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In the high-grade metamorphism and anatexis process, in which sapphirine was formed, the multistage crystallization of minerals resulted in the complexity of the mineral association, such as the differentiation of leuco-and melano-components. Generally, the mafic-rich minerals formed earlier, and the differentiation of magnesio-and iron-components is responsible for the earlier presence of ironrich minerals, i.e., magnesio-rich minerals crystallized later, thus the successive associations of multistage occurred.

在形成假蓝宝石的高级变质-深熔作用过程中,岩石矿物组合的变化主要是多阶段变质造成的,如浅-暗色组分发生了分离,其中含镁铁组分多的矿物较早结晶,而镁铁组分的分离使得相对富Fe的矿物较早结晶,即晚期形成的镁铁质矿物更富Mg组分,并形成递进演化的不同阶段的组合。

The results showed that the amounts of base cations leached from calcareous soils and coastal solonchak were lower than the cation exchange capacity and the releasing amounts of Al3+ being lower than 0.40mmol·kg-1 all the way under the treatment of simulated acid rain with each pH value from 2.5 to 5.6,so the H+ buffering...

结果表明,石灰土和滨海盐土的阳离子淋溶量低于阳离子交换量,土壤主要处于阳离子交换缓冲范围和碳酸盐-硅酸盐缓冲范围,Al释放量一般低于0.40mmol·kg~(-1),铁铝土纲系列土壤在阳离子释放总量超过阳离子交换量后,淋溶液pH值急剧下降,此时Al淋溶量明显增加,质子缓冲转向Al缓冲范围,其释放量决定于土壤富铁铝化程度的高低和活性Al含量的多少,紫色土在低pH模拟酸雨淋溶下,由于含大量硅铝率较高的易风化原生或次生矿物,盐基释放量高于CEC,但Al释放量未明显增加,淋溶液pH也较稳定,土壤尚处于矿物风化为主的硅酸盐缓冲范围。

Through the contrast analysis on the chemical constitution of the magnetic iron ore and the plagioclaseamphibolite in Nanling ultra poor magnetite, and the analysis of graphs of and (FeO+Fe2O3+TiO2)Al2O3MgO, combining the geological features of mining area and the ore body characteristics, the conclusion can be drawn as follows: the plagioclaseamphibolites including magnetite and the plagioclaseamphibolite in Nanling mining area are formed from the oceanic tholeiite with rich iron after the deteriorating, and their genesis types should be the ultrapoor iron deposit of weathered residual origin.

通过对南岭超贫磁铁矿的磁铁矿石、斜长角闪岩化学成分的对比分析,结合矿区地质特征和矿体特征,对矿体进行n-n和w( FeO+Fe2O3+TiO2)-w(Al2O3)-w 图解分析,结果显示南岭矿区的含磁铁斜长角闪岩和斜长角闪岩是大洋富铁拉斑玄武岩经变质作用而形成的,矿床的成因类型为风化残积型超贫铁矿床。

The results showed that the interactions between Al(superscript 3+), Fe(superscript 3+), polysilicic acid, the polynuclear hydroxy complexes of Al(superscript 3+), Fe(superscript 3+) and SO(superscript 2- subscript 4) had a compositive effect of electric neutralization, adsorption and bridge on the coagulating properties.

结果表明,含硅多核无机高分子絮凝剂的混凝作用是铁离子、铝离子、聚硅酸、铝铁离子的水解聚合物以及它们和硫酸根离子相互作用的产物对废水中胶体悬浮物颗粒的电中和、吸附架桥及粘附卷扫等综合作用的结果。

The feature of the shaft furnace-iron bath smelter charging carbon-bearing pellets is that partial off-gas of shaft furnace is mixed with gas from smelter and then put into shaft for preheating and pre-reduction. The optimum operational parameter is at the point of prereduction degree of 52% and post-combustion degree of 32% where the coal consumption is 750kg/tone-hot metal and oxygen consumption is 420Nm〓/tone-hot metal.(5) The systematic simulation of rotary hearth furnace-iron bath smeter is firstly formulated.

