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吡啶基

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Among which, the ligands with a so-called "pincer" structure have been investigated deeply recent years with regard to their synthesis as well as their potential application in homogeneous catalysis.

其中一类具有"pincer"结构的吡啶基含氮三齿配体的合成及其在均相催化中的潜在应用,近些年得到了较深入的研究报道。

In search of environmentally benign insecticides with high activity, low toxicity and low residue, a novel series of anthranilic acid esters containing N-pyridylpyrazole were designed and synthesized. All of the compounds were characterized and confirmed by IR, 1H NMR, MS and elemental analysis.

设计,合成了8个新的含N-吡啶基吡唑杂环的邻氨基苯甲酸酯类化合物,结构经FTIR, MS, 1H NMR 和元素分析确证,并且采用X-射线衍射分析方法确证了具有较好生物活性的化合物14d的结构。

In the complex, the tin atom is hepta-coordinated in a distorted pentagonal bipyramid including a bridging pyridyl N atom, by which the one-dimensional infinite chain is formed.

结果表明,该化合物中锡原子配位数为7,处在畸变五角双锥配位场中,化合物通过吡啶基氮原子的桥连作用形成了一维无限链状结构。

Polarization measurements showed that HBPT can inhibit the anodic reactions of the copper in 0.5mol/L H2SO4 and accelerate the cathodal reactions and act as a kind of anodic inhibitor.

极化曲线研究表明3,5-二(2-吡啶基)-1,2,4-三唑在0.5mol/L硫酸溶液中对铜的阳极反应起抑制作用,对铜的阴极反应起促进作用,属於阳极型缓蚀剂。

Resonance Raman spectra of aggregated meso-tetra(4-pyridinium)porphyrin diacid (H8TPyP6+)were studied with excitation near the exciton absorption bands of 470 nm.

研究了近激子吸收带激发下四-(4-吡啶基)卟啉二酸(H8TPyP6+)聚集体的共振拉曼光谱。

This indicates that the interpolymer complexation resulting from thestrong specific interactions has overcome the surface segregation effect caused by thedifferences in the surface free energies.

羟基和吡啶基之间的氢键概率随着羟基含量的增加而迅速增加,在高羟基含量(49 mol%)的情况下,几乎达到1.0,这也从另一个方面说明了在络合物中,链段配对的趋势很强。

In the thesis, a series of novel single and multi-armed oxadiazole bridging ligands and pyridyl-4, 5-imidazole dicarboxylic acid ligands have been synthesized. The coordination chemistry of these novel ligands with transition metal ions was investigated. In addition, two 1, 3, 4-oxadiazole bridging ligands end-capped by chelating Schiff-base coordination sites have been designed and synthesized. The coordination chemistry based on one of the two ligands with metal ions was primarily investigated.

本文报道了一系列新颖的含1, 3, 4-Oxadiazole杂环的单臂及多臂有机配体,研究了它们与过渡金属离子的配位反应化学;合成了吡啶基-4,5-咪唑二羧酸有机配体,研究了它们在水热条件下与过渡金属离子的配位反应化学;另外,还合成了1, 3, 4-Oxadiazloe杂环桥联的双Schiff-base有机配体,初步探讨了其与过渡金属离子的配位反应化学。

NAA, CPPU and EBR all induced parthenocarpic growth together with active cell division and enhanced transcripts of cell cycle-related genes.

奈乙酸,N-(2-氯-4-吡啶基)-N-苯基脲和表油菜素内酯都能诱导黄瓜单性结实,加快细胞分裂和提高细胞周期相关基因的表达。

Objective: To investigate the effect of photodynamic therapy mediated by meso-5, 10, 15, 20-Tetrakis-(N-methyl-4-pyridyl) porphine (TMPyP4) on human tongue carcinoma Tca8113 cells in vitro.

目的:探讨TMPyP4(〔四-(N-甲基-4-吡啶基)〕卟啉)对人舌癌Tca8113细胞的光动力学杀伤作用。

The different intercalation behavior of 5,10,15,20-tetrakis(1-methylpyridinium-4-yl)porphine into α-zirconium phosphate and γ-zirconium phosphate was investigated.

比较了水溶性卟啉meso-四(4-N-甲基吡啶基)卟啉对具有不同层间距和结构的层状磷酸锆的插层行为。

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