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The effects of the composition of catalyst (the structure and amount of bident ligand and strong acid, the cocatalytic activity of Cu〓, the roles of methanol and phenol etc.) and the copolymerization condition (the reaction time, temperature, amount of ST and CO, the structure and amount of solvent etc.) on catalytic activity were studied. The principle of the copolymerization was investigated.

研究了催化体系组成(含氮双齿配体的结构与用量、强酸的结构与用量、铜盐的助催化作用、甲醇和酚类化合物作用等)和共聚反应条件(共聚反应的温度与时间、溶剂种类与用量、苯乙烯与一氧化碳量等)对溶液共聚反应的催化活性的影响,探索溶液聚合反应规律。

The effects of the composition of catalyst (the structure and amount of bident ligand and strong acid, the cocatalytic activity of Cu〓, the roles of methanol and phenol etc.) and the copolymerization condition (the reaction time, temperature, amount of ST and CO, the structure and amount of dilution reagent etc.) on catalytic activity were studied in detail. Also the optimum copolymerization condition was chosen.

深入考察了催化体系组成(含氮双齿配体的结构与用量、强酸的结构与用量、铜盐的助催化作用、醇类与酚类化合物的作用等)和沉淀共聚反应条件(共聚反应的温度与时间、稀释剂结构与用量、苯乙烯与一氧化碳量等)对该共聚反应的催化活性的影响,优化共聚反应的聚合条件。

In recent years, with the development of various good catalysts especially the ruthenium alkylidenes bearing N-heterocyclic carbene ligands, the RCM reaction has been applied widely in the synthesis of complex organic molecules, biological molecules and natural products etc. The Nobel Prize in Chemistry 2005 goes to Yves Chauvin, Robert H.

近二,三十年来,随着各种性能优良的催化剂的不断发展,尤其是含氮杂环卡宾配体的钌催化剂的出现,关环复分解反应在合成复杂有机分子,生物活性大分子以及天然产物等方面已得到了极为广泛的应用。2005 年的诺贝尔化学奖分别授予了 Yves Chauvin,Robert H。

In my opinion, Cu complexes with unsaturated alcohol to form a complex compound; the nitrogenous compound introduced serves as the complex compound's stabilizing agent and reduces activation energy of reaction; TMPO serves as oxygen carrier and displays it's selective oxidation function. This new method and mechanism also demonstrates significance to other similar organic reactions.3 In the chlorohydrin reaction, NaCIO is replaced by Ca2see Chapter4.4.3.4(2 .A, this method hasn't been reported in previous literature,which exerts more buffer action to the react system, the yield increased from 52% to 88.6%; at the same time it solve the problem of poor stability and low percentage composition of NaCIO.

认为:CuD与烯醇形成络合物:含氮有机物的引入起到稳定络合物,降低活化能的作用:而TMPO则充当携氧子起传递氧的作用,并具有选择氧化功能:这种新的方法和理论对类似的反应(不饱和醇类在络合体系下选择性催化氧化为对应的醛也具有重要的指导作用。3在异戊二烯的氯醇化反应中,用次氯酸钙代替次氯酸钠见第4章4.3.4(2.A,本方法未见文献报道,使反应系统更加温和,收率由52%提高到88.6%:并解决了次氯酸钠稳定性差、有效氯含量低的实际问题,具有重要的实用意义。

Electrochemical behaviors on the surface of jamesonite in an acidic solution of pH4.0 buffer solution containing diethyl dithiocarbamate were investigated by the methods of cyclic voltammetry and AC impedance.The changes of the reactions,electrochemical adsorption,passivation action,electrochemical impedance and interfacial capacitance on jamesonite were discussed under the different conditions of electrode potentials.

用循环伏安和交流阻抗法,研究了脆硫锑铅矿在含乙硫氮的pH 4.0缓冲溶液中的表面电化学行为,讨论了在不同电位下脆硫锑铅矿表面的反应、电化学吸附、钝化作用、电化学阻抗、微分电容的变化。

With the standards established above and calculated results of gas chemistry of 25 nitrogencontaining gas mixtures at 3000K and 4000Pa, the C-H-N phase diagram for diamond growth was constructed kinetically for the first time, which was proved logical by many experiments in literature.

根据以上建立的标准和25种含氮混合物的气相化学计算结果,首次从动力学角度构建了C-H-N三元体系生长金刚石的相图,并为文献中的大量实验证实是基本合理的。

Under normaltemperature condition,it can retard elongation,Promote tillering,increase leafnitrogen and sheath starch content,increase leaf tissue electric resistance andchlorophyll content,increase free protine content;under low temperature stresscondition,paclobutrazol has the ability to minify the permeability of leaf cellmembrance,maintain leaf tissue electric resista...

在常温条件下,多效唑具有延缓早稻秧苗的伸长生长,促进分蘖,提高叶片含氮量和叶鞘淀粉含量,提高叶片组织电阻和叶绿素含量,提高游离脯氨酸含量等方面的生理效应;在低温胁迫条件下,多效唑能够减小秧苗叶片细胞膜透性,维持叶片组织电阻以及延缓叶绿素含量和净光合速度的下降趋势,提高脯氨酸含量,减轻回暖后秧苗的外部伤害程度。

Pyrrole and its derivatives are important pentatomic heterocyclic compounds. They are widely applied in medicine, pesticides, food, household chemicals, flatting putty, testile material, printing, paper making and so on.

吡咯及其衍生物是一种重要的含氮五元杂环化合物,广泛应用于医药农药食品、日用化工、涂料、纺织、印染、造纸等诸多领域,尤其是近年来在感光材料、高分子材料等高科技领域中的应用,更使吡咯类化合物的合成成为人们研究的热点。

These were attributed to the ion interactions resulting from the acid groups of ionomer and the vinylpyridine groups of PSVP.

这是由于体系中的酸基及其盐和含氮碱基的引入,在共混组分间产生了强烈的离子相互作用,从而导致分子间的缔合,使比浓粘度提高。

The cellulose pulp with α-cellulose higher than 90% and polymerisation degree of range of 450~625 was treated with 14%~16% sodium hydroxide solution for 30~40 min under temperature of 40~50°C, and blended with urea in the ratio of 1:2~3. The product was reacted in xylene as solvent at 137°C for 2~3 h.

指出:选用聚合度为450~625、α-纤维素含量大于90%的纤维素桨粕,用14%~16%的氢氧化钠溶液,于40~50℃条件下活化处理30~40min后,与尿素以1:2~3的比例混合,在137℃的二甲苯体系中反应2~3h,便可得到含氮量为2.4%~3.5%的纤维素氨基甲酸酯产物。

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