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It was discovered that this modified kaolin had ideal capability of removing arsenic from water because of its giant active surface and coordinate action, intensify, for arsenate ions AsO(superscript 3- subscript 4 and Fe(superscript 3+) fixed on the framework, and achieving the aim of removing the minimal content of arsenic from the water.

以高岭土为原料通过碱熔合成得到类似于分子筛的笼状骨架结构,并将Fe(上标 3+)通过离子交换吸附,负载在其骨架上,实现改性;利用改性后的吸附剂具有大的活性表面积,以及砷阴离子AsO(上标 3-下标 4与Fe(上标 3+)的强配位能力,实现了基于配体交换的固液分离的从微量含砷水中去除砷。

The produced water which was made by crude oil dehydration containing polymer, alkaline and surfactant, brought many technique problems in the water treatment process system, this made the polymer flooding and water flooding water treatment technologies difficult to suit to the disposal requirement of the special water. The developed experiment research indicated that: because of the surfactant, the semidiameter of the oil droplets in the ASP flooding is much smaller than that in polymer flooding, and the stability of the oil droplets is higher than that in polymer flooding, The viscosity and combine difficulty of the oil droplets increased, and all the changes of speciality resulted in the increased difficulty in the ASP flooding produced water disposal.

三元复合驱采出液经脱水后得到的采出水中,因含有聚合物、碱和表面活性剂,给采出水处理工艺系统带来了一系列的技术问题,使已经应用于水驱和聚合物驱采出水处理的技术难以适应这种特性的采出水的处理要求,已经开展的实验研究表明:三元复合驱采出水中由于表面活性剂的存在,使采出水中油珠的粒径远远小于聚合物驱采出水,油珠的稳定性明显大于聚合物驱采出水;由于聚合物的存在,采出水粘度增大,使油珠聚并难度增大,这些特性的变化造成三元复合驱含油污水的处理难度大于聚合物驱。

Stone is from rock, and rock is consist of the mineral, the mineral contain iron is the source of the iron in stone products , iron element spread widely in natural world, but most of them appear to be compound, iron element is belong to medium activity metal, under high temperature is easily to be strongly acted with oxygen, sulfur, chlorine, and easily dissolve in abio-weak acid solution and strong hydrochloric acid solution, at the same time, the strong alkali solution also corrade the iron.

石材是岩石经加工后所产生的制品,岩石是由矿物组成的,其中含铁矿物是石材中铁质的来源。铁元素在自然界中分布甚广,但大多以化合物的方式出现,由于铁元素属中等活泼性的金属,在高温下易和氧、硫、氯等元素发生强烈反应,并易溶于无机稀酸和浓盐酸的溶液中,同时浓碱溶液也易侵蚀铁。

Secondly, the influences of pH value of buffer solutions on the dedolomitization of dolostone powders and the expansion of a reactive dolomitic limestone were investigated. A program was conducted to study the reaction and expansion of dolostone powders in compacts and pastes of cement, and that of dolomitic rocks with few clay and quartz in alkaline solutions and concrete.

第二部分研究了溶液pH值对白云岩粉料的去白云化反应速率及活性白云质灰岩膨胀速率的影响;分析了白云岩粉料在水泥压实体中、含很少粘土和石英的白云质岩石在碱溶液及混凝土中所发生的化学反应,并测定了伴随化学反应产生的膨胀。

The results of the present research are as follows, The correlation between physico-chemical properties of organic compounds and their competitive power was studied, and it was indicated that organic compounds preferable to form H-bonding with organic matter of sorbents have stronger competitive power; Sorption behaviors of ionizable organic compounds in different species and their competitive power were examined, and the results showed that phenols and carbonxylic acids with benzyl circle have much stronger competitive power in molecular species than in ionized species, because negative charges of anionic forms can depressed their adsorption on the surface of the sediment; in contrast, organic bases such as aniline and p-chloroaniline show weaker competitive power in molecular species than in ionized species, and this is because both species of the organic bases could adsorb strongly onto the sediment; there is a correlation between competitive power of organic pollutants in multi-solute systems and their sorption isotherm nonlinearity in single-solute systems, and organic compounds whose sorption isotherms is linear in single-solute systems hardly have competitive power in multi-solute systems; Competitive sorption effects in more than two-solutes systems was studied, and it was exhibited that mixture of two cosolutes each of which could suppress sorption of nominal solute onto the sediment had synergistically competitive sorption effect on the nominal solute; A method about incorporating sorption/desorption of organic pollutants into river water quality model was developed, and discussion about degree of sorption/desorption effect on model prediction for different organic compounds was made, which will provide theoretical basis and practical processes for setting up more accurate water quality model.

论文主要取得了以下研究成果。(1)有机化合物的吸附竞争能力与其物化性质具有相关性,易与沉积物有机质形成氢键的化合物其竞争能力也比较强;(2)可离子化有机化合物的吸附竞争能力与其存在形态有关。酚类、含苯环的羧酸类化合物,其离子态的吸附竞争能力远小于分子态,其机理为有机酸阴离子所带的负电荷抑制了表面吸附能力,主要发生分配作用;而苯胺类化合物,其离子态和分子态都表现出显著的竞争能力,而且离子态的竞争能力略强于分子态,原因在于有机碱阳离子所带的正电荷促进了其表面吸附能力;有机化合物竞争能力的强弱与其单组分吸附等温线的非线性程度具有一定的相关性,吸附等温线近似为线性的化合物没有或只具有微弱的竞争能力;(3)对目标有机化合物的吸附具有竞争效应的有机化合物混合后,将对目标有机化合物的吸附产生协同竞争效应;(4)以京杭运河为例,率先提出了将有机污染物的吸附/脱附作用及水文水力参数耦合到水质模型中的方法,并讨论了吸附/脱附作用对不同有机污染物预测模型的影响,为建立更准确的水质模型及进行更客观的风险和生态评估提供了参考依据。

Twelve new Schiff bases of 5-amino-1H-1,2,3,4-tetrazolyl were synthesized. These Schiff bases were further converted into α-(5- tetrazolyl)-aminoalkyl phosphonates.

合成了12个新的5—氨基—1H—1,2,3,4—四唑的Schiff碱,而后与亚磷酸二乙酯反应,合成出了12个新的含四唑基的α-氨基烃基膦酸酯,通过IR,^1H NMR,^31P NMR和元素分析证实了它们的结构。

Chocolate to the dog run is Fatal Attraction, this is because chocolate contains theobromine, caffeine Caffeine and theobromine on the dog's heart and central nervous system have a serious impact, but some iron teeth of the dog owners will say that My dog has eaten chocolate, but perfectly good ah!

巧克力对狗狗而言是致命的吸引力,这是因为巧克力所含的咖啡因Caffeine及可可碱theobromine 对狗狗的心脏及中枢神经系统有严重的影响,但是有些铁齿的饲主一定会说我的狗狗有吃过巧克力可是还好好的啊!

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This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

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