和H_2SiO_3胶粒，水玻璃除对石英起抑制作用外，对矿浆还具有一定的分散作用。

At the heavy metal concentration of 3-4ppm, our study on adsorption capacity, adsorption selectivity of montmorillonite, illite and kaolinite to Cu〓、 Pb〓、 Zn〓、 Cd〓、 Cr〓 shows that the adsorption capacity is mainly determined by the capacity of exchangeable cations and the adsorption capacity of the three clay minerals decreases in this sequence: montmorillonite ＞＞ illite＞kaolinite. It is found that clay minerals have obvious adsorption selectivity to various heavy metals. Montmorillonite exhibits a stronger affinity to Cr〓 and Cu〓 while kaolinite and illite sorb Cr〓 and Pb〓 more effectively. At the same heavy metal concentration, adsorption amount of clay minerals to heavy metals increase with increasing pH value of the solution.

在痕量浓度下，研究了蒙脱石、伊利石、高岭石三种粘土矿物对Cu〓、Pb〓、Zn〓、Cd〓、Cr〓五种重金属离子的吸附容量、吸附选择性及其介质条件对吸附量的影响，结果表明，粘土矿物的阳离子交换容量越大，对重金属离子的吸附容量也越大，其大小顺序为蒙脱石＞＞伊利石＞高岭石；同时，不同粘土矿物对重金属离子具有明显的吸附选择性，蒙脱石对Cr〓和Cu〓有较好的选择性，伊利石和高岭石则对Cr〓和Pb〓有较好的选择性；随着吸附溶液pH值的增大，其吸附量有增加的趋势。

In this paper, adsorption is firstly described as a function of CSGC, and the effects of component and their ratio of grouts, leachate environment such as temperature, pH and salinity on adsorption are studied with equilibrium experiment. The evidence shows that the adsorption mechanism of CSGC to contaminant conforming to Freundlich Adsorption Model. It provides the theory for establishing CSGC and utilizing adsorption mechanism.

本文首次将吸附性能引入防渗帷幕的功能作用，通过大量的吸附平衡试验分析了浆液配比、地下水环境和用量对帷幕吸附污染物性能的影响，研究了帷幕对污染物的吸附规律和去除特征，结果表明粘土固化注浆帷幕对污染物的吸附符合Freundlich吸附模式，为建立粘土固化注浆帷幕、充分发挥其吸附性能提供了理论基础。

Hydrophobic-hydrophilic macroporous polydivinylbenzene/polyacrylethylenediamine interpenetrating polymer networks (PDVB/PAEM IPN) were prepared by the sequential suspension polymerization method. These were composed of two networks, of which one was hydrophobic and the other was hydrophilic. The objective of this work was to study the adsorption thermodynamics and adsorption kinetics of this hydrophobic- hydrophilic IPN. The focus was on adsorption isotherms of vanillin at different temperatures, and these fit well into the Freundlich adsorption isotherm. The isosteric adsorption enthalpy, adsorption Gibbs free energies and the adsorption entropy could be calculated according to thermodynamic functions.

采用分步悬浮聚合法制备了具有疏水性能的聚二乙烯基苯(polydivinylbenzene， PDVB)为第一网，具有亲水性能的聚丙烯酰乙二胺(polyacrylethylenediamine， PAEM)为第二网的疏水／亲水大孔聚二乙烯基苯／聚丙烯酰乙二胺互穿聚合物网络(interpenetrating polymer networks， IPN)，研究这类疏水／亲水IPN组成的树脂对吸附质的吸附热力学和吸附动力学；测定了该树脂对香兰素在不同温度下的吸附等温线，吸附等温线符合Freundlich等温吸附方程，利用热力学函数关系计算出了吸附焓、自由能和熵变。

Different compound adsorbents thermal conductivities were measured at different adsorption capacities.It got these conclusions: At the same adsorption capacity,the compound adsorbents thermal conductivities increase with the quantities of the silicate sol contents increase.The compound adsorbents thermal conductivities increase sharply during the silicate sol contents vary between 0%～(7.5%).The therm...

试验结果表明：在同一吸附量的情况下，导热系数与其添加的粘结剂含量正相关，并且在w=0%~7.5%的添加粘结剂范围内导热系数随着粘结剂含量增加而显著增加；13X沸石原粉、复合吸附剂样品Z1和Z2的导热系数随其吸附量增加呈近似线性增长，当吸附量从0%增加到25%时，各吸附剂导热系数均增加了150%以上；配置出复合吸附剂Z1和Z2在分别添加w=5.0%和7.5%的添加剂下，平均导热系数分别为0.183和0.199 W/，比13X原粉分别提高65.4%和80.1%；将配置的复合吸附剂Z2应用于太阳能冷管，其制冷系数COP约为

By comparison of eight micro adsorption, A resin with high adsorption rate and eluent rate was used to adsorb chlorogenic acid from extraction solution. The adsorption parameters are: the content of chlorogenic acid is 0.204 mg per mL adsorption solution, the acidity of adsorption solution is 4, the adsorption velocity of flow is 3 mL per min, the eluent is 30% ethanol, the eluting speed is 1.5 mL per min and the eluents volume is 4 times of resin volume. In the optimal adsorption condition, the final yield of CHA is 5.06%. the content of chlorogenic acid is 78.26% in dry productin.

通过对比8种大孔吸附树脂对绿原酸的吸附效果，选用对绿原酸吸附解吸性能均较好的树脂对绿原酸吸附，吸附参数如下：吸附液绿原酸的浓度为0.204mg／mL、吸附液pH值为4、流速为3mL／min，解吸参数如下：解吸剂为30％乙醇、解吸剂流速为1.5mL／min、解吸剂使用量为4倍树脂体积，在此条件下，绿原酸得率为5.06％，产物中绿原酸含量为78.26％。

Could be used as an efficient biosorbent for removal of heavy metal ions from aqueous solution and that the process was strongly affected by pH.

研究发现，溶液pH值对吸附过程有较大影响，最佳吸附pH值在5.5附近；最佳吸附温度为25～35℃；溶液浓度在10～500mg·L^-1范围内，固定化简青霉菌对重金属的吸附随金属离子浓度的增加而增加；吸附过程符合Langmuir等温吸附模型；生物吸附平衡时间约为60min。

Four different sorbents (CaSO4, kaoline, CaCO3 and bauxite) were used to make the control test of heavy metals; and different sorbents were found to have different adsorption of heavy metal. These sorbents not only had physical adsorption of heavy metals but also had chemical reaction between sorbents and heavy metals.

添加无水CaSO4，高岭土，铝土矿，无水CaCO3 4种不同的吸附剂，发现不同的吸附剂对不同的重金属有不同的吸附作用。4种吸附剂对重金属元素的吸附既有物理吸附，又有吸附剂与重金属之间的化学反应。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。