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First, the precursor polymer with azobenzene groups on main-chain was obtained by condensation polymerization between 4,4'-dihydroxyazobenzene and N,N-(2-bromoethyl)aniline through Williamson reaction. Then the azo polymer containing azobenzene groups both on main-chain and side-chain was prepared through an azo-coupling reaction between the precursor polymer and the diazonium salt of 4-nitroaniline.

设计并合成了一种新型的主侧链均含偶氮生色团的聚合物,首先通过4,4'-二羟基偶氮苯与N,N-二溴乙基苯胺之间的Williamson反应缩聚得到主链含偶氮苯基团的先驱聚合物,再通过重氮偶合反应得到目标产物,并利用核磁共振、红外光谱、紫外可见光谱、热分析等手段确认了所制备聚合物的结构。

In one embodiment, the invention is a system for initiating free radical polymerization comprising: a in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms and optionally containing one or more heteroatoms or heteroatom containing functional moieties, and one or more cationic counter ions and b in a second part, a liberating compound which reacts with the nitrogen atom bound to the boron atom upon contact with the amido-borate to form an organoborane radical.

在一个实施方案中,本发明是引发自由基聚合的体系,包括:a在一个部分中,一种或多种含有一个或多个包含有机硼酸根的阴离子酰氨基-硼酸盐部分和一个或多个阳离子抗衡离子的酰氨基-硼酸盐化合物,其中的硼原子键合到氨的氮原子或含一个或多个氮原子的有机化合物,例如烃基胺、烃基聚胺或含一个或多个氮原子和任选含一个或多个杂原子或含杂原子的官能部分的芳族杂环的氮原子上,和b在第二部分中,在与酰氨基-硼酸盐接触时与键合到硼原子上的氮原子反应形成有机硼烷基团的释放化合物。

In Chapter 5,the pyrolysis of substituted six-membered ring model compound 4-methyl pyridine has been investigated.Instead of detail theoretical analysis of the reaction mechanism,the general results have been proposed from the products distribution and the combination of the pyrolysis investigation of its analogous pyridine.The major products are H_2,C_2H_2,C_4H_2,C_3H_3N and HCN,here HCN is not a primary initial product at low extent of decomposition.The mole fraction profiles of products have been obtained from the near threshold ionization.The pyrolysis of 4-methyl pyridine is initiated from the methyl abstraction and hydrogen abstraction procedures which are associated with the understanding of the soot formation and the NOX precursor correspondingly.

主要产物为H_2,C_2H_2,C_4H_2,C_3H_3N和HCN,其中HCN为非低温时的热解产物;通过近阈值电离并导出物种随温度变化的摩尔分数曲线,更详细地定量地描述了产物随温度的变化。4-甲基吡啶热解主要从母体脱甲基和脱氢两个初始反应出发,一种趋势是形成大质量数的苯并或杂环的多环化合物,有助于了解炭黑形成过程中的复杂化学过程;另一趋势是开环生成小的碳氢和腈类物质,实验得出的含氮物质的种类及随温度变化有助于了解NO_x的前驱物质的形成及其变化规律。

In this paper,many achievements of studying on the synthesis,thermal decomposition properties and characteristics of the energetic complexes based on high-energetic compounds containing many nitrogen atoms such as carbohydrazide and 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one as well as tetrazole,etc.

概述了以高能多氮直链化合物如碳酰肼,富氮杂环化合物如三唑、四唑类为配体的配合物的合成、热行为以及性能的研究情况,同时简要地从分子或原子结构描述了一些其他多氮含能配体如肼、肼基甲酸甲酯等所形成的配合物的晶体结构以及热分解行为,并对含能配合物的发展方向进行了展望。

We found that the recording order of gratings with different periodicity made a crucial effect on the final forming of the microstructures. 4. Photo-induced birefringence phenomenons of P , containing mono azobenzene chromophore and P (MMA-co-GY7), containing diazobenzene chromophore were studied by static absorption and dynamic pump-probe techniques.

