吡啶

In chapter three, molecular imprinting chiral stationary phases against amino acid derivatives utilizing 2-vinylpyridine+acrylamide (2-VP+AM) as combined functional monomers were prepared. Comparing combined functional monomer 2-VP+AM with AM and methacrylic acid+2-VP, the former, 2-VP+AM showed higher imprinting ability. Explanation was given according to the compatibleness between the functional monomer and the imprinted molecule.

第三章系统考察了复合功能单体2-乙烯基吡啶+丙烯酰胺制备氨基酸衍生物分子烙印手性固定相的情况，发现复合功能单体2-乙烯基吡啶+丙烯酰胺烙印体系与丙烯酰胺及复合功能单体2-乙烯基吡啶+甲基丙烯酸烙印体系相比，对氨基酸衍生物表现出更好的烙印能力，验证了功能单体与烙印分子之间存在着匹配性的观点。

After the diazotization, a mixture of 2,3,5-trichloropyridine and 3, 5- dichloropyridine-2-ketone was got as a result of Sandmeyer reaction.

收率达84.7%。接着，我们以制得的2，3，5-三氯吡啶为合成2，3-二氟-5-氯吡啶的原料，用NMP为溶剂，加入KF和CsF的混合氟化剂，高温下反应合成了2，3-二氟-5-氯吡啶。

The degradation and removal of nitrogenous heterocyclic compound-pyridine under aeration stripping, aerobic, anoxia, anaerobic conditions and co-metabolism with quinoline, 2-methylpyridine, aniline, indene, naphthalene in A2/O process were conducted by flask-shaking tests.

通过摇瓶试验研究了氮杂环化合物吡啶在曝气吹脱、好氧、缺氧和厌氧条件下的降解规律以及吡啶与喹啉、2-甲基吡啶、苯胺、茚和萘共代谢条件下在A2/O工艺中的去除规律。

Based on broad information collection, author compared and studied on the old synthesis process, and proposed the better process that started from benzyl chloride, then according to the sequence of " synthesis of benzylamine, synthesis of N-benzyl-N--acetamine, synthesis of 2-chloro-5-methylpridine ,2-chloro-5-trichloromethylpyridine,2-chloro-5-trifluropyridine " five steps to get the final product, CTFP.

本文在查阅大量文献资料和对2-氯-5-三氟甲基吡啶合成路线进行分析比较的基础上，提出了较佳合成路线，即以氯化苄为原料，合成的反应步骤为&苄胺&合成、&N-苄基-N--乙酰胺&合成、&2-氯-5-甲基吡啶&合成、&2-氯-5-三氯甲基吡啶&合成、&2-氯-5-三氟甲基吡啶&合成五步。

It isconfirmed by ~1H NMR,~(13)C NMR and X-ray crystallographic analysis that complexes 60-63are monopyridine complexes and show distorted square pyramid geometries; complexes 64and 65 are bispyridine complexes and show pseudo-octahedral geometries, where twopyridine ligands are in cis arrangement and trans to the NHC and the benzylidene ligandrespectively, the bond length between ruthenium and pyridine ligand trans to the benzylideneligand is 16 pm longer than the bond length between ruthenium and pyridine ligand trans tothe NHC ligand.

1H NMR、~(13)C NMR及X射线单晶衍射分析证明，配合物60-63是单吡啶衍生物配位的钌卡宾配合物，具有变形的四方锥构型；配合物64、65为双吡啶衍生物配位的钌卡宾配合物，具有变形的八面体构型，其中两个顺式配位的吡啶衍生物分别处于氮杂环卡宾和苯亚甲基的反位，处于苯亚甲基反位的吡啶衍生物对应的钌-氮键长要比处于氮杂环卡宾反位的长出16 pm。

In searching for novel and high active fungicides with pyridyl moiety, with Dimethomorph as a model compound and isonicotinic acid as the main starting material, twenty-seven title compounds were designed and synthesized through chlorination, Friedel-Crafts acylation, Wittig-Horner reaction and other steps. All the target structures were confirmed via 1H NMR and elementary analysis.

