吡啶

The harmonic vibrational force field and the vibrational spectrum of γ-picolinic acid have been calculated by the ab initio gradient program TEXAS using a STO-4-21G basis set.

本文采用TEXAS分析梯度法从头计算程序，以STO-4-21G基组计算了γ-吡啶甲酸的谐性力场和振动光谱。

The vibrational spectra of two isotopic derivatives of γ-picolinic acid (-C^1^6O~2D,-C^1^8O~2H) have been predicted with the SQM force field resulting from the transferred scaling factors. The calculated isotopic shifts are in good agreement with experimental data.

用这组校正因子得到的力场预测了γ-吡啶甲酸的两个同位素衍生物(-C^1^8O~2H和-C^1^6O~2D)的振动光谱，所得同位素位移值与实验数据符合良好。

Using zeolite NaY and ZSM-5 as solid support, the zeolite-encapsulated vanadium picolinic complexes catalyst are synthesized and examined as "ship-in-a-bottle"catalyst.

本文进行了将钒氧吡啶酸络合物负载于NaY分子筛和ZSM-5分子筛中合成&ship-in-a-bottle&型非均相络合物催化剂的研究工作。

A triarylamine-based picolinic acid was synthesized through the Ullmann reaction and Negishi coupling reaction. Using this class of picolinic acid derivative as an auxiliary ligand and 1-phenylisoquinoline as a cyclometalated ligand, a cyclometalated iridium complex was also prepared.

通过Ullmann反应和Negishi偶联反应，合成了一种含三芳胺功能基的吡啶-2-甲酸衍生物；并以此为辅助配体、1-苯基异喹啉为环金属配体，设计合成了一种新型环金属铱配合物。

A triarylamine-based picolinic acid was synthesized through the Ullmann reaction and Negishi coupling reaction. Using this class of picolinic acid derivative as an auxiliary ligand and 1-phenylisoquino-line as a cyclometalated ligand, a cyclometalated iridium complex was also prepared.

通过Ullmann反应和Negishi偶联反应，合成了一种含三芳胺功能基的吡啶－2-甲酸衍生物；并以此为辅助配体、1-苯基异喹啉为环金属配体，设计合成了一种新型环金属铱配合物。

The 91% ee value was obtained by the pinacol coupling reaction catalyzed by 15mol% Schiff-base prepared by the chiral 1, 2-Diphenyethylenediamine and 2-pyridinecarboxaldehyde.

2由手性1，2-二苯基二胺与两分子2-吡啶醛缩合的Schiff-Base催化的Pinacol偶联反应，仅用15mmol％的量，可取得91％的ee值，这是不对称Pinacol偶联反应最好的结果之一。

The reaction mechanism was studied and the proposed methods were applied to the determination of SOD activity.Second, baded on sodium terephthalate trapping HO, an automated spectrofluorimetry for determining HO with flow injection analysis was developed. It was applied to the anti-oxidation determination of maize pollen polysaccharose and natural foods.

一设计合成了两种用于超氧阴离子自由基识别检测的荧光探针——香草醛缩-8-氨基喹啉和2-吡啶甲醛苯并噻唑啉，用普通荧光法和流动注射荧光法对超氧阴离子自由基进行分析测定，研究了反应机理，并将其用于超氧阴离子自由基和超氧化物歧化酶活性的测定。

Objective: To investigate the effect of photodynamic therapy mediated by meso-5, 10, 15, 20-Tetrakis-(N-methyl-4-pyridyl) porphine (TMPyP4) on human tongue carcinoma Tca8113 cells in vitro.

目的：探讨TMPyP4（〔四－（N-甲基－4-吡啶基）〕卟啉）对人舌癌Tca8113细胞的光动力学杀伤作用。

The different intercalation behavior of 5,10,15,20-tetrakis(1-methylpyridinium-4-yl)porphine into α-zirconium phosphate and γ-zirconium phosphate was investigated.

比较了水溶性卟啉meso-四(4-N-甲基吡啶基)卟啉对具有不同层间距和结构的层状磷酸锆的插层行为。

In chatpter three the mechanism of the gold-catalyzed cycloisomerization of propargylic pyridine was reported.

论文第三章将报道金催化的炔丙基吡啶衍生物的环异构化反应的机理研究结果。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。