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The less the oxygen content and the more content of N element in the form of pyrrole-N were observed under stronger microwave power radiation. It was affirmed that the desulfurization capability of activated carbon could be greatly increased by microwave modification. According to the analysis on surface physical and chemical characteristics, a mechanism was concluded: Modified by microwave, functional groups begin to dissociate, alkalescency is enhanced, and surface oxygen content is reduced; the amount of active sites produced by dissociation of oxygen-containing groups increased, so did the pyrrole-N groups. Apparently, the activated energy of SO〓 adsorption decreased.

通过比较微波改性活性炭前后的吸附脱硫能力,结合它们的表面物理和化学性质的变化分析,确认微波改性活性炭的脱硫性能有显著提高,其作用机理在于微波处理后,活性炭表面微观形貌发生了较大的变化,化学基团发生分解,碱性特征增强,表面含氧量减少,以CO形式释出的含氧官能团分解后产生的活性部位和吡咯氮官能团数量增加,吸附SO〓的表观活化能降低。

Cyclic voltammetry indicated that there were Cr→Cr, Cr →Cr oxidation reaction on anode, while there were Cr→Cr, Cr→Cr, Cr →Cr deoxidization reaction on cathode. The graphite electrodes treated by acid and heating could enhance the reversibility and kinetic of the electrode reaction. The nature graphite electrodes had been eroded during charge/discharge process, while the graphite electrodes by activation could avoide corroding by hexad chromium ion. The reversibility and kinetic of the electrode reaction of chromium ion on activation electrode had been increased, so which indicated that graphite surface augment oxygenous function corps which could increase electrode hydrophile capability.

循环伏安实验表明:铬液流电池的电极反应非常复杂,在阳极存在Cr→Cr,Cr→Cr的氧化反应,在阴极存在Cr→Cr,Cr→Cr,Cr→Cr的还原反应;热处理的石墨电极和重铬酸钾处理的石墨电极能提高电极反应的活性和可逆性;在充放电实验中未处理的石墨电极发生严重腐蚀;分别用这两种方法处理过的石墨电极具有防止六价铬侵蚀的功能;铬离子在活化处理过的石墨电极上的反应活性和可逆性增加,可以认为:重铬酸钾溶液活化处理和加热处理后的石墨表面的含氧官能团增加,电极亲水性增强。

In this paper,the nanometer carbon blacks of high oxygenous functional groups were used for carrier of target antitumor medicine,it was studied that the nanometer carbon black was oxidized by two ways and that the oxidized carbon black was used to graft antitumour etoposide(VP-16) by two ways also.

本文以高含氧官能团的纳米炭黑为抗肿瘤靶向药物的载体,研究了纳米炭黑的两种氧化改性方法以及在改性后的纳米炭黑表面接枝抗肿瘤药物依托泊苷(VP-16)的两条合成路线。

From FT-IR we think that the hydrogen bond between the polar oxygenous group on the thin film surface treated with plasma and acetone molecules would enlarge the distance between the carbon black particles, resulting in the addition of the electrical resistance, then the response behavior of the thin film to acetone was improved greatly.

我们通过FT-IR研究认为,等离子体处理后,薄膜表面引进的极性含氧基团与丙酮分子之间氢键的形成会增大炭黑粒子之间的距离,导致了薄膜电阻的极大增加,使薄膜对丙酮蒸气的响应得到很大改善。

The study showed that the biosorption process could be described well by pseudo-second-order kinetic model and Freundlich isotherm model.Higher cell concentration was favorable to the biosorption.Temperature's effect on the biosorption was not obvious.The oxygenous and nitrogenous functional groups on the cell wall played a very important role in the process of biosorption.Microdeposits were formed by int...

