含金属的

The acidic composition can be prepared by mixing a monovalent or polyvalent cation and an organic acid in the presence of a strong oxyacid, wherein the resultant acidic composition is less corrosive to a ferrous metal than a solution of a mineral acid having the same acidic pH value as that of the acidic composition, and where in the acid composition is more biocidal than a mixture of the organic acid and a metal salt of the organic acid which mixture has the same acid normality value as that of the acidic composition.

所述酸性组合物可以在一种强羟基酸存在时，通过混合单价或多价阳离子和有机酸来制备，其中与具有相同的酸性pH值的无机酸溶液相比，所形成的酸性组合物对含铁金属的腐蚀性更小，并且与具有相同酸当量值的有机酸与有机酸金属盐的混合物相比，所述的酸组合物具有更强的杀生物作用。

The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.

第二章 研究了二碘化钐、金属钐促进的有机反应：1、二碘化钐促进下α，β-炔基酮的偶联环化反应，提供了一种制备多取代环戊二烯的新方法；2、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮的Michael加成反应，为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法；3、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮和醛、酮的Michael—aldol串联反应，提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法；4、烯丙基溴化钐与α，β-炔基酮的高度区域选择性的1，2-亲核加成反应；5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。

A chromium free conversion coating at least equivalent in corrosion protective quality to conventional chromate conversion coatings can be formed on metals, particularly cold rolled steel, by a dry-in-place aqueous acidic liquid comprising: a component of anions, each of said anions consisting of at least four fluorine atoms and at least one atom of an element selected from the group consisting of titanium, zirconium, hafnium, silicon, and boron, and, optionally, ionizable hydrogen atoms, and optionally, one or more oxygen atoms; a component of cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, zirconium, iron, and copper; the ratio of the total number of cations of this component to the total number of anions of component being at least 1:5; sufficient free acid to give the composition a pH in the range from 0.5 to 5.0; a component selected from the group consisting of phosphorus-containing inorganic oxyanions and phosphonate anions; and a component selected from the group consisting of water-soluble and water-dispersible organic polymers and polymer-forming resins and, preferably, also including a component selected from the group consisting of tungstate, molybdate, silicotungstate, and silicomolybdate anions.

通过对包含以下成分的含水酸性液体进行干燥，可以在金属上形成无铬的转换涂层，该涂层与普通铬酸盐转换涂层相比，至少在抗腐蚀质量上等效：$_一种阴离子成分，所述各个阴离子包括至少4个氟原子，至少选自钛、锆、铪、硅与硼元素中的1个原子。任选地可离解的氢原子，任选地1个或多个氧原子；$_一种选自钴、镁、锰、锌、镍、锡、锆、铁与铜元素的阳离子成分，上述成分的阳离子总数与成分内的阴离子总数之比至少为1∶5；$_足够的游离酸以使该组合物的pH值在0.5～5.0的范围内；$_一种选自含磷的无机含氧阴离子与膦酸盐阴离子的成分；$一种选自水溶性与水可分散性有机聚合物与聚合物形成的树脂的成分，优选还包括一种选自钨酸盐、钼酸盐、钨硅酸盐与钼硅酸盐阴离子的成分。

On the basis of molecular design and assembly, the polyoxometalate compounds supported by Keggin, Dawson, lacunary Keggin, and Silverton-type etc. polyanions on the basis of well-known and novel polyanions as building blocks were successfully synthesized by the hydrothermal technique, which are"decorated"or"bridged"by organic N-donor and/or O-donor ligands. The study on synthetic conditions and rules for these hybrid compounds and characterization by X-ray crystallography, spectroscopic, thermal, electrochemical and magnetic properties are carried out.

本文主要利用水热合成方法，从分子设计及组装的思想出发，借助不同N和含O的有机配体对多金属氧酸盐阴离子结构进行&修饰&或&桥连&，合成了一些以饱和Keggin结构、饱和Dawson结构、缺位Keggin结构和Silverton结构等阴离子为构筑模块的多金属氧酸盐化合物，研究了这些化合物的合成条件及规律并对它们的晶体结构、谱学性质、热性质以及磁性质进行了研究。

The identified proteins are involved in a variety of cellular process including several zinc finger proteins relevant to transcription regulation, such as zinc finger 198, 263, 14, 224, zf6, novel protein similar to transcriptional represser CTCF, and kruppel-like zinc finger protein; two members of the ADAMs (a disintegrin and metalloprotease domain) family; two members of integrin family; several proteins involved in the signal transduction, cell-cycle control, chromatin remodeling and transcription repression; and also some proteins of cell skeleton and some with unknown functions.

