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吡啶

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Based on analysis of degradation and transformation of organic compounds in coke plant wastewater through every stage of the A 1 A 2 O biofilm system,several typical nitrogen heterocyclic compounds (pyridine,indole,quinoline,isoquinoline,2\|methyl quinoline and 8\|hydroxyl quinoline) in coke plant wastewater were selected for the study.

在对焦化废水中有机物在A1 A2 O生物膜系统中降解转化规律进行分析的基础上,选取焦化废水中 6种主要的含氮杂环化合物:吡啶、吲哚、喹啉、异喹啉、2 甲基喹啉、8 羟基喹啉,与苯酚共同配制成溶液,在A1 A2 O生物膜系统中运行,结果表明上述几种含氮杂环有机物在A1 A2 O系统中都可得到较完全的去除。

In this research, two novel compounds in which alkylenedithiomethylene Malonic acid act as the main coordination agents and the compounds containing N atom (such as pyridine, Phenanthroline Ethanediamine and 4,4'-Bipyridinyl) act as the associating coordination agents have been synthesized by the means of solution and solid-liquid diffusing reactions. 9 coordination complexes and polymers have been designed and synthesized in which the transition metals Cu and Zn acted as the centre ions. These compounds have been characterized by X-ray single crystal diffraction analysis, and some properties of them have been tested and analyzed.

本论文设计合成了两种结构新颖的含有二硫缩烯酮结构的丙二酸类化合物,以此为主要配体,以含氮化合物(吡啶、邻菲罗啉、乙二胺和4,4'-联吡啶)为辅助配体,采用常规溶液合成和固-液相扩散等方法,设计合成了9个过渡金属Cu和Zn离子配合物和配位聚合物,采用单晶X-射线衍射等技术对晶体结构表征,并对其部分性质进行了测试和分析。

Compared to bis(1-phenylisoquinolyl-N,C2') iridium, the iridium complex containing the triarylamine-based picolinic acid displays increased MLCT transition and low oxidation potential and is expected to be a promising red phosphorescent material.

与传统的二(1-苯基异喹啉)(吡啶-2-甲酸)合铱配合物相比,设计的环金属铱配合物具有增强的MLCT电子跃迁吸收和低的氧化电位,是一种有发展潜力的红色磷光材料。

The nitrogen in the coal exists in the forms of pyridine (N-6), pyrrolic and pyridone (N-5), quaternary nitrogen and nitrogen oxides. The N-Q near 401.5eV is assigned to a protonated or oxide form of pyridinic nitrogen. On this basis, the nitrogen in six-membered rings is the dominant in Yibin coal.

研究结果表明,宜宾煤中氮的官能团有4种,即吡啶(N-6)、吡啶(N-5)、质子化吡啶和氮氧化物,其中吡咯含量最大,煤中的N-X就是N-O,是煤中吡啶结构氮与氧直接结合的结果。

A strange chemical term "pyridyl", so that listed companies in Nanjing Red Sun in 2008, quickly became popular.

一个奇怪的化学术语&吡啶&,使上市公司2008年在南京红太阳,很快流行起来。

Methyl - 2- pyridyl) merhylenerhodanine ; Gold.

5-(3-甲基-2-吡啶);亚甲基若丹宁;金;光度法

It is found that when the molar ratio of sulphoxide,pyridine and acetyl bromide is 1∶0.6∶0.4,the catalytic effect on the ring-enlargment is the best,and the yield and purity of the final product can reach 76% and 97% respectively at a pH of 1.8 in toluene under refluxing for about 3.5h.

通过正交实验可得出以下结论:当N,N′-双脲-亚砜为2.5∶1,乙酰溴-亚砜为0.4∶1,吡啶-乙酰溴为1.5∶1,回流时间为3.5h,酸化pH值为1.8时,扩环反应结果最好,总收率可达76%,纯度97%以上。

The effect of the different coupling unit s on the spin multiplicities of the ground states and their stabilities was investigated by means of .

利用—·N—S—为自旋中心,苯为端基,苯、吡啶、哒嗪、嘧啶、吡嗪、三嗪为耦合单元,设计三种不同排列方式的新型稳定高自旋分子。

The results showed that Kaidimycin was chemically neutral, macrocylic polylactones, stable and liable to dissolve into water and pyridine, slight to dissolve into methanol, ethanol and N-butanol, difficult to dissolve into ethyl acetate, acetone, benzene and chloroform. Chemical reaction of functional group of Kaidimycin showed that it had glycoside, amino acid and aldehyde, no reducing sugar, polypeptide and phenol.

凯地菌素属中等极性的、中性抗生素,极性纸层析结果与多烯类抗生素的纸层析结果相似:易溶于水、吡啶,微溶于甲醇、乙醇、正丁醇,不溶于乙酸乙酯、丙酮、苯、三氯化碳;对高温、光照和紫外处理有很好的稳定性;官能团反应试验结果发现,凯地菌素可能含有糖苷键、氨基酸伯氨基和醛基,不含有还原糖、多肽和酚基,高锰酸钾、浓硫酸反应与多烯大环内酯类抗生素的特性相似;并且依据纯品,采用生物法和分光光度法对摇床发酵液进行了效价的测定。

Advances on the development of new oxidation reagents and methodologies and their applications in both target-and diversity-oriented synthesis have been regularly surveyed and constituted one of the most extensively and actively investigated areas of current organic synthesis.1 In this context,a plethora of oxidants,including those small organic molecule-based reagents (such as Dess-Martin periodinane,Swern oxidation,Moffatt oxida- tion,Corey-Kim oxidation,and 三氧化硫/pyridine)and metal-based systems(such as Jones reagent,Collins reagent,pyridinium chlorochromate,pyridinium dichromate,barium permanganate, manganese dioxide,ruthenium tetroxide,silver carbonate,and Oppenauer oxidation),have been identified to be powerful tools promoting conversion of various alcohols into their corresponding aldehyde or ketone products and thus evolved as a most important class of tools in synthetic chemists'arsenal.

关于新的氧化试剂和方法,在两个目标和多样性为导向的发展及其应用合成的进步定期调查,构成一个最广泛,积极探讨在这方面,过多的地区目前有机合成。1氧化剂,包括有机小分子为基础的试剂(如Dess - Martin氧化剂,斯文氧化反应,氧化法特,科里,金氧化,三氧化硫/吡啶)和金属为基础的系统(如琼斯试剂,柯林斯试剂,吡啶氯铬,吡啶铬,钡锰,二氧化锰,四氧化钌,银碳酸盐和开瓶器氧化),已被证实为推动中相应的醛或酮醇转化的各种产品,功能强大的工具,因而作为一个最重要的阶级演变在阿森纳的工具合成化学家。

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