结果表明,菌体对银的吸附量可达91.75 mg/g,吸附过程符合Pseudo-second Order吸附动力学模型,相关系数高达0.999 9;吸附热力学很好地符合Freundlich吸附等温模型,相关系数为0.99;考察菌体浓度和温度对吸附的影响发现,菌体浓度增加有利于对银离子的吸附,温度对吸附影响较小;FTIR、SEM及EDAX实验结果表明吸附存在2种吸附机理,一为菌体表面一些含氮氧的基团对Ag+的络合作用,二为菌体分泌的胞外多糖等物质对Ag+的微沉淀成晶作用。

Titanium incorporated mesoporous molecular sieves Ti-MCM-41, Ti-HMS, and Ti-MSU were synthesized through S〓I〓, S〓I〓, and N〓I〓 pathways using cetylpyridium bromide, tetredecylamine, and polyoxyethylene (10) stearyl ether as the structure-directing agents, respectively. The framework structure and the titanium coordination environment of these materials were characterized by XRD, N〓 adsorption/desorption, TG, TEM, FT-1R, DR UV-Vis, and ICP-AES. It was confirmed that the titanium was highly dispersed in the silica-based framework positions, and all samples were free of extra framework titanium impurities. The catalytic performance of these titanium containing mesoporous materials was investigated in the oxidation of styrene with aqueous H〓O〓 as the oxidant.

以TEOS和TBOT为硅源和钛源,分别以溴代十六烷基吡啶、十四胺和十八烷基聚氧乙烯基醚为模板剂,通过S〓I〓、S〓I〓和N〓I〓方式合成了含钛的介孔分子筛Ti-MCM-41、Ti-HMS和Ti-MSU,用XRD、N〓吸附/脱附、TEM、FT-IR、DR UV-Vis和ICP-AES等方法对它们的骨架结构、孔道结构以及钛原子的存在方式等进行了系统表征,结果表明钛原子以高分散的形式存在于以SiO〓为基本单元的介孔分子筛的骨架结构中,制备过程中未形成聚集态的骨架外金属氧化物物种。

Three results are obtained by an orthogonal experiment. The main components of essential oil in separating containerⅠare terpenoid, terpeneless compound is in separating container Ⅱ. Through second-level separation the technological conditions of de-terpene are: pressure 7MPa, temperature 32℃ in separating containerⅠ;pressure 4~5MPa, temperature 32℃ in separating containerⅡ. The optimum technological parameters of obtaining two essential oils are: particle size 0.60mm, pressure 10MPa, temperature 36℃, operating time 90 minutes. There are 1.46% and 1.88% essential oil in separating containerⅠand Ⅱ respectively.

通过正交试验表明:分离器Ⅰ中精油的主要成分是萜烯烃类化合物,分离器Ⅱ中精油的主要成分是由高级醇类、醛类、酮类、酯类等组成的含氧化合物;二级分离脱萜的适宜参数是:分离器Ⅰ的压力为7MPa,分离器Ⅱ的压力与循环压力相同,温度都为32℃;同时得到萜烯烃类精油和低萜精油的最优工艺组合是粒度0.60mm,萃取压力10MPa,萃取温度36℃,萃取时间90min,精油得率分别为1.46%和1.88%。

The improved process produces a polyester of improved color versus other titanyl oxalate catalysts and a novel polyester without the presence of antimony.

此改进的方法制备出一种与采用其它钛氧基乙二酸盐催化剂的方法相比具有改进的色泽的聚酯和一种不含锑的新型聚酯。

At different flow velocity, corrosion rate is further increased by the entrained sand in the medium.

旨在探讨缓蚀剂在含砂的高流速腐蚀介质中的腐蚀抑制和室内评价方法的建立,极端腐蚀条件下改性环氧涂料的性能,以及柴油的微生物处理过程中细菌的协同作用机理,为管道系统的内腐蚀防护应用和石油烃处理提供理论依据和技术支持。

Above the glacial layers sits a red sandstone containing hematite—a mineral that forms only under oxygen-rich skies. Hematite has also been found at the landing site of the Mars rover Opportunity.

覆盖于冰期地层上方的砂岩,则含有只在含氧丰富的环境中才会形成的赤铁矿(火星巡迴者机会号探测车的著陆点亦发现赤铁矿的存在,然因颗粒较粗,故呈灰色。

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