吡啶

This thesis includes two parts. One part studied the two photon excited luminescent properties of thirty pyridinium compounds in solution, another part studied the two photon excited luminescence properties of HMASPS and HEASPS in polymer matrix.

论文分为两个部分：第一部分研究的是吡啶盐溶液的双光子上转换性质，第二部分研究的是吡啶盐HMASPS和HEASPS在聚合体系中的双光子上转换性质。

Because of the exciting prospect of this kind of materials by direct two photon excitation, thirty pyridinium compounds with six different donors and four different anions have been synthsized and their two photon excited luminescent properties have been studied.

由于这些材料诱人的应用前景，我们以这类吡啶盐为研究对象，合成并系统研究了包含6种推电子基、四种不同阴离子共30个吡啶盐的双光子上转换发光性质。

With sodium acetate as catalyst, inosine was esterified with acetic anhydride in the yield of 92% to give 2',3',5'-triacetyl inosine, which was treated with pyridine and phosphorus oxychloride to form a pyridinium solution, followed by performing an amination at 40℃ and 0.25~0.30 MPa to achieve adenosine in the yield of 67%.

肌苷在醋酸钠存在下与醋酸酐发生酯化反应以92%的收率得到2'，3'，5'-三乙酰肌苷，其化合物经吡啶和三氯氧磷处理形成吡啶盐溶液，未分离直接在40℃、0.25~0.30 MPa压力下进行氨解反应以67%产率制得腺苷。

The enhancement of the reaction activity is attributed to the phasetransfer capability of the built-in quaternary ammonium and pyridinium salts of theMn catalyst.

分子内季铵盐和吡啶盐具有相转移能力，对于取代色烯不对称环氧化的作用与外加的吡啶盐和卤化铵的作用相似，使Mn催化剂催化取代色烯环氧化反应的活性明显提高。

The largest chemical shifts were observed for the proton 1.48 ppm adjacent to the central pyridinium ring and para-protons 1.47 ppm with respect to the nitrogen of pyridinium.

对于与中心吡啶环相邻的质子（ΔHa=1.48ppm）以及相对于吡啶的氮的对位质子（（ΔHc=1.47ppm）观察到了最大的化学位移。

The enhancement of the reaction activity is attributed to the phasetransfer capability of the built-in quaternary ammonium and pyridinium salts of theMn catalyst. The effect of the internal quaternary ammonium and/or pyridiniumsalt on the epoxidation of substituted chromenes is similar to that of the externalpyridinium salts and ammonium halides.

分子内季铵盐和吡啶盐具有相转移能力，对于取代色烯不对称环氧化的作用与外加的吡啶盐和卤化铵的作用相似，使Mn催化剂催化取代色烯环氧化反应的活性明显提高。

A novel complex of Ni (3-PyOH)4Cl2 (3-PyOH=-pyridone) was synthesized by the reaction of NiCl26H2O and 3-hydroxypyridine in an alcohol solution, and characterized by elemental analysis, IR spectrum and single crystal X-ray diffraction.

利用氯化镍和3-羟基吡啶在乙醇溶液中反应得到了配合物Ni(3-PyOH)4Cl2（3-Pyon=3-羟基吡啶），并对其进行了元素分析、红外和单晶X射线的表征。

A few of aryl pyridylalkyl ethers were synthesized by Mitsunobu reaction from substituted phenols 1a-b and pyridyl alcohols 2a-e at room temperature in 45%~70% yields.

在室温下，以取代苯酚1a-b和吡啶烷基醇2a-d为原料通过Mitsunobu反应合成了相应的芳基吡啶烷基醚，反应收率为45%￣70%，反应物2和1之比为1.11∶。

A Mn TPP-Au/SiO2 composite catalyst was obtained by immobilizing Manganese porphyrin on Au/SiO2 (5% Au loading) using mercaptopyridine with sulfhydryl and pyridyl groups as bridging agent, and it was used for the aerobic oxidation of cyclohexane for the first time.

以包含巯基和吡啶基官能团的巯基吡啶为桥联剂，实现了MnTPP在金负载量为5%的Au/SiO2催化剂上的固载化，从而得到了一种新型MnTPP-Au/SiO2复合催化剂。

Two sorts of polyacrylate derivates were designed and systhesized. One has benzoic acid groups linked to backbone via an alkyl chain of different length, the other has pyridyl groups at its side chain. On the basis of hydrogen-bonding between carboxyl and pyridyl groups, multilayer film was fabricated in mixed solvents. We studied the effect of either the composition of mixed solvents or length of alkyl chain on the structure of a multilayer film.

设计合成了两类聚丙烯酸酯类高分子，一种侧链含有通过不同个数的亚甲基和主链相连的苯甲酸基团，另一种侧链含有吡啶基团，基于羧基和吡啶基之间的氢键相互作用，在混合溶剂中制备了多层膜，并研究了溶剂组成与高分子侧链间隔基长度对多层膜结构的影响。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了