含氧化合物

The ECL intensity and mechanism depends on the type of substituent in indole ring.

吲哚环上含羟基的化合物与含甲氧基的化合物的反应历程不同，引起发光效率差异。

Benzyloxy benzoyldimethylsulfoxide was prepared by the reaction of ethyl 4-benzyloxybenzoate and dimethyl sulfoxide in the presence of sodium hydride, followed by Pummerer reaction with concentrated hydrochloric acid to afford eo-hydroxy-co-thio-methyl-(4/-benzyloxy) acetophenone, which reacted with urea, thiosemicarbazide, semicarbazide hydrochloride and o-phenylenediamine to give imidazolidine-2,4-dione, l,2,4-triazine-3- one and quinoxaline derivatives, respectively.

本文用4-苄氧基苯甲酸乙酯和二甲亚砜为原料，在氢化钠存在下反应，合成了(4′-苄氧基)-苯甲酰基-二甲亚砜。研究了该亚砜在浓盐酸的存在下发生的Pummerer重排反应，用重排产物ω-羟基-ω-甲硫基-(4′-苄氧基)-苯乙酮分别与尿素、氨基脲、氨基硫脲和邻苯二胺反应合成了2，4-咪唑啉-二酮、1，2，4-三嗪-3-酮、喹喔啉等含氮杂环化合物。

In the biological treatment, anaerobic biological treatment is used to reduce selenate ions and/or selenite ions presented in the raw wastewater to transfer to single insoluble selenium.

在生物法中，采用厌氧生物处理来降低原始废液中可溶的硒酸盐与亚硒酸盐，并转化为不溶性的单质硒，从而以不溶性单质硒的形式去除硒酸盐或亚硒酸盐；在絮凝沉淀法中，通常是向生物处理后的废水中加入一种金属盐，使该金属盐与可溶性硒反应并生成一种不溶性硒化合物，从而以不溶性硒化合物形式去除残留的可溶性硒；在过滤法中，将絮凝沉淀法中残留在废水中的不溶性硒去除，这样就能在不用大量化学药剂和不产生大量沉淀的情况下去除含硒废水中的可溶性硒。

A process for the carbonylation of allylic butenyl ether (for example, methyl crotyl ether, 3-methoxybutene-1 and mixtures thereof) or mixture of butadiene and alcohol and production of beta-gamma unsaturated carboxylic acid esters (for example, methyl-3-pentenoate) utilizing a rhodium-containing catalyst for example, dicarbonylacetylacetonate rhodium(I or the like promoted with an iodide-containing compound (for example, HI, AlI3, SnI4, TiI4, CrI3, and CoI2 or the like).

一种将烯丙型丁烯基醚(如甲基巴豆基醚、3－甲氧基丁烯－1及其混合物)或者丁二烯与醇的混合物羰基化的方法，以及由含碘化物化合物(如HI、AlI3、SnI4、TiI4、CrI3和CoI2或等效物)促进，用含铑催化剂如二羰基乙酰丙酮酸铑(I或其等效物制备β－γ不饱和羧酸酯(如甲基－3－戊烯酸酯)的方法。

In Granards' reactionof fluorinated β-ketophosphonium salts we found differentGranard reagents give different reaction mechanisms andPhMgBr realized the enolate reaction of fluorinatedβ-keto-phosphonium salts.

在研究含氟β-酮基鏻盐的β位亲核加成反应中，我们利用含氟α-烷氧基-β-酮基鏻盐与有机锂试剂的亲核加成反应一锅法高度立体选择性地合成了E式或Z式三氟甲基的烯醚类化合物。

On the basis of molecular design and assembly, the polyoxometalate compounds supported by Keggin, Dawson, lacunary Keggin, and Silverton-type etc. polyanions on the basis of well-known and novel polyanions as building blocks were successfully synthesized by the hydrothermal technique, which are"decorated"or"bridged"by organic N-donor and/or O-donor ligands. The study on synthetic conditions and rules for these hybrid compounds and characterization by X-ray crystallography, spectroscopic, thermal, electrochemical and magnetic properties are carried out.

