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Starting from 3-benzoyl-5-formyl-indolizine, 3-benzoyl-5-(2'2'-diacetylethenyl)-indolizines and analogs were obtained by the 〓mediated aldol condensation or Wittig reaction. These compounds,promoted by low-valent titanium, gave highly functionlizedcycl[3,2,2]azine derivatives. The coupling reaction proceeded betweenthe carbonyl group and the carbon-carbon double bond, a rare example inMcMurry reaction.

我们以3-苯甲酰基-5-甲酰基中氮茚为原料,通过三碘化钐促进的aldol反应和Wittig反应制备了3-羰基-5-羰基乙烯基中氮茚,随后经低价钛还原偶联,没有生成正常的分子内羰基-羰基偶联产物,而是得到反常的羰基与α,β-不饱羰基的双键偶联产物,较高收率地得到了含多官能团的CycI[3,2,2]azine衍生物。

It analyses the changeable TiO_2 content in chrome ore and the structural form,the balance of Ti,the reaction mechanism of Ti and its existence form in alloys,the affect factor of Ti content in alloys,and benefits and control methods during the process of smelting low titanium high carbon ferrochrome .

分析了低钛高碳铬铁生产过程中铬矿TiO_2含量变化与结构形式,冶炼过程中Ti的平衡、反应机理和在合金中的存在形式,合金含Ti量高低的影响因素,以及效益与控制方法。

These results indicated that a well structured anatase TiO2 was obtained by impregnation method under 500℃. Flow rate, in the activity test, could be neglected for mass transfer effects. As a matter of fact, relative humidity played the most important role in this reaction. The highest removal efficiency was obtained while relative humidify of 56.8%. Water molecules are sources of ; however, excessive water molecules could inhibit reactions by competing activity sites with organic containments. In the regeneration test, photocatalyst could be reactivated through a running water vapor with UV light illumination process.

研究结果指出,以含浸法制备之触媒於500℃锻烧下,具有良好的锐钛矿晶体结构;另外在活性测试的部份,流量的增加,污染物之去除效果不受影响,所以本实验选择以200ml/min之流量可忽略质传影响;湿度扮演重要的角色,当RH=56.8%时去除效率最高,主要因水气是产生氢氧自由基的主要来源,但是过多之水气可能与有机物竞争触媒表面上的活性位置,因而抑制反应的进行;初使浓度对去除率之影响中得知,初使浓度的高低不会影响触媒对有机物的催化能力,实验使用之触媒量适合催化200~250ppm之有机物,可藉由增加触媒量提高对有机物之催化能力;此外再生的测试,触媒可经由连续曝水及紫外光的照射,使触媒恢复原有的活性,可再次利用。

As flux used in light metal processing for metal surface treatment; as component in the production of aluminum-titanium-boron alloys and for the fabrication of grinding wheel and abrasive disc to reduce operating temperature; as flux used in welding; as fire retardent for cotton and artificial fibre; rodent for the removal of exposed lead in printed circuit board; chemical analytical reagent in electrochemistry; used to melt with silver, gold, stainless steel; as material to produce boron alloys.

作为熔剂用于轻金属加工对金属表面处理,制造铝钛硼合金和作砂轮研磨盘的成份,以降低操作温度;用于焊接上作助熔剂及制造其它氟盐的原料;用作棉花和人造纤维的阻燃剂,用来清除印刷电路中露出铅的侵蚀液;用于电化学合成的化学分析试剂,用于熔接和熔合银、金、不锈钢等金属,可做铝镁浇铸生产含硼合金的原料。

For the metastable Beta and near Beta phase alloys, with the increasing of hydrogen amounts, the flow peak stresses gradually increase; the elongations for fracture go down through minima and then go up to return or surpass the levels for the uncharging alloys.

由于在高温时氢致弱键机构相对说来不再重要,在正应力高的区域富集的倾向亦大为减小,钛合金在高达上万个PPm的含H量时仍具有相当好的塑性,表现出对氢有巨大的容忍力。

At first, mineral composition and distributing of impurities in andalusite grains were studied by SEM and EDS. The results showed that main mineral impurities were biotite, ilmenite, clay species, the wall rock conglutinated at brim of andalusite and impurities in the chiastolitic cruciform pattern were easily removed, but the small impurities in andalusite grain were hardly removed.

首先,利用SEM和EDS分析了红柱石矿的矿物组成和杂质分布,结果显示这种红柱石矿所含的杂质矿物主要是黑云母、钛铁矿和黏土矿物等,其中分布在红柱石颗粒边缘的围岩和空晶石内的黑十字容易去除,而分布在晶内的细粒杂质则不易去除。

Generally the catalysts have high activity and good selectivity. At present the coupling reactions of organoborahes with terminal olefins s acid chlorides and aryl halides play an important synthetic approaches in organoborane chemical. The catalysts can be used by many kinds of organometal compounds such as: irons cobalt nickel ruthenium rhodium palladiums titaniums zirconiums tins indium and lithium organic compounds; The achievement has been amazed in preparing of unsaturated or saturated compounds and in synthesizing of natural products bioactive molecules and chiral compounds.

目前,卤代烃与不饱和烃的偶联反应和有机硼试剂与酰卤和卤代烃的偶联反应已成为有机合成的研究热点,此类反应可用铁、钴、镍、钌、铑、钛、锆、锡、铟、锂等多种有机金属化合物来催化,用于形成含饱和或不饱和C-C键的化合物,并已在天然产物、液晶、具有生理活性物质和手性化合物的合成中应用。

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With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐,因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。

Closes the eye, the deep breathing, all no longer are the dreams as if......

关闭眼睛,深呼吸,一切不再是梦想,犹如。。。。。。