含硫的

The present invention relates to the depolymering cyclization reaction of aromatic dithio ether polymer to prepare aromatic cyclic dithio ether compound under the presence of mercapto group containing compound and alkali matter.

本发明涉及利用芳香双硫醚聚合物的解聚成环反应来制备芳香双硫醚环状化合物的方法。该方法采用芳香双硫醚聚合物在含巯基的化合物和碱性物质存在的条件下发生解聚成环反应生成双硫醚环状化合物。

In order to find high active pesticide containing heterocycle, six novel terephthaloyl bisthioureas containing 1, 3, 4-thiodiazole were synthesized by the reaction of 2-amino-5-alkyl-1, 3, 4-thiodiazoles with terephthaloyl diisothiocyanate.

摘 要：为寻找高活性的含杂环农药，由中间体5-烷基-2-氨基-1， 3， 4-噻二唑与对苯二甲酰基二异硫氰酸酯反应，合成6种新的含1， 3， 4-噻二唑环的对苯二甲酰基双硫脲化合物Ⅲaf。

In order to find high active pesticide containing heterocycle, six novel terephthaloyl bisthioureas Ⅲ(subscript a-f containing 1,3,4-thiodiazole were synthesized by the reaction of 2-amino-5-alkyl-1,3,4-thiodiazoles with terephthaloyl diisothiocyanate.

为寻找高活性的含杂环农药，由中间体5-烷基－2-氨基－1，3，4-噻二唑与对苯二甲酰基二异硫氰酸酯反应，合成6种新的含1，3，4-噻二唑环的对苯二甲酰基双硫脲化合物Ⅲ。

Result The results showed that its components were quite complex, and 89 organic compounds were identified. There were 72 kinds of oxygen-containing organic compounds which included esters, phenols, aethers, ketones and alcohols in the depolymerization product, small amounts of alkanes, alkenes, arenes, thiophenol and nitrogen-containing organic compounds were also detected, which showed that characteristics of the product with high oxygen content, low nitrogen and sulphur content.

结果］超临界乙醇解聚产物成分十分复杂，GC/MS分析鉴定出89种有机化合物，其中72种为含氧化合物，主要有酯、酚、醚、酮和醇等，还检测出少量烷烃、烯烃、芳烃、苯硫酚和含氮化合物，反映了解聚产物的高含氧量和低含氮硫量的特性。

Two benzothiazole ester compounds containing boron with different alkyl chain, Di-n-hexyl-[2-(2-benzothiazolylthio)] ethyl boric acid ester (BNS-1) and Dicyclohexyl-[2-(2-benzothiazolylthio)] ethyl boric acid ester(BNS-2), were synthesized and their tribological performance as additives in rapeseed oilwas investigated using a four-ball testing machine.

合成了两种含不同烷基链的含硼苯并噻唑酯类化合物，即二正己氧基-2-[(2-苯并噻唑基)硫代]乙氧基甲硼烷(BNS-1)和二环己氧基-2-[(2-苯并噻唑基)硫代]乙氧基甲硼烷(BNS-2)。

The oxidant 〓 plays indirect role in dissolving gold, and mainly controls the mix potential of Au in the alkaline thiourea solution. In which the "mix potential"is the decisive factor affecting the dissolution of gold. The reaction driving force is enough to have formamidine disulfide oxidize Au to Au〓 at the potential of about 0.4V. And then thiourea molecular complexes with Au〓 ion soon, which causes the fast dissolution of gold in the alkaline thiourea media. The dissolved weight of gold in 0.25 M thiourea solution with 0.05M Na〓SO〓 and 0.1M 〓 of pH 12. 5 by air at the temperature of 303K is 7. 8mg·cm〓 within 1hr.