4本文建立的含碳球团竖炉—铁浴工艺流程模型的特点之一是竖炉炉顶出口煤气的一部分与铁浴煤气混合后,重新进入竖炉,本文报道的对系统部分出口物流返回反应器的非序贯式流程进行的系统模拟,为今后类似问题的模拟提供了参考,本工艺的最低消耗点的操作条件是:预还原度52%,二次燃烧率32%,这时的最低煤耗为750kg/tFe(中挥发份煤VM=19%),氧耗约420Nm〓/tFe,对应于预还原度30~70%的优化组合的二次燃烧率为32~13%。

The experimental products include crystal phase quartz, feldspar (alkila-feldspar, albite, K-feldspar), zinnwaldite and topaz, a melt phase and a trace vapour. The solid products were been studied by optics method, electron microprobe and X-ray analysis. The results show that liquidus temperature raises slightly and solidus temperature falls down obviously and that the upper temperature limit raises for the stability field of quartz and topaz, and falls down for the stability field of alkila-feldspar as F contents in crease.

实验淬火产物包括结晶相石英,长石(碱性长石,钠长石、钾长石),铁锂云母和黄玉及玻璃相和微量流体,对固相淬火产物进行了系统和详细的显微观察及电子探针和x射线分析,研究了F对钠长花岗岩液、固相线温度、相关系和相组合的影响和含F钠长花岗岩的结晶序列和熔体演化、F在流体和熔体之间的分配及F对花岗质熔体结构的影响,对含黄玉矿物组合进行了一系列热力学矿物平衡计算,获得如下重要结论

A compartmented soil-glass bead culture system was used to investigate characteristics of arsenic accumulation in iron plaque and in mature rice plants irrigated using water with arsenic in greenhouse.

采用土壤-玻璃珠联合培养的方式,选择2个氧化能力不同的水稻品种YY-1、94D-64和采自浙江富阳的土壤(砷的本底值为13.8 mg.kg-1),并设灌溉清水和含砷水2个处理(即在分蘖期、拔节期、孕穗期、开花期和灌浆期5个生育阶段灌溉含砷污水,随灌溉水进入土壤中砷的浓度为3.2 mg.kg-1),研究了砷在土壤-根表铁氧化物-水稻系统中的累积规律以及土壤和灌溉水对水稻秸秆和籽粒富集砷的贡献程度。

A compartmented soil-glass bead culture system was used to investigate characteristics of arsenic accumulation in iron plaque and in mature rice plants irrigated using water with arsenic in greenhouse. Arsenic was supplied as a solution of Na3AsO4·12H2O at the following stages: tillering, stem elongation, booting, flowering and grain filling.

采用土壤-玻璃珠联合培养的方式,选择2个氧化能力不同的水稻品种YY-1、94D-64和采自浙江富阳的土壤(砷的本底值为13.8 mg·kg-1),并设灌溉清水和含砷水2个处理(即在分蘖期、拔节期、孕穗期、开花期和灌浆期5个生育阶段灌溉含砷污水,随灌溉水进入土壤中砷的浓度为3.2 mg·kg-1),研究了砷在土壤-根表铁氧化物-水稻系统中的累积规律以及土壤和灌溉水对水稻秸秆和籽粒富集砷的贡献程度。

Two series of polyurethane acrylate grafted acrylic resins (Acr-g-TPU-PETA and Acr-gPPU-PETA) self-emulsifying systems are obtained by grafting -NCO group modified polyurethane acrylates with acrylic copolymer prepared from n-butyl acrylate, styrene,βhydroxyethyl methacrylate and acrylic acid The self-emulsifying systems showed Newtonian fluidity with viscosity closed to that of water, the solid contents were around 30% The T〓 of 15~4℃ for dried film before photocuring favored film formation at room temperature DSC and DMA results showed that PU-PETA is compatible with acrylic resin in the grafted resin The TG and dTG curves for Acr-g-PU-PETA samples were substantially different from the corresponding blends, and the brodened dTG peaks for photocured grafted resin suggest that there might be multiple interactions among chain segments The photocued film of the grafted resins self-emulsifying system exhibited good overall properties with polyurethane acrylate grafts ranging from 30% to 50%, and Acr-g-TPU-PETA series showed better properties than Acr-gPPU-PETA series The adhesion of the photocured film was 1~2 grade, impact strength was 50kg-cm and flexibility was 1mm The Shore hardness and the adhesion of the film decreased markedly if PETA was replaced by HEMA as photoactive group due to the lower C=C double bond content in the grafted resin The polyhydroxy amine-linked thioxanthones photoinitiators can be evenly dispersed in self-emulsifying system without color spot appearing in the dried film The films photocured with IV〓~IV〓 generally exhibited higher Shore hardness, gloss and solventresistance than that cured with Irgacure 2959 and did not induce the rusting of the iron substrate Pigmenting with titanium oxide had no effect on the photocuring The polyhydroxy amine-linked thioxanthone IV〓 and IV〓 can be new candidates for the formulation of titanium oxide pigmented photocurable water-borne coatings for their pale-yellow appearance and slight interference with the color of the coatings WB 4759 with high water-solubility coalesced and separated from the dried resin film, and even induced the rusting of iron substrate.

