吡啶

The calculated results showed that the decrease of the pyridylene content and the para-linked pyridylene in the backbone of the polythiophene resulted in a narrowed energy gap and bathochromic absorption and emission peaks.

另外，共聚物主链中吡啶成分减少以及吡啶的对位连接导致了能隙的变窄和吸收及荧光波长的红移。

Based on studies of RCM reaction of 50 and CM reaction ofacrylonitrile with 1-octene or 1-decene catalyzed by pyridine derivative-coordinatedruthenium benzylidene complexes, it can be concluded that ruthenium benzylidene complexwith the more labile dissociating ligand exhibits the higher initial activity and better catalyticperformance.

吡啶衍生物配位的钌卡宾配合物催化含氰基烯烃50闭环交互置换反应和丙烯腈与1-辛烯、1-癸烯交叉交互置换反应表明，催化剂中吡啶衍生物配体越易解离，其初活性越高，催化活性越好。

To improve water solubility of betulin, two acyl groups were introduced at C-3 and C-28 hydroxy groups of betulin. 3, 28-di-O-glutaryl-betulin was synthesized with pyridine as solvent and DMAP as catalyst from betulin and glutaryl anhydride.

为了增强桦木醇的亲水性，对桦木醇的C-3位、C-28位羟基进行修饰，在吡啶作溶剂、二甲基氨基吡啶作催化剂的条件下，与戊二酸酐反应合成桦木醇戊二酸酯。

In the procedures of syntheses, we chose 2,2"-bipyridine (2,2"-bipy), 4,4"-bipyridine (4,4"-bipy), 1,10-phenanthroline (1,10-phen) and 8—hydroxyquinoline as neutral ligands, and lead, copper, zinc, cadmium and manganese as metal ions in our research.

使用的中性配体为2，2′-联吡啶(2，2′-bipy)、4，4′-联吡啶(4，4′-bipy)、1，10-邻菲罗啉(1，10-phen)和8—羟基喹啉，研究的金属离子为主族金属Pb以及过渡金属Cu、Zn、Cd和Mn。

It was found that when the 2,2'-bipyridyl was used as a ligand for metal complex formation,an abnormal new peak was observed obviously whether in fluorescence or absorption spectrum.It indicated that a new species was formed owing to the reaction between them.

发现当以联吡啶为络合物配体时，无论荧光和吸收光谱中均出现反常的新峰，这和 1-溴乙基苯与吡啶间发生了成盐反应有关。

In order to find biologically active urea compounds,seven new N-[5-(3-pyridyl)-1,3,4-thiadiazol-2-yl]-N'- urea derivatives were synthesized by the reaction of 2-amino-5-(3-pyridyl)-1,3,4-thiadiazole with aroylazides,which were prepared starting from carboxylic acids,ethyl chloroformate and sodium azide by one-pot procedure.

为了寻找高生物活性的脲类化合物，通过2-氨基-5-(3-吡啶基)-1，3，4-噻二唑与酰基叠氮化物反应，设计合成了7个新的N-[5-(3-吡啶基)-1，3，4-噻二唑-2-基]-N'-取代苯基脲，其中芳酰基叠氮化物是以芳酸、氯甲酸乙酯、叠氮化钠为起始原料采用&一锅法&所制得。

R-1,c-2, t-3, t-4-1,3-bis(4-biphenyl)-2,4-di(4-pyridyl)cyclobutane was obtained in diluted sulfuric acid by photodimerization reaction.

通过反-1-(4-联苯基)-2-(4-吡啶基)乙烯在稀硫酸中的光二聚反应合成了r-1，c-2，t-3，t-4-1，3-双(4-联苯基)-2，4-二(4-吡啶基)环丁烷。

Seven 1-phenyl-(4-pyridinyl)acetylene derivatives were conveniently synthesized in this paper using corresponding styrylpyridines as starting materials by bromination, rearrangement and debromination.

本文采用简单易行的方法从苯乙烯基吡啶类衍生物通过溴化、重排和脱溴化反应合成了7种苯乙炔基吡啶类单体，研究了它们在1mol/L盐酸水溶液中的光环加成反应。

The results show that in the protonation process, because of the effect of meso-(p-methylpyridyl), the changes of the structure and bond charge population are obvious; the frontier molecular orbitals have opposite change trend with the case of meso-yridyl, the rapid exchanges of inner hydrogens of the protonated diacid with solvent protons become more difficult.

结果表明，由于m-甲基吡啶的影响，在质子化过程中结构和键电荷布居有明显变化；前沿分子轨道具有与四吡啶基情形相反的变化趋势，质子化二酸与溶液质子的快速交换作用也变得更困难了。

This is the first example of two-dimensional lanthanide MOFs with one dimensional water chains.2、Coordination polymer[Nd_2_3(H_2O)_2]·bpy·4H_2O(2)(bpdc=2, 2′-bipyridine-3,3′-dicarboxylate,bpy=4,4′-bipyridine)had been synthesized under hydrothermal conditions and its structures were determined by X-ray diffraction,and confirmed by IR and TG analysis.

该结构是在二维骨架的镧系配位聚合物中首次观察到的一维的水链结构。2、以Nd_2O_3，2，2′-联吡啶-3，3′-二羧酸和4，4′-联吡啶为原料，采用水热法合成了一个具有二维骨架结构的配位聚合物[Nd_2_3(H_2O)_2]bpy·4H_2O，通过IR、x射线单晶衍射分析和热重等手段对其结构进行了表征。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了