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The experimental results show that:Under the conditions of reaction temperature 350℃,space velocity 4 800 h~(-1)and volume ratio of air to waste gas 15,the conversion rates of chloromethane and total hydrocarbon are all larger than 99%;There is almost no phosgene generation;HCl in the tail gas of oxidation can be well absorbed by NaOH solution;The activity of the catalyst usingγ-Al_2O_3 a...

实验结果表明:在反应温度为350℃、空速为4 800 h~(-1)、空气与氯甲烷废气的体积比为15的条件下,氯甲烷转化率和总烃转化率均大于99%,催化氧化过程中基本不产生光气;催化氧化反应后尾气中的HCl用NaOH溶液作吸收剂的吸收效果较好;γ-Al_2O_3为载体的催化剂活性基本稳定。

The wastewater from gum benzion production contains benzaldehyde, cyanide, gum benzoin and ethyl benzoate. When the cyanide is determined by isonicotinic acidpyrazalon method, the ethyl benzoate is distilled and goes into NaOH absorption liquid with cyanide in the process of predistillation, because its boiling point is low. Thus the absorption liquid produces a great deal of foam and feculence.

摘要]有机化工产品安息香生产废水中含有苯甲醛、氰化物、安息香和苯甲酸乙酯,在用异烟酸吡唑啉酮法对其进行氰化物测定时,由于油酯类的沸点较低,在预蒸馏过程中被蒸出和氰化物一起进入NaOH吸收液,使得吸收液产生大量泡沫和沉淀,严重干扰后续比色测定。

In this paper the key points discussed were that, under the condition of a sharp hypsography of desert areas of Ordos basin, we used some new geophysical methods in the investigation of surface structure to obtain high accurate surface structure data and provide reliable scientific foundation for data acquisition and process; we dealt with the optimum coupling of surface geophones and the digital realization technique in desert areas, dug into a method of high frequency compensation according to attenuations by absorption near surface, adopted data processing and correction technique, solved high frequency attenuation and geophone coupling, eliminated the influences of sharply transverse fluctuation of hypsography in desert area on the seismic data, enhanced the fidelity and SNR of seismic section, and finally picked up more geologic information on the seismic profile and improved the precision of the lateral prediction for the reservoir beds.

本文旨在研究鄂尔多斯盆地沙漠区地表变化比较大的情况下,在表层结构调查中通过应用一些地球物理新方法,以获取高精度的表层结构数据,为资料采集和数据处理提供更科学的依据;研究在沙漠区地表检波器最佳耦合的方式与数字实现技术,研究通过近地表的吸收衰减规律进行高频补偿的方法,采用数据处理校正技术,解决高频吸收及检波器耦合,消除沙漠区表层横向剧烈变化对地震资料的影响,提高地震剖面的保真度和信噪比,从而使更多的地质信息能够从地震剖面中反映出来,提高储层横向预测的精度。

HBTMPDTP-TBPkerosene keeps its ability to separate Am from lanthanides till a total dose of 10〓Gy, which is one order of magnitude higher than that of HBTMPDTP-kerosene.

HBTMPDTP-TBP-煤油具有良好的辐照稳定性,吸收剂量小于10〓Gy时,萃取性能不变,允许吸收剂量比HBTMPDTP-煤油提高一个数量级。

The results showed that nutrient ions were further absorbed and transported selectively and the harmful ions of salt were further restrained with the application of nitrogen and phosphorus. It is an effective way to increase saline tolerance and seed yield of oil sunflower by the use of nitrogen and phosphorus in the coastal mudflat of northern Jiangsu.

说明N肥和P肥的施入增强了油葵对营养离子的选择性吸收与运输,抑制了油葵对盐害离子的选择比吸收与运输,表明在苏北沿海海涂上施用肥料能够改善油葵营养状况并增强油葵耐盐性,对于增加油葵籽粒产量是一个很有效的办法。

The conclusions were as follows: theνO-H andνC=O IR absorption maxima shifted towards higher wave numbers after imprinting 17β-estradiol on TFMAA-co-TRIM copolymer with the red shift of theνO-H groups being apparent after precipitation polymerization for 16h while that forνC=O groups being observed after polymerization for 24h. A strong interaction between TFMAA and 17β-estradiol was confirmed by the high selectivity for 17β-estradiol, as indicted by the values of the separation factor of isomers of 17β-estradiol/17α-estradiol (2.28) and the imprinted factor (3.01). Particle diameter of TFMAA-co-TRIM polymer was between 300 nm and 1.5μm, which suited well for solid phase sorbent throughout at low column pressure. The recognition of imprinting TFMAA-co-TRIM polymer for sterol molecules was driven by enthalpy eluted with acetronitile, and low temperature was in favor of the separation of sterol structure analogues on imprinting column. TFMAA-co-TRIM polymer possessed of determinate anti-heat stability, with melting point beginning at 255.84℃, Tp=257.40℃, control TFMAA-co-TRIM polymer and imprinting TFMAA-co-TRIM polymer were respectively decompounded at 267.79℃and 343.11℃, and solid micro-extraction noddle prepared by the special polymerization also showed definite recognition for 17β-estradiol by GC/MS detecting at 270℃. By selection of various washing and elution solvents, elution reagents of close polymerization system were of more advantage in template molecules retention and recognition on molecularly imprinted solid phase extraction column. At a certain extent, progesterone, 17α-estradiol, 17β-estradiol and 4-androstene-3, 17-dione could be intercepted on the MISPE column. Especially, MISPE had high selectivity for progesterone, and imprinting TFMAA-co-TRIM polymer could achieve adsorption balance within 50 min by absorption kinetics test for 17β-estradiol. However, MISPE column showed better selectivity and enrichment property for 17β-estradiol than C18 and CSPE columns according to the data from HPLC and GC/MS analyses. Recovery of 17β-estradiol on MISPE column was up to 85.5% while when prime extracting solution of milk powder was sampled, the recovery of CSPE and C18 columns were 43.7% and 30.7%, respectively.