为了寻找具有高活性的含吡啶杂环杀菌剂，以烯酸吗啉为模板化合物，以异烟酸为起始原料，通过卤代反应、Friedel-Crafts酰基化反应、Wittig-Homer反应等，将吡啶－4-基或2-氯吡啶－4-基引入到模板结构中，设计合成了27个4-［3-（吡啶－4-基）－3-取代苯基丙烯酰］吗啉类化合物，其结构通过1H NMR和元素分析确证。

Macrocycle with one pyridyl unit and one aryl oxdiazole unitCondensation of Ts-amino acids with 2,6-bishydroxymethyl pyridinegave di-esters in the presence of DCC and TsOH in pyridine. DMAP,another acylation catalyst was also discussed in our esterification.

二。含一个吡啶环和一个二苯基噁二唑单元：直接采用Ts保护的氨基酸与吡啶二醇在吡啶-TsOH反应体系中，在DCC作用下生成吡啶二醇二酯，讨论了酯化过程中不同酰基化试剂的应用。

The nitrogen in the coal exists in the forms of pyridine (N-6), pyrrolic and pyridone (N-5), quaternary nitrogen and nitrogen oxides. The N-Q near 401.5eV is assigned to a protonated or oxide form of pyridinic nitrogen. On this basis, the nitrogen in six-membered rings is the dominant in Yibin coal.

研究结果表明，宜宾煤中氮的官能团有4种，即吡啶(N-6)、吡啶(N-5)、质子化吡啶和氮氧化物，其中吡咯含量最大，煤中的N-X就是N-O，是煤中吡啶结构氮与氧直接结合的结果。

The result of the test showed that the fed quantity of TiO2 was 1.25 mg／mL,the photocatalytic degradation of the pyridine was in conformity with the first order kinetic equation,the feeding of 0.2％H2O2 obviously increased the degradation rate of the pyridine and the nitrogen in the pyridine converted into ammonia nitrogen;the pearlite-loaded TiO2 had the same catalytic effect as that of powered TiO2 and was easy to recover and reutilize.

以钛酸四丁酯水解法制备TiO2，采用溶胶一凝胶法在膨胀珍珠岩上负载TiO2，在UV-TiO2体系中对水中吡啶进行光催化降解，结果表明：TiO2加入量为1.25mg／mL，吡啶的光催化降解符合一级动力学方程，加入0.2％H2O2可明显加快吡啶的降解速度，吡啶中氮转化为氨氮，珍珠岩负载型TiO2与粉末TiO2具有相同的催化效能，且便于回收和重复使用。

There are some isomeric compounds of hydroxypyridinone. The compounds of 2-hydroxy-6-pyridinone have been used to dyestuff and pesticide widely. The compounds of 3-hydroxy-2-pyridinone and 3-hydroxy-4-pyridinone are paid attention to, because they are very useful heavy metal chelations. Especially, they are wonderful candidate medicament for the toxicosis of depleted uranium, so they can settle the DU jeopardize to the people.

羟基吡啶酮化合物有不同的同分异构体，2-羟基-6-吡啶酮已被广泛用于染料和农药行业，而3-羟基-2-吡啶酮和3-羟基-4-吡啶酮也引起了人们的重视，因为这两种异构体的化合物是非常理想的重金属络合剂，尤其重要的是，它可作为解决贫铀中毒的候选药物，有望解决战争中由于贫铀中毒带来的危害。

Fancy gold-plated dangling earrings with facetted White Opal crystals.

花式镀金悬垂耳环与facetted白欧泊水晶。

This essay chooses the study aim from biology teachers in middle school in Shi Jiazhuang which tells us that most of the middle school biology teachers in Shi Jiazhuang have the"burnout", lower successfulness, individualize.

本文选取石家庄市初中生物教师作为研究对象，运用问卷调查的方法对石家庄市初中生物教师职业倦怠的现状进行调查，调查结果发现，石家庄市初中生物教师这一群体普遍存在职业倦怠，情感枯竭程度偏高，成就感偏低，去个性化程度最为严重。