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The comples formed with phen,dipy and variant valence metal such as Fe,Co,Ru and so on was statable and had higher electric potential at low valence.There was difference between the colours of low and high valence methal complex,so it played very important rule in oxidate-reduction titration and spectrophotometry.

邻二氮菲、联吡啶与铁、钴、钌等变价元素形成配合物,低价态呈稳定态,电对电位升高,且高低价态配合物颜色有明显差异,使之在光度分析,氧化还原滴定中获得重要应用。

MCM-41, HMS, and MSU mesoporous silica molecular sieves were prepared via S〓I〓, S〓X〓I〓, S〓I〓, and N〓I〓 assembly pathway, in which cetylpyridium bromide, tetredecylamine, and polyoxyethylene (10) stearyl ether was used as the template, respectively. The mesostructures were characterized and confirmed by XRD, N〓 adsorption/desorption, TG, and high resolution TEM. The difference and relationship between these mesophases were also investigated.

分别以溴代十六烷基吡啶、十四胺和十八烷基聚氧乙烯基醚为模板剂,通过S〓I〓、S〓X〓I〓、S〓I〓和N〓I〓&超分子组装模式&合成了具有MCM-41、HMS和MSU结构的介孔SiO〓分子筛,用XRD、N〓吸附/脱附、TG和高分辩TEM等方法对它们的骨架和孔道结构进行了表征,并系统地比较了这几种介孔结构之间的区别与联系

Titanium incorporated mesoporous molecular sieves Ti-MCM-41, Ti-HMS, and Ti-MSU were synthesized through S〓I〓, S〓I〓, and N〓I〓 pathways using cetylpyridium bromide, tetredecylamine, and polyoxyethylene (10) stearyl ether as the structure-directing agents, respectively. The framework structure and the titanium coordination environment of these materials were characterized by XRD, N〓 adsorption/desorption, TG, TEM, FT-1R, DR UV-Vis, and ICP-AES. It was confirmed that the titanium was highly dispersed in the silica-based framework positions, and all samples were free of extra framework titanium impurities. The catalytic performance of these titanium containing mesoporous materials was investigated in the oxidation of styrene with aqueous H〓O〓 as the oxidant.

以TEOS和TBOT为硅源和钛源,分别以溴代十六烷基吡啶、十四胺和十八烷基聚氧乙烯基醚为模板剂,通过S〓I〓、S〓I〓和N〓I〓方式合成了含钛的介孔分子筛Ti-MCM-41、Ti-HMS和Ti-MSU,用XRD、N〓吸附/脱附、TEM、FT-IR、DR UV-Vis和ICP-AES等方法对它们的骨架结构、孔道结构以及钛原子的存在方式等进行了系统表征,结果表明钛原子以高分散的形式存在于以SiO〓为基本单元的介孔分子筛的骨架结构中,制备过程中未形成聚集态的骨架外金属氧化物物种。

To further testify the high efficiency of these new reagents in the synthesis of sterically hindered peptides, we successfully synthesized the extensively -N-methylated peptide moiety of the antineoplastic and lipophilic depsipeptide Dolastatin 15 using reagent BEP and FEP. We also synthesized the highly hindered tetrapeptide segment of Cyclosporin A using reagent BEMT and BEP, respectively.

为进一步检验这类吡啶正离子型缩合剂在有空间位阻的多肽合成中的性能,我们以BEP和FEP为缩合剂,成功地合成了具有抗肿瘤活性的亲脂性酯肽Dolastatin 15分子中高N-烷基化的肽链部分;分别以BEMT和BEP为缩合剂合成了生物活性肽Cyclosporin A中空间位阻最大的四肽片断。

This article introduces the naming, properties, usage,chemical structure and sensitization principal of the photoemulsion madeof styryl phridine salts.

本文详细介绍了有机苯乙烯基吡啶盐树脂感光胶的命名、性能特点、用途、化学结构及其感光原理、使用该胶制备网印版的方法及国外应用概况,并对此种感光胶的主要成分的光化反应机理进行了论述。

A new organic dye ,trans,trans-4-{4-[4-(N,N-diphenylamino)styryl]styryl}N-methylpyridinium iodide,has been synthesized and structurally investigated.

合成了一种新型有机染料,反式,反式-4-{4-[4-苯乙烯基]苯乙烯基}-N-甲基吡啶碘盐。

A three-level energy model is forwarded on the nonlinear absorption properties o f a two-photon absorption dye trans-4-[4′-(N- hydroxyethyl- N-eth ylamino)styryl]-N-methylpyridinium p-toluene sulfonate.

提出了有机染料反式 4 [4′(N 羟乙基 N 乙基胺基)苯乙烯基 ] N 甲基吡啶对甲苯磺酸盐非线性吸收的三态模型。

The results showed that sulfourea and cetylpyridinium bromide respectively had an inhibitive effect on corrosion of 16Mn steel under thin electrolyte film with H_2S.

结果表明,硫脲和溴化十六烷基吡啶分别都表现出一定的缓蚀效果,复配后具有缓蚀协同效应,存在一个最佳缓蚀浓度极值和一个最佳缓蚀浓度比。

The inhibitive effect of each sulfourea and cetylpyridinium bromide and their synergistic inhibitive effect on 16Mn steel under thin electrolyte film with H2S were investigated by using potentiodynamic polarization technique and EIS.

用极化曲线和交流阻抗技术研究了硫脲和溴化十六烷基吡啶在复配前后对含H_2S 薄层液膜下的16Mn钢的缓蚀行为,得到了一些重要结论,并对其进行解释和讨论。

The method of activating hydroxyls of fullerenols using 2-fluoro-l-methylpyridinium p-tolu- ene sulphonate to covalently linking with bovine serum albumin and further its effect on BSA was studied.

考察了2-氟-1-甲基吡啶对甲苯磺酸盐对富勒醇羟基的活化方法,以便将富勒醇通过共价交联的方法与牛血清白蛋白连接,进而研究富勒醇修饰对BSA所造成的影响。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

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