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Interaction of Cucurbit [7] Uril with N,N'-Bisalkyl-1,3-(4,4-bispyridyl) Propanes

篇名 七元瓜环与N,N'-二烷基-1,3-(4,4'-二吡啶基)丙烷衍生物的相互作用

The synthesis, crystal structure and characterization of 4, 5-dimethyl-2-(2-pyridyl) imidazole were reported.

为了制备研究2-取代咪唑配合物,设计合成了4, 5-二甲基-2-(2-吡啶基)咪唑,用IR、MS、1H-NMR对其结构进行了确证,并对其晶体结构进行了分析。

Ethyl-4-phenyl-5-(2-pyridyl)-1,2,4-triazole was synthesized by several-step reactions fromα-picoline, and was confirmed by IR、1H-NMR and MS spectra. Part II.

以α-甲基吡啶为原料,经多步反应合成了3-乙基-4-苯基-5-(2-吡啶基)-1,2,4-三唑,并用红外光谱、1H-NMR谱及质谱对产物进行了确证。

The influences of different organic bridging ligands pyrazine,2-pyrazinecarboxylate,4,4′-bipyridine and 1,2-bis(4-pyridyl)ethane on the cobalt vanadate system were explored.

同时还研究了不同的有机桥式配体吡嗪、2-吡嗪羧酸、4,4′-联吡啶和1,2-联(4-吡啶基)乙烷在钴钒体系中的作用。

10-arylmethylene anthrone pyridine compounds and the raw materials for the reaction conditions, join in alkaline, phase transfer catalysts and acceleration response, KI synthesis of containing pyridine 10,10 - dialkyl anthraquinone.

以蒽酮和含吡啶基的化合物为反应原料,在碱性条件,加入相转移催化剂和KI加速反应的进行,来合成含吡啶基的10,10-二烷基蒽酮。

R-1,c-2, t-3, t-4-1,3-bis(4-biphenyl)-2,4-di(4-pyridyl)cyclobutane was obtained in diluted sulfuric acid by photodimerization reaction.

通过反-1-(4-联苯基)-2-(4-吡啶基)乙烯在稀硫酸中的光二聚反应合成了r-1,c-2,t-3,t-4-1,3-双(4-联苯基)-2,4-二(4-吡啶基)环丁烷。

The results show that in the protonation process, because of the effect of meso-(p-methylpyridyl), the changes of the structure and bond charge population are obvious; the frontier molecular orbitals have opposite change trend with the case of meso-yridyl, the rapid exchanges of inner hydrogens of the protonated diacid with solvent protons become more difficult.

结果表明,由于m-甲基吡啶的影响,在质子化过程中结构和键电荷布居有明显变化;前沿分子轨道具有与四吡啶基情形相反的变化趋势,质子化二酸与溶液质子的快速交换作用也变得更困难了。

Active radicals in the photolysis of (Ph3P)3CunXn (n = 1, 2; X = Cl, Br, I, CN) and (Ph3P)CuX (X = Cl, Br, I; biL = 2,2'-dipyridyl, 1,10-phenanthroline) were investigated by combination of spin trapping technique, chromatog.

用自旋捕捉技术-柱色谱-电子自旋共振相结合的方法研究了(Ph3)3CunXn(n=1,2; x=Cl,Br,I,CN)和(Ph3P)CuXX=Cl,Br,I;biL-2,2'-二吡啶基-1,10-菲绕啉光解中的活性自由基。

The products have an isoxazole mother core with 3-morpholinopyridyl substitution and possess an approxi-mately planar structure. In addition a number of ester groups, amino groups, triazole groups and oxazolidi-none groups were introduced to 5-position of the isoxazole mother core.

这些化合物均以异噁唑为母核,具有近似的平面结构,在异噁唑环的3-位引入吗啉吡啶基,而在5-位引入酯基、取代氨基、三唑环和噁唑烷酮环。

This thesis is concerned with the synthesis of new chiral sulfinyl NADH models, whose key step is the synthsis of chiral R-3-pyridyl sulfoxides.

本论文的研究工作主要是合成新的手性亚砜类辅酶NADH模型物,工作重点在手性R基-3-吡啶基亚砜的合成上。

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