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Four new salicylaldehyde derivatives with a glucose or mannose moiety were synthesized with 2-tert-butylphenol or 4-tert-butylphenol as the starting material, followed by the formylation, chloromethylation, nucleophilic substitution reaction with the desired carbohydrate. The salicylaldehyde derivatives condensed with ethylenediamine to give the Schiff bases, which coordinated with Mn to afford four novel sugar-based Salen Mn complexes.

首先,分别以2-叔丁基苯酚和4-叔丁基苯酚为起始原料,经过甲酰化反应、氯甲基化反应、和糖类衍生物的亲核取代反应制得了四种新型并入葡萄糖基或甘露糖基的水杨醛衍生物,将它们与乙二胺缩合生成希夫碱配体,得到的配体与过渡金属Mn~(3+)配位制备出四种新型含糖基的Salen Mn配合物。

Different from the conventional catalyst immobilization methods, the self-supporting strategy utilizes homochiral metal-organic coordination polymers generated by self-assembly of chiral multitopic ligands with metal ions without using any support.

与传统的负载模式不同,手性自负载催化剂通过含双或多官能团的手性配体与金属通过自组装形成一类有机-无机聚合物,因此无需使用任何载体,即能够有效地实现手性催化剂的回收和再利用。

In the oxygen steelmaking processes, material from the blast furnace saturated with carbon is placed in a vessel capable of holding some 100 ~ 300 t of hot metal. Oxygen is then lanced from above the bath for about 15 min, or alternatively a mixture of oxygen and propane is blown up through tuyeres in the bottom of the vessel (bottom-blown).

在氧气炼钢工艺中,把来自于高炉的含饱和碳的铁水兑人一个容量约为100一300吨的转炉中,然后用氧气从金属熔池上面向熔池喷吹约I5分钟,或者通过熔池底部喷嘴喷入氧气和丙烷的混合气体。

Selected novel olefinic orthoesters, may be copolymerized with other olefins using certain late metal transition catalysts, to form novel polyolefins containing orthoester pendant groups.

利用某些后过渡金属催化剂,可以使选择的新颖烯烃原酸酯与其它的烯烃共聚合,以形成含原酸酯侧基的新颖聚烯烃。

It was found that casting Al-Si alloy conforming to industrial standard could be obtained after refining by using cryolite and sodium chloride as purificant and removing iron by using manganese as de-ironing medicine.

研究结果得出,使用含冰晶石和氯化钠混合物的精炼剂以及金属锰为除铁剂并采取适当的工艺方法,可以有效地去除一次铝硅合金中的杂质,制取符合工业标准的铸造铝硅合金。

This dissertation involves the syntheses, reactivities and structures ofGroup 6 metal carbonyl complexes containing the pyrazole ligands.

本论文开展了对含吡唑类配体的VIB金属羰基配合物的合成、反应及结构的研究,合成了70余个新化合物,并取得了如下研究成果。

Sixteen Scenedesmus species or strains have been employed to investigate the maximum capacity of nickel accumulation in 10 mg/L Ni solution. The results showed that the capacity of accumulating Ni from aqueous solution in 16 Scenedesmus species or strains showed the diversity.

对不同Scenedesmus品种的藻细胞从含镍水溶液(10mg/L)中累积金属镍的能力进行了分析,结果表明:藻细胞对镍的生物累积量表现出明显的品种差异性。

The research firstly focused on the effects of catalytic reductive dechlorination of the composite wastewater with chloroform and tetrachloromethane by zero-valent iron, optimizations of influencing factors on the dechlorinating process, and kinetics of chloroform dechlorination.

本文首先以配制的含氯仿和四氯化碳的废水为处理对象,研究了金属铁催化还原脱氯的效果,优化了处理工艺参数,简单分析了氯仿脱氯动力学特征。

In this paper, we synthesized a series of new tripodal schiff base compounds and their transition mental ion complexes.

本文设计合成了一系列三脚架结构的含硫西佛碱及其与过渡金属离子的配合物,研究了它们的波谱性质并对其进行了生物杀菌活性研究。

According to the property of mud of gas of plum steel blast furnace, undertook to its zincic experiment studies receiving iron to fall, no matter use magnetic separation,the result makes clear or classification the law all can reclaim from which content of major iron ore and purify is major zinc, stock of will tall zinc, low zinc undertakes effective depart, iron concentrate yield and grade all achieve 52% above, iron metal reclaims rate 70%, take off zinc to lead 50% above.

梗概: 介绍了梅钢高炉瓦斯泥的性质、试验情况及结果,国内外处理使用含锌高炉瓦斯泥的方法。根据梅钢高炉瓦斯泥的性质,对其进行了收铁降锌的试验探究,结果表明无论用磁选还是分级法均能从中回收大部分铁矿物并去除大部分锌,将高锌、低锌物料进行有效分离,铁精矿产率和品位均达到52%以上,铁金属回收率70%,脱锌率50%以上。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。