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Three metal ion bridged self-assembled films of cis -di-bis(2,2'-bipyridyl-4,4'-dicarboxylate) ruthenium were fabricated and characterized by contact angle, UV spectra, cyclic voltammetry and XPS. Their photoinduced electron transfer properties were examined.

本文通过三种金属离子桥联的方式制备了一系列cis-RuL22 (L代表4,4'二羧基-2,2'联吡啶)自组装膜,并利用接触角,UV光谱,循环伏安法以及XPS对自组装功能膜进行了表征。

ABSTRACT In this paper, by employing dicarboxylic acids with special conformation, i.

利用几个结构上有特点的二元羧酸,即2,6-吡啶二甲酸、三个异构体苯二甲酸,顺丁烯二酸和4,4'-联苯甲酸作为首要桥基配体,并结合使用含氮中性配。。。

Factory engaged in medicine, veterinary medicine, agricultural chemicals and raw materials development and production of intermediates, the series of export products: 2,2 - bipyridine, 2,6 - dihydroxy toluene, propiconazole intermediates, phenol line P , Fluometuron, fluorine pyronaridine oxadiazon, oxadiazon pyronaridine fluorine intermediates, Robenidine hydrochloride and so on.

本厂从事医药、兽药、农用化学品原料药及中间体的研制与生产,系列出口产品:2,2-联吡啶,2,6-二羟基甲苯,丙环唑中间体,酚线磷,伏草隆,氟咯草酮,氟咯草酮中间体,盐酸氯苯胍等等。

Dimethylamino)ethyl methacrylate was polymerized using PS-CH_2Cl as macroinitiator and CuCl/ 2,2 '-Bipyridyl as catalyst in toluene to acquire amphiphilic brush-type copolymers of PS-g-PDMAEMA.

再以氯甲基化的聚苯乙烯(PS-CH_2Cl)为大分子引发剂,在CuCl和2,2′-联吡啶(2,2′-Bipyridyl,bpy)存在下,以甲苯为溶剂,进行甲基丙烯酸N,N-二甲胺基乙酯2-(Dimethylaminoethyl methacrylate,DMAEMA的ATRP聚合,得到两亲性的梳状共聚物PS-g-PDMAEMA。

The influences of additives [K4Fe6, 2, 2'-dipyridyl and L-argiine] on the depositing rate and stability of electroless copper bath and the corrosion resistance, conduction and adhesion of copper plating were investigated using electrochemical methods etc.

用电化学等方法,研究了添加剂亚铁氰化钾、2,2'-联吡啶和L-精氨酸对陶瓷化学镀铜镀液的沉积速度与稳定性、镀层的耐腐蚀性、导电性及结合力的影响。

A series of mixed rare earth complexes of europium and lanthanum with o-aminobenzoate and 2,2-dipyridyl were synthesized by the reaction of EuCl3 and LaCl3 with o-aminobenzoate and 2,2' dipyridyl in solution.

用邻氨基苯甲酸和2,2'-联吡啶与氯化铕和氯化镧在溶液中反应,合成了混合稀土配合物。

The electroless copper plating was studied in a bath consisting of glyoxylic acid as reducing agent,Na2EDTA as complexing agent,both 2,2′-dipyridyl and K4Fe6 as additives,focused on the influence of the additives on the deposition rate,as well as on the composition,structures and surface morphology of the deposits.

以乙醛酸作还原剂、Na2EDTA为络合剂、2,2′-联吡啶和亚铁氰化钾作为添加剂组成化学镀铜体系,研究了两种添加剂对化学镀铜速率、镀层表面形貌、组成和结构的影响。

A series of hydrogen-bonding associated main-chain complexes based on dipyridyl and dicarboxylic acid derivatives have been prepared by slow solvent evaporation, and a comparative investigation has been conducted on their thermotropic phase transitions and liquid crystalline behavior by FTIR, DSC and polarized optical microscopy.

采用慢挥发溶剂组装方法制备了一系列羧酸/吡啶氢键缔合的主链型超分子复合物,并采用FTIR, DSC以及偏光显微镜等对其相转变与热致液晶相行为进行了比较研究。

Methods In the medium of H2SO4, the catalytic action of Feon the oxidation of dibromomethyl carboxyazo by KIO4 was effectively inhibited by EDTA with α,α'-dipyridyl as an activator of the reaction.

方法在硫酸介质中,以α,α'-双吡啶为活化剂,Fe催化碘酸钾氧化二溴对甲基偶氮羧的反应可被微量EDTA有效阻抑,被过量EDTA有效终止。

A highly ordered copper phthalocyanine-3,4',4",4"'-tetrasulfonic acid, tetrasodium salt/4,4'-dipyridyl dihydrochloride nanotube array was successfully fabricated by the layer-by-layer self-assembly technique using micropore anodic aluminum oxide as templates. The assembly process of the nanotube array was investigated by UV-Vis spectrometry, XRD and FT-IR, and the morphology of the nanotubes was analyzed by scanning electron microscopy and transmission electron microscopy, respectively.

在阳极多孔氧化铝模板中利用层层自组装技术制备出了高度有序的聚电解质磺化酞菁铜/4,4′-联吡啶盐酸盐纳米管,并对其组装过程用UV-Vis, XRD和FT-IR进行了分析,纳米管的微观形貌通过SEM和TEM进行表征。

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