鉴定出 的蛋白包括多个与转录调控相关的锌指蛋白，如锌指蛋白198、263、14、224、zf6、转录抑制因子cTcF样蛋白、幻肚pple样锌指蛋白等：两个含金属蛋白酶结构域和整合素结合结构域的家族成员ADAM28和ADAM17；两个整合素家族成员pZ整合素和含十个EGF样结构域的整合素；与细胞信号转导通路有关的蛋白；与细胞周期调控有关的蛋白；与染色体重塑和基因转录抑制有关的蛋白；细胞骨架蛋白以及其他功能未明的蛋白等。

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公司专业生产选矿设备，提供工艺流程，选矿实验，安装指导13697077005www.lzkysb.cn温良禹0797-5745599溜槽，螺旋溜槽，玻璃钢螺旋溜槽，玻璃钢溜槽，选矿溜槽，选矿螺旋溜槽，萤石浮选设备，旋转螺旋溜槽，玻璃钢旋转螺旋溜槽，旋转溜槽，江西螺旋溜槽，江西溜槽，石城螺旋溜槽，石城溜槽， BLL溜槽， BLL型玻璃钢螺旋溜槽， 5LL螺旋溜槽，公司生产的螺旋溜槽，玻璃钢螺旋溜槽，玻璃钢旋转溜槽，玻璃钢旋转螺旋溜槽有BL，LL，CBX等系列BL的特点是新型复合断面，超短螺距，大直径，宽断面，特别适于原矿的拖泥及非金属，金属矿物细粒级(-0.2毫米)的分选，不需冲水，具有结构简单，无需动力，重量轻，占地面积小，处理量大，分选效率高，LL的用于选别粒度0.3-0.02毫米的铁锡，钨，钽，铌，煤矿，金矿，独居石，金红石，锆英石及具有足够比重差的其它矿物CBX对于选别钽，铌，锡，钨，金，钛，铁和其它比重差大于1的矿物锯齿波跳汰机，隔膜跳汰机，旁动式跳汰机，侧动式跳汰机，下动式跳汰机，双室隔膜跳汰机，选矿跳汰机，动筛跳汰机，锯齿波大颗粒跳汰机，JT跳汰机，选金跳汰机，选金机，选锡跳汰机，重选跳汰机，公司生产的跳汰机，单斗跳汰机，隔膜跳汰机，双斗跳汰机，锯齿波矩形跳汰机，锯齿波梯形跳汰机，左式和右式跳汰机有JT，LTS等各种系列，该机是固定筛子式，适用于选别金属矿石，如钨，含金的砂矿，精选锡矿等，也可用于选细粒物料和粗粒物料，最大给矿粒度为30毫米。

The cutoff conditions of metal-clad waveguides or loss dielectric waveguides are discussed. The effects of metal-cladding on the cutoff condition of graded index waveguides are analyzed at first. The principle of cutoff intensity modulator has discussed in detail.

本文首次提出一种适合于分析含金属覆盖层的均匀和渐变介质波导在截止点附近的光学特性的近似的解析方法，并对金属覆盖层的均匀阶跃介质波导在截止点附近的模传播特性作了全面的分析，所得到的结果同精确的数值解结果相吻合。

Because of advantages such as containing metal-free, so the organocatalyst has not the potential risk of leaching of toxic metal ion to the environment; generally has good catalytic activity, some might exhibit peculiar character and catalytic mechanism as enzyme; easily handled, can be performed in solution or air without the necessity of severe conditions like water-free a...

因为其不含金属离子，不存在有毒金属离子泄漏而造成环境污染；一般具有较高的催化活性，有些显示出类似酶的特性和催化机理；反应容易操作，可在溶液或空气中进行，不需要无水无氧等苛刻条件；价格一般比较便宜，易于制备、修饰和改性，可调控性大；易于与产物分离及从反应体系中回收等一系列&绿色&的优点。

Because of advantages such as containing metal-free, so the organocatalyst has not the potential risk of leaching of toxic metal ion to the environment; generally has good catalytic activity, some might exhibit peculiar character and catalytic mechanism as enzyme; easily handled, can be performed in solution or air without the necessity of severe conditions like water-free and oxygen-free.

因为其不含金属离子，不存在有毒金属离子泄漏而造成环境污染；一般具有较高的催化活性，有些显示出类似酶的特性和催化机理；反应容易操作，可在溶液或空气中进行，不需要无水无氧等苛刻条件；价格一般比较便宜，易于制备、修饰和改性，可调控性大；易于与产物分离及从反应体系中回收等一系列&绿色&的优点。

In this experimental study firstly a sulphur-bearing alkanethiol-derivatised gold nanoparticles has been selected and prepared. The alkanethiol-derivatised gold was put in the mud-stone samples bearing terreau. In varies elevated temperature the gas products were collected by foam plastics in a special installation. The measurements on the contents of gold in foam plastics and on the composition of gas phase were carried out and the comparisons for various samples were made.

本项研究选取并制备了作者认为有地质意义的含硫的金的金属有机化合物-烷基硫醇衍生纳米金，将其添加至含有机物质的泥岩样品中，在专门设计的真空装置中用泡塑收集不同温度气相产物，分析所产生气相组成及带出金的含量并与添加氯金酸水溶液的样品进行对比。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。