吸光系数

IR, UV-Vis, 1H NMR The IR, UV-Vis and 1H NMR of selenadiazoles were investigated. Their IR peaks were classified as the corresponding groups or bonds; The relation of their structure with the conjugative effects, absorbtion wavelength and molar absorb coefficients were discussed with the UV-Vis. The value of selenadiazoles in analytical chemistry and the varieties of structure with the pH were discussed.

IR，UV-Vis，~1H NMR 对硒二唑类化合物的IR吸收峰进行了归类与指认，讨论了SPO、SPDO的异构体的分子结构；探讨了UV-Vis、吸收波长和摩尔吸光系数与分子结构的相对应关系，以及紫外吸收光谱性质在分析化学上的应用价值和溶液的pH值引起SPO、SPDO的结构变化。

Dual wavelength method and Balance dialysis method were expounded and the experimental results were consentaneous compared with molar wavelength ratio.

研究发现，PVP-BPB缔合物的结合比为nBPB∶nPVP=1∶10，表观摩尔吸光系数ε=4.55×104L/，PVP与BPB作用的条件平衡常数K=4.32×103。

Electron donating substituent CH〓, OCH〓 and 4, 5-benzo make λ〓 red shift, electron with -drawing substituent F, Cl and CF〓 make λ〓 hypsochromic shift; b The W〓 is bigger than relative symmetrical carbocyanines, and the ratio of 0-1＇ and 0-0＇ transition intensity increase with the increase of σ〓; c The absorption and the fluorescence spectra are mirror image, and the λ〓 have a good linear relationship; d The Stokes shift △λ〓 and the Hammett σ〓 constant have a good linear relationship.

研究了染料的光物理性质，①苯环上取代基影响染料的λ〓和摩尔消光系数，相对于H，给电子取代基CH〓、OCH〓、4，5-benzo使λ〓红移，摩尔消光系数减小，吸电子取代基F、Cl、CF〓使λ〓蓝移，摩尔消光系数减小；②化合物吸收峰的半峰宽较相应的对称染料的大，且振动肩部与最大吸收峰的强度比随σ〓增大而增大；③吸收光谱与荧光光谱呈镜像关系，且λ〓与λ〓呈良好的线性关系；④化合物的Stokes位移△λ〓与取代基的Hammett σ〓常数呈线性关系。

Under the optimum conditions, the liner range is 0 to 200 mg/L for BSA and 0 to 125 mg/L for HSA, the molar absorptivity is 1.61×10^5 Lmol^(-1)cm^(-1) for bovine serum albumin and 1.75×10^5 Lmol^(-1)cm^(-1) for human serum albumin. Based on this, a new method is proposed to determine protein. After the method is applied in the determination of the total proteins in real human serum samples, the results are in good agreement with the Kjeldahl method.

在确定的最佳试验条件下，BSA浓度在0~200 mg/L、HSA在0~125 mg/L范围内符合比尔定律，对BSA和HSA的摩尔吸光系数ε567分别为1.61×10^5和1.75×10^5Lmol^(-1)cm^(-1)，据此建立了一种测定蛋白质的新方法，用于人血清样品中总蛋白的测定，结果与凯氏定氮法基本一致。

The chromogenic reaction of cetyltrimethyl ammonium bromidewith 2,4,6-tri nitrophenol was studied.

生成的缔合物在4 2 0 nm处有最大吸收，表观摩尔吸光系数为1.6×10 4 L·m ol- 1 ·cm- 1 ，苦味酸浓度在0～12 0μg·m L- 1 范围内符合朗伯-比尔定律，此法可应用于DDNP废水中硝基酚类的测定。

In the acid medium,residual chlorine discolors the methyl orange whose biggest wave length of absorption is 510 nm.

在酸性介质中，余氯使甲基橙褪色，最大吸收波长510 nm，摩尔吸光系数A510=5.41×10-3l/mol.cm，余氯质量浓度在(0.05~1.00)mg/l范围内遵守朗伯？？

Rresults from those studies can be summariazed as follow:(1) A preliminary study no correlationship between the UV-VIS reflection spectrum of tomato fruit surface and the lycopene amount of tomato fruit was undertaken. Based on observation from this study, a damage-free and in-situ detection technique of lycopene amount from tomato was developed with UV-VIS reflection spectroscopy;(2) The geometrical isomers of lycopene were separated successfully on C30-HPLC-PDA-ELSD. The absorption coefficients of Z-isomers were consequently dedermined. The geometrical isomer composition of lycopene could therefore be assessed. Those efforts formed a solid base to identify the natural product from synthetic compound of lycopene;(3) Lycopene resource from the fruit of Autumn oliver was proved to be available for industrial application. An extraction methos of lycopene from the fruit of Autumn oliver by supercritical carbon dioxide was developed at laboratory scale;(4) A method to extract lycopene by supercritical liquid with improved efficiency was developed; Data from this investigation suggested that a proper raw material pre-extraction process was important for a better extraction efficiency;(5) Variation in the geometrical isomer composition of lycopene during its metabolish in rat was assessed. A large amount of Z-isomers were observed. This variation took place in serum;(6) The absorption rate and accumulation in serum of natural lycopene in rat were assessed;(7) Ability to quench singlet oxygen by different geometrical isomers of lycopene was compared;(8) It was detected that whether natural lycopene had functions to regule blood-lipids and LDL antioxidation;(9) A C31 degradation piece of lycopene was found in the prostate gland of rat.

研究结果包括：[1]应用UV-VIS反射光谱法建立了番茄果实中番茄红素含量的无损伤、现场检测技术；[2]应用C30-HPLC-PDA-ELSD技术实现了对番茄红素几何异构体的分离，测定了不同顺式异构体的吸光系数，建立了天然番茄红素几何异构体组成的检测方法，为区分和鉴定人工合成品和天然产物奠定了基础；[3]证实了秋橄榄果实中的番茄红素资源具有工业开发价值，并建立了超临界CO_2萃取的实验室方法；[4]探索了提高番茄红素超临界流体萃取效率的方法，证明了物料前处理对提高萃取效率起了极其重要的作用；[5]观察了番茄红素在大鼠体内几何异构体组成的变化情况，发现了大量顺式异构体的存在，并证实了几何异构体组成在血清中发生了显著变化；[6]测定了天然番茄红素在大鼠体内的吸收率和在大鼠血清中的动态积累规律；[7]比较了不同番茄红素几何异构体淬灭单线态氧的能力；[8]检测了天然番茄红素是否具有调节血脂作用和抗低密度脂蛋白氧化的功能；[9]首次发现大鼠前列腺内存在番茄红素C31降解片段，并证实其仍具有淬灭单线态氧的能力。

Dichloro-2 pyridine azo-2,4 diamine methyl benzene is used as the developer for cobalt in determination of trace cobalt in iron ore.

应用5—［（3，5—二氯—2—吡啶）偶氮］—2，4—二氨基甲苯作钴的显色剂测定铁矿石中的微量钴，最大吸收峰位于波长590nm处，摩尔吸光系数为1。

The test results prove that the work curve has good linear relationsh...

经测定表明，工作曲线在钛含量为0-360μg/(50mL)范围内，有较好的线性关系，其表观摩尔吸光系数为8.813×103L/。

The linear range of standard curve is 0~40 mg/L for BSA.

该法的表观摩尔吸光系数为1.56×106L·mol-1·cm-1，线性范围为0~20 mg/L。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。