吡唑啉酮

Sodium diethyl oxalacetate ; \ Claisen condensation ; \ 1 phenyl 3 carbethoxy 5 pyrazolone

钠代草酰乙酸乙酯； Claisen酯缩合； 1苯基3羧酸乙酯5吡唑啉酮

Measurement of cyanide ; isonicotinic acid-pyrazolone colorimetric method ; experimental condition

氰化物测定；异烟酸—吡唑啉酮比色法；实验条件

The lower detection limit was 0.0006 mg/L Conclusion: Compared with the conventional isonicotinic acid 3-methy-1-pheny 1-5-pyrazolone spectrophotometry method, the advantages of the method are auto-sampling, rapid analysis speed and lower reagent consumption, etc.

与传统异烟酸－吡唑啉酮分光光度法相比，该方法具有自动进样、分析速率快、试剂耗量低等优点，可应用于大批量常规地表水分析。

A new photochromic organic compound of thiosemicarbazone, 4-( p -bromo-α-methylaminothiocarbonyl hydrazonobenzal)-2,5-dihydro-3-methyl-5-oxo-1-phenyl pyrazole, was synthesized and characterized by elemental analyses, IR, 1H NMR spectra, and X-ray single-crystal diffraction analysis.

文章合成了一个新的有机化合物1-苯基-3-甲基-4-对溴苯亚甲基-吡唑啉酮-5 缩甲基氨基硫脲(1)，并分别用元素分析、红外光谱、氢核磁共振及X-射线单晶衍射对化合物的结构进行了确证和表征。

Studies on the Synthesis, Crystal Structures and Photochemical Photochemical Properties of Pyrazolone Thiosemicarbazones

论文标题：吡唑啉酮缩氨基硫脲类化合物的合成，晶体结构及光化学性质研究

The coordination compounds of rare earth with macrocyclic、pyrazolone and tripodal ligand have distinctive structure and properties, and potential applications in exploring new materials, the investigations of analysis and separation of the ions.

稀土穴醚、吡唑啉酮、三脚架化合物具有独特的结构和性质，在新材料的研究、稀土的分析及分离等方面有潜在的应用。

In this dissertation, basing on molecular designs, two functional blocks such as perylene bisimide and pyrazolone were introduced to the polymer structures,trying to obtain two novel Schiff-based polymers, whose optical property and electrical property are more excellent and the inherent properties of Schiff-based polymers will be kept.

论文在综合文献的基础上，通过分子设计，将苝酰亚胺与吡唑啉酮两种官能团引入席夫碱聚合物结构中，试图构筑两类新型席夫碱聚合物，在保持席夫碱固有的性质功能的基础上，进一步改善席夫碱聚合物的光学和电学性能。

The study of crystal structure indicates that the complexes belongs to tetragonal,14(1)/a, a=b=27.047(5) A, c=14.103(3) A, a=b=y =90,V=10317(4)A3, Z=16, Dc=1.071g/cm3, F(000)=3408, R,=0.1395, R2=0.1766 and every unit of the tetranuclear complexes is four-coordinated to tridentate ligand and nitrogen atom in pyrazolone from other ligand. The complexes is slightly deformed square-planar geometry.

晶体结构研究表明，该配合物为四方晶系，空间群I4(1)/a，a=b=27.047(5)，c=14.103(3)，α=β=γ=90°，V=10317(4)，Z=16，Dc=1.071g/cm~3，F(000)=3408，R_1=0.1395，ωR_2=0.1766，其结构单元是由一个三齿配体中的ONO和另一个配体吡唑啉酮环二位上的N配位后形成略微畸变的平面四边形构型，其中Cu的配位数为4。

Two different fading procedures were studied. One is the oxidation procedure on polyester fibers,the other is the reduction procedure on wool fibers.The study of oxidation procedure mainly focused on 11 disperse azo dyes and 11 disperse anthraquinone dyes. The study of reduction procedure mainly focused on 7 pyrazolone coupled acid azo dyes and 10 azo disperse dyes which has sulfonic group on the couple component.

本论文研究了11支偶氮型分散染料，11支蒽醌型分散染料在聚酯纤维上的分子结构与光牢度的定量关系，同时研究了7支以吡唑啉酮为偶合组份的偶氮型酸性染料和10支偶合组份上带有磺酸基的偶氮型酸性染料在羊毛纤维上的分子结构与光牢度的定量关系。

The light fastness of pyrazolone coupled acid azo dyes has the relationship with 5 independent factors:the NK N2 charge (E-N1 E-N2),the dipole moment,the frontier orbit energy. The equation revealing the relationship was founded.

以吡唑啉酮为偶合组份的偶氮型酸性染料在羊毛纤维上的光牢度主要与下述5个分子结构独立因素有关：N1、N2上的电荷密度（E-N1、E-N2，分子偶极矩（μ，前线轨道的能量Ehomo、Elumo），并建立线性关系式。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。