研究了单偶氮苯聚合物P、双偶氮苯聚合物P(MMA-co-GY7)的紫外-可见吸收光谱、荧光光谱,并对单偶氮苯、双偶氮苯聚合物材料光谱性能的差异进行了分析;研究了偶氮苯聚合物的超快光致双折射过程,并对单偶氮苯聚合物与双偶氮苯聚合物进行了比较,分析了含双偶氮聚合物超快光致双折射过程的来源。

Good correlations were obtained between aromatic ring destruction and trichloroacetic acid , but dichloroacetic acid production were related to not only activated aromatic ring but also nitrogenous type structures such amino acid type structure.

从腐殖质的结构特性与卤乙酸的相关性分析,得出三氯乙酸的形成主要与腐殖质的芳香环的断裂有关。DCAA的形成则与腐殖质上芳香环和含氮官能团的多少有关。

The study showed that the biosorption process could be described well by pseudo-second-order kinetic model and Freundlich isotherm model.Higher cell concentration was favorable to the biosorption.Temperature's effect on the biosorption was not obvious.The oxygenous and nitrogenous functional groups on the cell wall played a very important role in the process of biosorption.Microdeposits were formed by int...

结果表明,菌体对银的吸附量可达91.75 mg/g,吸附过程符合Pseudo-second Order吸附动力学模型,相关系数高达0.999 9;吸附热力学很好地符合Freundlich吸附等温模型,相关系数为0.99;考察菌体浓度和温度对吸附的影响发现,菌体浓度增加有利于对银离子的吸附,温度对吸附影响较小;FTIR、SEM及EDAX实验结果表明吸附存在2种吸附机理,一为菌体表面一些含氮氧的基团对Ag+的络合作用,二为菌体分泌的胞外多糖等物质对Ag+的微沉淀成晶作用。

The factors which affect the rate of evaporation in enclosed LNG storage tank are various, and they mainly are the initial filling rate, the ambient temperature , the insulation structure (effective thermal conductivity ), the initial pressure within the tank, the tank pressure of work , the amount of nitrogen in LNG, the tank volume size and so on.

影响密闭LNG储罐蒸发率的因素是多方面的,主要有储罐的初始充满率、环境温度、储罐保温结构、储罐内的初始压力、储罐的工作压力大小、LNG中含氮量的多少、储罐的容积大小等。

The brand name has since been changed to Ilfochrome Classic. The print consists of polyester sheet material coated with highly fade-resistant Azo color dyes, and has a distinct look. Unlike regular color prints, which chemically create the dyes during processing, Cibachrome material contains all the dyes initially, then bleaches out the unwanted dyes during processing, leaving only the exposed color image in the completed print.

印刷材料由涂着高度防退色的含氮染料的聚酯片材组成,不同于普通的彩色印相——在印相过程中以化学方法来制造染料, cibachrome 材料从最初就包含所有染料,然后在印相的过程中漂去无用的染料,只剩下适当曝光的颜色来完成印制。

We are the spirit of "excellent quality, integrity of reciprocity" principle, we know the quality and technology on Product modeling and the importance of constant innovation and focus on high-quality requirements, the introduction of high-quality China-made high-quality steel and steel products "in Guangzhou Industrial Research Institute of Electrical and Mechanical Heat Treatment Technology Research Center "co-operation to provide customers with high-quality steel heat treatment and testing services, including high-quality vacuum hardening, nitriding, carbonitriding, boron nitrogen permeation, soft nitriding, annealing, quenching and tempering,, the high-frequency surface hardening, surface hardening VHF, chemical surface heat treatment, vapor deposition, such as titanium nitride.

我们本著&卓越品质,诚信互惠&的原则,我们深知质量及技术对制模及产品之重要性,不断创新服务及注重高品质要求,推出国产名优钢厂之优质钢材及与&广州市机电工业研究所热处理技术研究中心&合作为客户提供高品质热处理及钢材化验服务,含高质素真空淬火、氮化、碳氮共渗、硼氮共渗、软氮化、退火、调质、中、高频表面淬火、超音频表面淬火、化学表面热处理,气相沈积氮化钛等。

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