含乙氧基的

This dissertation aims to: improvement in regularity of ladderlike polysiloxane through strong H-bonding template and"half-water-hydrolysis"methods; synthesis of several functional polysilsequioxane with ethoxyl, hydro and aminopropyl groups respectively; and the preparation of nanoporous film with good mechanic properties from ladderlike functional polysilsesquioxane with intermolecular porogen via micro-phase separation process.

本论文旨在利用强氢键模板作用和"半水水解-脱氯化氢缩聚"的改进方法，提高反应性的梯形聚硅氧烷的规整度；合成乙氧基封端、含氢基和氨丙基的几种功能性梯形聚硅氧烷；以及探索利用含分子内成孔剂的梯形聚倍半硅氧烷通过微相分离制备低介电常数二氧化硅纳米微孔膜。

The UV-Visible absorption spectra and the fluorescence emission spectra of sixteen tetra-substituted metallo-phthalocyanine complexes {R4PcM, where R=2-［4-(2-sulfonic ethyl)piperazin-1-］ ethoxyl, 2-(piperidin-1-yl)ethoxyl; substitution position at α-position and β-position of phthalocyanine ring; M=Zn, Ni, Coand Cu} were measured.

报道了16种含哌嗪或含哌啶四取代酞菁金属配合物{R4PcM， R=2-［4-(2-磺基乙基)哌嗪-1-基］乙氧基、 2-(哌啶-1-基)乙氧基；取代位置分别在α位和β位； M=Zn， Ni， Co， Cu}的UV-Vis吸收光谱和荧光发射光谱的测定，探讨了中心金属离子、取代基种类及其取代位置、溶剂等因素对酞菁金属配合物UV-Vis吸收光谱和荧光发射光谱性质的影响。

In order to improve the radiation resistance of condensed-type RTV silicone rubber, two kinds of crosslinking agents are synthesized successfully: triethoxysilane with acenaphthenyl groups m.p.

当三乙氧基硅烷和三乙氧基硅烷用作缩合型RTV硅橡胶的交联剂时，由于二者所含的稠环基团的空间位阻较大，因而样品硫化速度较慢。

Two benzothiazole ester compounds containing boron with different alkyl chain, Di-n-hexyl-[2-(2-benzothiazolylthio)] ethyl boric acid ester (BNS-1) and Dicyclohexyl-[2-(2-benzothiazolylthio)] ethyl boric acid ester(BNS-2), were synthesized and their tribological performance as additives in rapeseed oilwas investigated using a four-ball testing machine.

合成了两种含不同烷基链的含硼苯并噻唑酯类化合物，即二正己氧基-2-[(2-苯并噻唑基)硫代]乙氧基甲硼烷(BNS-1)和二环己氧基-2-[(2-苯并噻唑基)硫代]乙氧基甲硼烷(BNS-2)。

The process is carried out by addition reacting nitrogen benzide dye containing R group with carbimide propyl triethoxy-silane to obtain final product.

将含R基团的偶氮苯染料与异氰酸基丙基三乙氧基硅烷进行加成反应即得含偶氮苯染料的硅氧烷先驱体。

A fully ethoxy-terminated polymethylsilsesquioxane has been prepared via a dehydration ethanolysis reaction between absolute ethanol and an ordered ladder-like HO-Me-T, which improved long-term storage stability of HO-Me-T. Meanwhile, EtO-Me-T can still participate in the cross-linking reaction with hydroxy-terminated PDMS in the presence of catalyst.

利用含端羟基的LPS与无水乙醇之间的催化脱水反应合成了一种乙氧基为末端基团的活性梯形聚甲基倍半硅氧烷，有效地改善该类聚合物的长期稳定性；同时，该乙氧基封端聚合物仍然具有活性，可以代替常用的正硅酸乙酯与羟基硅油进行交联反应。

The process comprises the subsequent steps a through e: a reacting phthalic anhydride with fluorobenzene or a derivative thereof in appropriate reaction conditions; b over reducing the product obtained in step a at the ketone moiety; c reducing the product obtained in step b with sodium dihydro-bis (2- 15 methoxyethoxy) aluminate to the corresponding alcohol ; d chlorinat ing the alcohol obtained in step c ; e inserting CO into the product obtained in step d through an appropriate Pd-containing catalytic system.

该方法包括以下步骤a～e：a使邻苯二甲酸酐与氟苯或者其衍生物在适当的反应条件中反应；b完全还原步骤a中获得的产品的酮部分；c用二氢-二(2-甲氧基乙氧基)铝酸钠将步骤b中获得的产品还原成相应的醇；d对步骤c中获得的醇进行氯化；e通过适当的含Pd的催化剂体系，将CO插入到步骤d中获得的产品中。

PK values of 3-ethoxy-N-desmethyldiazepam (3-EtO-NDZ) in ethanol and acetonitrile containing various concentrations of sulfuric acid, determined by spectrophotometry and spectropolarimetry, were found to be 3.4 and 0.63 respectively. Temperature dependent racemization of enantiomeric 3-EtO-NDZ in ethanol containing various acid concentrations was studied by monitoring changes of ellipticity at 365 nm as a function of time on a spectropolarimeter.

3-乙氧基－N去甲基安定（3-EtO-NDZ；diazepam=安定）在含不同硫酸浓度的乙醇和乙腈中的pK值用光谱法和旋光光谱法作了测定，其结果分别为3.4和0.63.3-EtO-NDZ之对映异构体在含各种不同酸浓度的乙醇中与温度相关的消旋过程，用旋光光谱仪选择其圆二色谱在365nm波长处强度的改变为时间函数的方法作了测定。

Ambient temperature self-crosslinking acrylic latexes were prepared through semicontinuous emulsion polymerization using 3 different polymerizable alkoxysilanes, i.e. vinyl tri silane (A172), Vinyl triethoxy silane and γ-methacryloxypropyl trimethoxy silane (A174). The hydrolysis of these siloxanes under different pH was characterized, and dependence of the latex and polymer properties on these siloxanes and their incorporated amounts in the polymers was studied.

使用三种含不饱和双键硅氧烷，乙烯基三硅烷(A172)、乙烯基三乙氧基硅烷和γ-甲基丙烯酰氧丙基三甲氧基硅烷(A174)为功能单体，采用半连续乳液聚合法制备了室温自交联丙烯酸酯乳液，探讨了硅氧烷功能单体在不同pH条件下水解情况以及其种类和用量对乳液及乳胶膜性能的影响。

A series of pH- and temperature-sensitive hydrogels carrying pendant phosphategroups have been synthesized by copolymerizing 2-methacryloyloxyethyl dihydrogenphosphate with N-isopropylacrylamide. The swelling ratio, swelling and deswellingkinetics have been investigated. High loading percentage of lysozyme into hydrogelshas been achieved and the release profile has been studied.

通过N-异丙基丙烯酰胺和含磷酸基团的单体2-甲基丙烯酰乙氧基二氢磷酸酯的共聚合，合成了一类含磷酸基团的既对温度敏感又对pH敏感的水凝胶，研究了它们在不同pH及温度时的溶胀率及溶胀动力学，并初步研究了其对溶菌酶的释放行为。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。