在碱性硫脲溶金过程不起直接作用，而是通过S〓O〓来控制二硫甲脒有效形成的金在溶液中的混合电位；&混合电位&是影响碱性硫脲溶液溶金与否的决定性因素，在0.4V左右，有足够的推动力致使二硫甲脒氧化Au成Au〓，随后硫脲与Au〓络合形成稳定的络离子Au〓，从而使金快速溶解；温度为303K、pH为12.5时，在含0.05MNa〓SO〓、0.1M 〓及0.25M硫脲的溶液中，鼓入空气，金的溶解量在1hr内为7.8mg·cm〓；铜只有微量溶解，银、镍、铁则几乎不溶解。

Sulfur isotope measurements of deposits such as those in the 1.1 Ga Duluth Complex, the Per-mo-Triassic intrusions of the Noril'sk area, and the 1.4 Ga Kabanga intrusions provide evidence for the derivation of S from both sulfide-and sulfate-bearing country rocks. The 1.3 Ga Voisey's Bay deposit provides an example where δ^34 S values of the ores commonly fall within the accepted mantle range of 0±2‰, but detailed studies of Proterozoic metasedimentary country rocks show that their weighted average δ^34 S value is also within this range.

如1.1 Ga的Duluth杂岩、Noril'sk地区二叠－三叠纪侵入岩和1.4 Ga的Kabanga侵入岩体中矿床的硫同位素测定结果证明硫来自含硫化物和硫酸盐的围岩。1.3 Ga的Voisbey's Bay矿床矿石的硫同位素δ^34 S值通常落入公认的地幔硫同位素组成范围(0±2‰)内，而对其元古宙变质沉积围岩进行的详细研究结果显示δ^34 S的平均值也在此范围。

Sulfur isotope measurements of deposits such as those in the 1.1 Ga Duluth Complex, the Per-mo-Triassic intrusions of the Noril'sk area, and the 1.4 Ga Kabanga intrusions provide evidence for the derivation of S from both sulfide-and sulfate-bearing country rocks. The 1.3 Ga Voisey's Bay deposit provides an example where δ^34 S values of the ores commonly fall within the accepted mantle range of 0±2‰, but detailed studies of Proterozoic metasedimentary country rocks show that their weighted average δ^34 S value is also within this range.

如1.1 Ga的Duluth杂岩、Noril'sk地区二迭－三迭纪侵入岩和1.4 Ga的Kabanga侵入岩体中矿床的硫同位素测定结果证明硫来自含硫化物和硫酸盐的围岩。1.3 Ga的Voisbey's Bay矿床矿石的硫同位素δ^34 S值通常落入公认的地幔硫同位素组成范围(0±2‰)内，而对其元古宙变质沉积围岩进行的详细研究结果显示δ^34 S的平均值也在此范围。

The catalytic transformation pathway can change to decrease the yield of hydrogen and yield methyl-contained sulfides such as methyl mercaptan, dimethyl sulfide and dimethyl disulfide, but overlarge concentration of methanol would holdback the transformation of isobutyl mercaptan. The transformation of isobutyl mercaptan was favorable if the volume ratio of methanol and benzene was 0.2.The addition of methanol assume certain effect on the catalytic cracking of di-n-butyl sulfide in solvent benzene but without changing the cracking reaction mechanism of di-n-butyl sulfide.

甲醇也可以使异丁硫醇的催化转化路径发生改变降低硫化氢的产率，生成甲硫醇、甲硫醚及二甲基二硫化物等含甲基硫化物，但甲醇的浓度过高会抑制异丁硫醇的转化，在反应体系中当甲醇的体积占到溶剂苯体积的20%时对异丁硫醇的转化较为有利；甲醇的添加对丁硫醚在溶剂苯中的催化裂化有一定影响，但没有改变丁硫醚的裂解反应历程。

According to the research of Pb isotopic, the metallogenetic material mainly originated from the Permian basalts; the study of sulfur isotopic find that the sulfur of the basalt-type copper deposits and carbonaceous sedimentary interlayers-type copper deposits originated from both Permian basalts and evaporate of sedimentary section, S in bauxitic mudstone-type copper deposits originated from evaporate of sedimentary layers.

研究区三种类型铜矿的铅同位素示踪研究，成矿物质主要来自于邻近的二叠纪玄武岩；硫同位素研究结果显示，玄武岩型铜矿和含碳沉积岩夹层型铜矿中的硫有两种来源：二叠纪玄武岩和蒸发岩中的硫；而铝土质泥岩铜矿中的硫主要来源于沉积地层中蒸发岩的硫。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。