以丙烯酸丁酯,甲基丙烯酸-β-羟乙酯,丙烯酸及苯乙烯合成厂丙烯酸共聚树脂,并与含-NCO端基的聚氨酯丙烯酸酯接枝反应,经水性化后,得到两个系列(Acr-g-TPU-PETA和Acr-g-PPU-PETA)各5个不同配比的丙烯酸树脂接枝聚氨酯丙烯酸酯自乳化体系,粘度与水相近,为牛顿流体,固含量30%左右。光固化前干燥涂膜的玻璃化转变温度在-15℃~4℃之间,有利于室温下成膜。DSC及DMA谱表明两种树脂基本相容。Acr-g-PU-PETA的热失重行为明显不同于共混材料,接枝样dTG峰明显宽化,表明接枝样中链段之间的相互作刚有多重性,丙烯酸树脂与聚氨酯之间有一定的相容性。接枝树脂自乳化体系光固化涂层的综合性能以聚氨酯丙烯酸酯成分为50%~30%者相对较好,且以Acr-g-TPU-PETA系列更理想。光固化膜的附着力为1~2级,冲击强度为50kg·cm,柔软性多为1mm。以HEMA代替PETA作为接枝树脂的活性基团,碳—碳双键密度太低,光固化膜交联点太少,硬度和附着力均较差。多羟基胺连硫杂蒽酮光引发剂能均匀分散于树脂自乳化体系和接枝树脂干膜中,不出现色斑,光固化膜肖氏硬度一般高于以Irgacure 2959为光引发剂的光固化膜,光泽度及耐丁酮溶剂性能均有所提高,不会诱导铁基生锈,钛白着色对光固化结果几乎没有影响。本论文所合成的多羟基胺连硫杂蒽酮光引发剂IV〓与IV〓为浅黄色,对光固化涂层的颜色干扰较小,为配制钛白着色光固化水性涂料提供了新的光引发剂。水溶性太强的WB 4759在干膜中易聚结析出,且对所附着的铁基有诱导锈蚀作用。

And a relative preparation is characterized in that according to mol ratio (0.8-0.975):(1.8-1.95):(0.010-0.15):(0.010-0.15) to prepare and mix Mg powder, B powder, C nanometer powder, and SiC nanometer powder uniformly to be filled into an iron tube or iron-copper composite tube to be sealed, rotationally forges, draws and rolls to obtain MgB2 superconductive material containing C and SiC nanometer powder, or tablets the raw powder mixed uniformly via a tablet press, to obtain MgB2 superconductive block containing C and SiC nanometer powder, arranges obtained band or block in a vacuum furnace, vacuums and fills argon gas, keeps temperature for 0.2-3h at 600-1200DEG C, and obtains MgB2 superconductive material containing C nanometer powder and SiC nanometer powder.

制备这种MgB 2 超导材料的方法,其特征在于,将Mg粉,B粉,C纳米粉,SiC纳米粉按照摩尔比(0.8-0.975)∶(1.8-1.95)∶(0.010-0.15)∶(0.010-0.15)配制并混合均匀,装入铁管或铁铜复合管中密封后,按顺序先后进行旋锻、拉拔、轧制,得到含C和SiC纳米粉的MgB 2 超导线材;或者将混合均匀的原料粉用压片机进行压片,得到含C和SiC纳米粉的MgB 2 超导块材;将得到的线带材或块材放置真空炉中,抽真空后充入氩气,在600℃-1200℃保温0.2-3小时,最终得到含有C纳米粉和SiC纳米粉的MgB 2 超导材料。

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