本文主要利用水热合成方法，从分子设计及组装的思想出发，借助不同N和含O的有机配体对多金属氧酸盐阴离子结构进行&修饰&或&桥连&，合成了一些以饱和Keggin结构、饱和Dawson结构、缺位Keggin结构和Silverton结构等阴离子为构筑模块的多金属氧酸盐化合物，研究了这些化合物的合成条件及规律并对它们的晶体结构、谱学性质、热性质以及磁性质进行了研究。

The thesis consists of two main sections. The synthesis of 1,3,4-thiadiazoles,triazolotriazines and dioxapyrrolinopyrazoles containing chiral pyrazolyl moietyfrom D-glucose is described in the first part and the section one is about theDiels-Alder reactions between dienophile enaminones and diene 1,2,4-triazines,which provides a new methodology to construct the pyridine compounds. A total of37 new compounds were synthesized.

本论文包含两部分内容，一是以D-葡萄糖为原料合成含手性吡唑基的1，3，4-噁二唑、三唑并三嗪及二氧代吡咯啉并吡唑类化合物；二是将烯胺酮作为亲双烯体，与双烯体1，2，4-三嗪类化合物发生Diels-Alder反应，发现了一令人意外的构建吡啶类化合物的新方法。

In thesecond chapter, eleven 1,3,4-oxadizoles bearing chiral pyrazolyl moieties(4a-k) andfive triazolotriazines bearing chiral pyrazolyl moieties(5a-e) were obtained from5-[(1"S)-1",2-diacetyl-oxyethyl]-1-phenylpyrazol-3-carboxaldehyde(1) with arylcar-bohydrazide or (5-aryl-1,2,4-triazin-3-yl)hydrazine through an intramolecular1,3-dipolar cycloaddition in the presence of the non-metal oxidant IBD.

其中第二章介绍了以D-葡萄糖为原料制得的5-[(1′S)-1′，2′-二乙酰氧基乙基]-1-苯基吡唑-3-醛(1)分别与芳基甲酰肼、(5-取代苯基-1，2，4-三嗪-3-基)肼反应，在无金属氧化剂—IBD引发下，发生分子内1，3-偶极环加成，采用&一锅煮&法合成了11种含手性吡唑基的1，3，4-噁二唑类化合物(4a-k)和5种含手性吡唑基的三唑并三嗪类化合物(5a-e)。

By setting the retting duration of 20 hours, the factors affecting the residual gum percentage of the retted kenaf fibers are studied. The experimental results show clearly that the following factors have the significant influence on the residual gum percentage of the retted kenaf fibers and show the obvious variation tendency. The preferred processing parameters are as follows: pH value 7. 0、bath ratio 1: 50、reuse percentage of retting liquid 50%、air flow volume 2. 5L/min、temperature 40℃、nitric additives (ammonia is better than nitrates) percentage 0.45%.By comparison with anaerobic retting, the retting duration using aerobes is much shorter than that using anaerobes.

确定了以好氧微生物脱胶作为本课题的脱胶路线后，在特定的脱胶时间（20小时）条件下，通过分析不同参数条件下的残胶率，研究了好氧微生物脱胶的各种影响因素对红麻脱胶的影响规律，并优选出最佳脱胶液回用比为50％，最佳pH值为7.0，最佳气流量为2.5L/min，最佳浴比为1：50，最佳水浴温度为40℃，最佳含氮添加剂为铵盐类化合物，最佳含氮添加剂用量为0.45％。

A reactive phosphorus-containing compound, bis-phenoxy (3-hydroxy) phenyl phosphine oxide was successfully synthesized to produce the phosphorus-containing flame retardant epoxy resin.

合成了一种含磷二羟基化合物双(3-羟基-苯氧基)苯基磷氧化物，并在此基础上合成了含磷环氧树脂BHPPO-EP。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！