吡啶基

We examined the effects and mechanisms of methyl pentyl 1,4-dihydro-2,6-dimethyl-4-(3-notrophenyl)-3,5-pyridinedicarboxylate (Mn9202), a novel DHPs calcium antagonist and lacidipine on the 5-HT2B receptor in cultured rat stomach fundus smooth muscle cells.

本研究以富含5-HT_(2B)受体的大鼠胃底平滑肌细胞为模板，观察了二氢吡啶类钙拮抗剂2，6-二甲基-4-（3-硝基苯基）-1，4-二氢-3，5-吡啶二羧酸-3-甲酯-5-正戊酯（Mn9202）、拉西地平对 5-HT_(2B)受体功能的影响，并对其影响机制进行了较为深入的研究。

Reporter molecules (thiophenol, bipyridine derivates, cyanopyridine derivates) were attached to different immuno-gold colloids, respectively. By means of the specific adsorption between antigen and antibody, a sandwich structure was constructed, in which labelled immuno-gold colloids and antigen covalently bound to substrate specifically capture different antibodies.

以多种不同的标记分子(苯硫酚，联吡啶类分子，氰基吡啶类分子)分别标记多种不同免疫金溶胶，通过抗体抗原之间所具有的特异吸附性，进一步组装"固相抗体-待测抗原-标记免疫金溶胶"多组分三明治复合体系。

Four non-ionic europium complexes,〓-phen(11),〓·bipy(12),〓·dia(13) and 〓(14)(TTA=2-thenoyltrifluoroacetone, DBM=dibenzoylmethane, phen=phenanthroline, bipy=2,2'-bipyridine, dia=4,5- diazafluoren-9-one, dmbp=4,4'-dimethyl-2,2,-bipyridine), were synthesised and the triboluminescent phenomena of 12, 13 and 14 were firstly observed. Structure determinations of 11,12 and 14 were carried out. The triboluminescence maxima of 12 and 13 are similar to those of their photoluminescence. X-Ray structure analyses show that Eu atoms all exhibit eight-coordinate tetragonal antiprismatic geometries and complexes 11, 12 and 14 are all centrosymmetric.

二、合成了四个非离子型的铕的配合物：〓、〓、和〓(14)[HTTA=2-噻吩三氟甲酰丙酮，DBM=二苯甲酰基甲烷，phen=邻菲罗啉， bipy=2，2'-联吡啶，dia=4，5-二氮杂芴-9-酮，dmbp=4，4'-二甲基-2，2'-联吡啶]，首次报道了12、13及14的摩擦发光性质，测定了11、12及14的晶体结构，并系统地讨论了晶体结构和摩擦发光活性之间的关系。12及13的摩擦发光光谱的极大值均类似与其相应的光致发光光谱，表明它们有相同的激发态。

METHODSThe compounds were prepared by using 2ethylpyridine, through the Whol Ziegler reaction, the Williamson reaction and aminolysis. The effects for ability of memory in mice were measured by swimming maze test.

方法］以2乙基吡啶为原料，经WholZiegler反应、Williamson反应及氨解反应得到2［1（2吡啶）乙氧基］乙酰4取代哌嗪，采用水迷宫法观察所合成的化合物对小鼠记忆力的影响。

Based on studies of RCM reaction of 50 and CM reaction ofacrylonitrile with 1-octene or 1-decene catalyzed by pyridine derivative-coordinatedruthenium benzylidene complexes, it can be concluded that ruthenium benzylidene complexwith the more labile dissociating ligand exhibits the higher initial activity and better catalyticperformance.

吡啶衍生物配位的钌卡宾配合物催化含氰基烯烃50闭环交互置换反应和丙烯腈与1-辛烯、1-癸烯交叉交互置换反应表明，催化剂中吡啶衍生物配体越易解离，其初活性越高，催化活性越好。

Because of the exciting prospect of this kind of materials by direct two photon excitation, thirty pyridinium compounds with six different donors and four different anions have been synthsized and their two photon excited luminescent properties have been studied.

由于这些材料诱人的应用前景，我们以这类吡啶盐为研究对象，合成并系统研究了包含6种推电子基、四种不同阴离子共30个吡啶盐的双光子上转换发光性质。

A few of aryl pyridylalkyl ethers were synthesized by Mitsunobu reaction from substituted phenols 1a-b and pyridyl alcohols 2a-e at room temperature in 45%~70% yields.

在室温下，以取代苯酚1a-b和吡啶烷基醇2a-d为原料通过Mitsunobu反应合成了相应的芳基吡啶烷基醚，反应收率为45%￣70%，反应物2和1之比为1.11∶。

A novel BB'2-type aromatic triamine containing pyridine ring was successfully synthesized by catalytic reduction of the trinitro compound obtained by a modified Chichibabin reaction in acidic medium with hydrazine hydrate.

采用商品化的原料，在酸性介质中经改进的Chichibabin反应先合成含吡啶环的三硝基化合物，再用水合肼催化还原得到一种新型的含吡啶环BB'2型芳香三胺单体。

We have synthesized a series of 4,4′ perfluoro-alkylated bipyridine ligands[4,4′- bis(RfCH2OCH2)-2,2′-bipyridine , Rf=HC4F8(1a), HC8F16(1b), C3F7(1c) and C10F21 (1d)] by nucleophilic substitution reactions. The reaction of fluorinated alkoxide on 4,4′-bis-2,2′-bipyridine results in the systheses of these four fluorinated ligands. These reactions are high yieldings and purification is easy. The structures are analyzed by GC-MASS、NMR、FT-IR etc.

中文摘要我们已合成出一系列在联吡啶的4，4′位置有两个氟化烷基侧链的联吡啶配位基[4，4′-bis(RfCH2OCH2)-2，2′-bipyridine ， Rf=HC4F8(1a)， HC8F16(1b)， C3F7(1c)及C10F21(1d)]，经由亲核取代反应，由4，4′-bis-2，2′-bipyridine反应而得，并具有不错的产率，其纯化也简易可行，所合成之产物并可用GC-MASS、NMR、FT-IR鉴定其化学结构。

The coordinated COD of 3 and 4 can be replaced by carbon monoxide to yield the corresponding dicarbonyl species [(C,N-pyN^C-R) M2]BF4 (14, M= Rh; 15, M= Ir). Ligand substitution of 11a by phosphines and azide causes the de-complexation of pyridinyl-nitrogen donor to generate the corresponding carbene rhodium complexes [(C-pyN^C-Mes)RhPR3] (17a, R = Ph, 17b, R = Et) and [RhN3] (19), respectively, indicating the labile nature of steric-hindered pyridinyl-nitrogen donor.

螯合错合物的吡啶配位，可以容易被σ-予体，如卤离子、叠氮阴离子、膦试剂，置换；但是铑与铱金属螫合物与π-酸试剂，如一氧化碳、异腈，则发生COD被置的产物14a与16；与三甲基亚磷酸酯反应时，COD及吡啶均会被取代而得到单芽的三铑-碳烯错合物18；双膦化合物则会取代铑金属上全部的配位基。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。