通过研究阐明:紫外聚合产物TFMAA-co-TRIM中的νO-H振动吸收峰在聚合16h后红移,νC=O振动吸收峰在聚合24h后红移;TFMAA-co-TRIM对雌二醇异构体的印迹因子达到了3.01,α为2.28,优于其它功能单体参与得到的聚合物识别特性;TFMAA-co-TRIM聚合物粒径介于300 nm至1.5μm之间,作为色谱固定相具有良好的通量和低的柱压;在乙腈流动相中,TFMAA-co-TRIM分子印迹固定相的分离过程主要被焓驱动,低温有利于分子印迹固定相分离甾醇结构类似物;TFMAA-co-TRIM分子印迹聚合物在255.84℃时开始熔融,Tp=257.40℃,聚合物CP的降解温度在267.79℃,MIP降解温度在343.11℃,制备的固相微萃取头初步经GC/MS 270℃的耐热性测定;不同的洗提溶剂筛选证明了选择接近聚合溶剂的洗脱体系更有利于MISPE发挥识别效应;分子印迹固相萃取柱对孕酮、17α-雌二醇、17β-雌二醇和雄烯二酮都具有不同程度的保留特性,可作为此类化合物的吸附材料,特别对孕酮强保留的富集特性,可作为孕酮的选择性识别吸附剂,其分子印迹聚合物对17β-雌二醇的吸附动力学测定显示在50 min内基本达到吸附平衡,具有作为传感器核心敏感材料的潜力;对比萃取奶粉中17β-雌二醇性能,MISPE柱比非分子印迹固相萃取柱和C18柱具有更高的保留,回收率依次为85.5%,43.7%和30.7%。

The method is easily realized with small computation amount,and its absorption effect is better than conventional paraxial approximation absorption boundary condition.

该方法简单易行,计算量小,而吸收效果比常规旁轴近似吸收边界条件更好。

In addition, the two-photon absorption cross section σ non-linearly increased with a ratio of 1∶2.8∶3.7, which is near to the ratio of the square of branching number n2 (1∶2.25∶4), indicating a remarkable cooperative enhancement of σ in the multi-branched pyrazine derivatives.

另外, 从双支到四支结构,双光子吸收截面σ按照1∶2.8∶3.7的比例增加,接近于支链数目的平方之比(1∶2.25∶4),表明多支结构的双光子吸收存在显著的增强效应,其中四支结构的σ值为1007 GM。

Character: Yellowish or yellow crystalline powder,smell-less; Assay: 98.0%—102.0%; Specific Optical Rotation:+63.0°to +69.0°; Ph:3.0 to 5.0;Clarity of Solution complies with the standard. Related Substance:(Single impurities≤0.5%; total impurities≤1.5%);Methanol:≤0.3%;Dichlormethane≤0.06%Acetone≤0.5%;walter:7.0%—9.5%; Residue on Ignintion:≤0.1%; Heavy Metals:≤0.0002% Identification:Most absorb at the wavelength 220nm,256nm,370nm; The infrared spectrogram according to the comparison; positive reflection

特征及特性:淡黄色或黄色结晶性粉末,无臭;含量98.0%—102.0%;鉴别:1)在220nm、256nm、370nm的波长处有最大吸收;2)供试品溶液在主峰的保留时间与对照品溶液主峰的保留时间一致;3)供试品红外光吸收图谱与对照品的图谱一致;4)呈正反映;比旋度:+63.0°至+69.0°;酸度:3.0—5.0;溶液颜色符合规定;有关物质:(单个杂质≤0.5%;总杂质≤1.5%)甲醇:≤0.3%;二氯甲烷:≤0.06%;丙酮:≤0.5%;水分:7.0%—9.5%;炽灼残渣:≤0.1%;重金属:≤0.0002

Two new Raman spectral lines of I_2 in benzene solution are found in the experiment which is proved that resonance absorption Raman spectrum by liquid-core optical fiber much stronger than resonance absorption Raman spectrum by absorption tube.

发现了两条新的属于碘分子的拉曼谱线,这证明了使用液芯光纤方法获得的共振吸收拉曼光谱比吸收池方法获得的谱线强度强很多倍。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力